WO2004049358A2 - Multifunctional particulate material, fluid, and composition - Google Patents
Multifunctional particulate material, fluid, and composition Download PDFInfo
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- WO2004049358A2 WO2004049358A2 PCT/US2003/016230 US0316230W WO2004049358A2 WO 2004049358 A2 WO2004049358 A2 WO 2004049358A2 US 0316230 W US0316230 W US 0316230W WO 2004049358 A2 WO2004049358 A2 WO 2004049358A2
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M171/00—Lubricating compositions characterised by purely physical criteria, e.g. containing as base-material, thickener or additive, ingredients which are characterised exclusively by their numerically specified physical properties, i.e. containing ingredients which are physically well-defined but for which the chemical nature is either unspecified or only very vaguely indicated
- C10M171/001—Electrorheological fluids; smart fluids
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01F—MAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
- H01F1/00—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties
- H01F1/0036—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties showing low dimensional magnetism, i.e. spin rearrangements due to a restriction of dimensions, e.g. showing giant magnetoresistivity
- H01F1/0045—Zero dimensional, e.g. nanoparticles, soft nanoparticles for medical/biological use
- H01F1/0054—Coated nanoparticles, e.g. nanoparticles coated with organic surfactant
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01F—MAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
- H01F1/00—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties
- H01F1/44—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of magnetic liquids, e.g. ferrofluids
- H01F1/447—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of magnetic liquids, e.g. ferrofluids characterised by magnetoviscosity, e.g. magnetorheological, magnetothixotropic, magnetodilatant liquids
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/02—Hydroxy compounds
- C10M2207/021—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/022—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms containing at least two hydroxy groups
- C10M2207/0225—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms containing at least two hydroxy groups used as base material
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2020/00—Specified physical or chemical properties or characteristics, i.e. function, of component of lubricating compositions
- C10N2020/01—Physico-chemical properties
- C10N2020/055—Particles related characteristics
- C10N2020/06—Particles of special shape or size
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2020/00—Specified physical or chemical properties or characteristics, i.e. function, of component of lubricating compositions
- C10N2020/01—Physico-chemical properties
- C10N2020/055—Particles related characteristics
- C10N2020/061—Coated particles
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/08—Resistance to extreme temperature
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/60—Electro rheological properties
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/14—Electric or magnetic purposes
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- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/17—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on variable-absorption elements not provided for in groups G02F1/015 - G02F1/169
- G02F1/172—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on variable-absorption elements not provided for in groups G02F1/015 - G02F1/169 based on a suspension of orientable dipolar particles, e.g. suspended particles displays
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- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F2203/00—Function characteristic
- G02F2203/52—Optical limiters
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01F—MAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
- H01F1/00—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties
- H01F1/01—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials
- H01F1/03—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity
- H01F1/12—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of soft-magnetic materials
- H01F1/14—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of soft-magnetic materials metals or alloys
- H01F1/20—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of soft-magnetic materials metals or alloys in the form of particles, e.g. powder
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01F—MAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
- H01F1/00—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties
- H01F1/01—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials
- H01F1/03—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity
- H01F1/12—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of soft-magnetic materials
- H01F1/34—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of soft-magnetic materials non-metallic substances, e.g. ferrites
- H01F1/36—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of soft-magnetic materials non-metallic substances, e.g. ferrites in the form of particles
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
- Y10T428/2991—Coated
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
- Y10T428/2991—Coated
- Y10T428/2993—Silicic or refractory material containing [e.g., tungsten oxide, glass, cement, etc.]
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
- Y10T428/2991—Coated
- Y10T428/2993—Silicic or refractory material containing [e.g., tungsten oxide, glass, cement, etc.]
- Y10T428/2995—Silane, siloxane or silicone coating
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
- Y10T428/2991—Coated
- Y10T428/2993—Silicic or refractory material containing [e.g., tungsten oxide, glass, cement, etc.]
- Y10T428/2996—Glass particles or spheres
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
- Y10T428/2991—Coated
- Y10T428/2998—Coated including synthetic resin or polymer
Definitions
- the present invention is generally directed to a particulate material, and more particularly to a multifunctional particulate material, composition, and fluid capable of exhibiting one or more properties, such as magnetic, thermal, optical, electrical, biological, lubrication and Theological.
- Dispersions of particles in fluids termed as functional fluids, exhibit controllable property changes with an application of either one or a combination of electrical, thermal, optical or magnetic impulses.
- the prominent examples from the art include thermal heat transfer fluids, magnetorheological (MR) fluids and electrorheological (ER) fluids.
- ER and MR fluids are known to exhibit changes in rheological behavior in the presence of an electrical and magnetic field, respectively, making them useful in a wide spectrum of applications, such as brakes, clutches, dampers and many others.
- these fluids could exhibit more than one functionality, their performance and life would increase many-folds.
- MR fluids in addition to rheological control, have a thermal tunablity, the life of the device, which is adversely affected by the dissipated heat, can be significantly increased.
- Such multifunctional fluids are not known to exist presently.
- the principal object of the present invention is to provide a particulate material that is capable of exhibiting multifunctional properties.
- An object of the present invention is to provide a particulate composition that is capable of exhibiting multifunctional properties.
- Another object of the present invention is to provide a fluid that is capable of exhibiting multifunctional properties.
- a fluid in accordance with the present invention is capable of exhibiting one or more properties, such as magnetic, thermal, optical, electrical, biological, chemical, lubrication, rheological, etc.
- An additional object of the present invention is to provide a fluid that is sensitive to one or more stimuli or fields, such as magnetic, thermal, optical, electrical, etc.
- Yet an additional object of the present invention is to provide a particulate material, a composition, a fluid, and/or an article including one or more of the same, which is capable of exhibiting substantially simultaneous variations in one or more of its properties when subjected to one or more stimuli, such as magnetic, thermal, optical, electrical, etc.
- Still yet an additional object of the present invention is to provide a particulate material, a composition, a fluid, and/or an article including one or more of the same, wherein multifunctional properties are preferably derived from the core particles, one or more coatings, and the carrier medium.
- the main object of the present invention is to provide a fluid which includes single or multilayered coated particles of one or more compositions in a suitable carrier medium.
- the particles, coatings and the carrier medium preferably include non-interacting compositions.
- the fluid exhibits a novel multifunctional behavior.
- a fluid possesses multifunctionality when it exhibits two or more properties.
- a wide variety of processes are adopted to (1) synthesize the particles in various sizes (about 1nm to 500 ⁇ m), shapes (spherical, needle-like, etc.), and composition (iron and its oxides, cobalt, nickel, etc.), (2) apply a coating of a variable thickness (about
- the main properties attained by the present invention include magnetic, optical, thermal, electrical, rheological, lubrication, and biological, in various combinations.
- the properties of the fluid can be easily tuned by either altering the material properties, or the proportion of applied stimuli. Table 1 (below) lists various tunable parameters for the fluid of the present invention.
- Figure 1 is a schematic illustration of various shapes for the core particles in accordance with the present invention.
- Figure 2 is an enlarged cross-sectional view of an embodiment of a multifunctional particle in accordance with the present invention.
- Figure 3 is an enlarged cross-sectional view of a multifunctional particle with two layers of generally the same thickness
- Figure 4 is a view similar to Figure 3, showing a multifunctional particle with two layers of different thicknesses
- Figure 5 is a schematic view showing a multifunctional fluid
- Figure 6 is a schematic illustration of magneto-responsive functional particles showing a change in viscosity upon application of a magnetic field
- Figure 7 is a schematic illustration of a magneto-optic functional fluid showing a change in turbidity upon application of a magnetic field
- Figure 8 is a schematic illustration of magneto-responsive functional particles showing an increase in electrical pathway
- Figure 9 is a schematic illustration of a magneto- responsive functional fluid showing controlling or arresting internal hemorrhage
- Figure 10 is a schematic illustration of a magneto- responsive functional fluid showing inhibiting angiogenesis
- Figure 11 is a schematic illustration of an optical fluid showing a change in transparency upon application of light intensity
- Figure 12 is a schematic illustration of an electro-optical functional fluid showing a change in transparency with increasing electric field
- Figure 13 is a schematic illustration of a thermo-optical functional fluid showing a change in color due to a change in temperature
- Figure 14 is a schematic illustration of an optical fluid showing a change in color with the application of a chemical or biological stimulus
- Figure 15 is a schematic illustration of an electro- responsive functional fluid showing a change in viscosity upon application of an electric field
- Figure 16 is a schematic illustration of a functional fluid wherein a pre-ceramic polymer coating on a core particle becomes ceramic when heat is applied.
- a multifunctional fluid in accordance with the present invention, is capable of exhibiting substantially simultaneous variations in one or more of its properties, when subjected to one or more specific stimuli.
- the multifunctional fluid includes one or more core particles with one or more coatings, dispersed in a suitable carrier medium. While the overall properties of the fluid are generally dictated by all three components, the core particles contribute the main desirable property, while the coatings and the carrier medium adds various other variable functionalities.
- the core particles that are the subject of the present invention can be synthesized by various methods, such as chemical synthesis, sol-gel, chemical co-precipitation and rapid solidification. The microwave plasma technique, described in U.S. Patent No.
- 6,409,851 issued June 25, 2002 (incorporated herein in its entirety by reference) is the preferred technique as it can make a wide spectrum of particles with high purity.
- the properties of the particle including electrical, thermal, magnetic or optical, vary significantly with the size of the particle. Tailoring the size of the particle can be used as a tool to effect required changes in the system.
- the functional fluid of the present invention includes core particles, preferably having an average particle size of about 1 nm to 500 ⁇ m.
- Other parameters as listed below in Table 1 , influence the desired functionality of the final fluid, and can be controlled by optimizing the synthesis process. For example, as the shape of the particle changes, so does the active surface area and the filled-up volume.
- the particles can be made of metal, polymer, ceramic material, intermetallic material, alloy, or a combination thereof.
- metal include iron, cobalt, nickel, copper, gold, silver, chromium, tungsten, silicon, aluminum, zinc, magnesium, titanium, molybdenum, tin, vanadium, germanium, zirconium, niobium, rhenium, iridium, cadmium, indium, hafnium, tantalum, platinum, neodymium, gallium, zinc, and a combination thereof.
- the polymer include polystyrene, polymethyl methacrylate, polyvinyl alcohol, polyphenylene vinylene, and a combination thereof.
- the ceramic material include iron oxide, zinc ferrite, manganese ferrite, zinc oxide, aluminum oxide, silicon dioxide, silicon carbide, boron carbide, carbon and its types, indium oxide, titania, aluminum nitride, zirconia, tin oxide, chromium oxide, yttrium oxide, niobium oxide, hafnium oxide, tantalum oxide, tungsten oxide, magnesium oxide, boron nitride, silicon nitride, hafnium nitride, tantalum nitride, tungsten nitride, iron nitride, vanadium nitride, titanium, silicon carbide, chromium carbide, vanadium carbide, titanium carbide, iron carbide, zirconium carbide, niobium carbide, hafnium carbide, tungsten carbide, tantalum carbide, titanium diboride, vanadium boride, iron boride, zirconium di
- the intermetallic material include titanium aluminide, niobium aluminide, iron aluminide, nickel aluminide, ruthenium aluminide, iridium aluminide, chromium aluminide, titanium suicide, niobium suicide, zirconium suicide, molybdenum suicide, hafnium suicide, tantalum suicide, tungsten suicide, iron suicide, cobalt suicide, nickel suicide, magnesium suicide, yttrium suicide, cadmium suicide, berryllium oxide, nickel berryllide, niobium berryllide, tantalum berryllide, yttrium berryllide, tantalum berryllide, zirconium berryllide, and a combination thereof.
- the alloy include indium tin oxide, cadmium selenide, iron-cobalt, ferro-nickel, ferro-silicon, ferro-manganese, ferro- magnesium, brass, bronze, steel, a combination of two or more of the aforementioned metals, and a combination thereof.
- Preferable examples of the shape of the particles, utilized in the present invention include spherical, needle-shaped, cubic, oval, irregular, cylindrical, diamond-shaped, lamellar, polyhedral, and a combination thereof ( Figure 1).
- the present invention involves uniformly coating particles
- the precursors or starting materials for synthesizing particles, as well as the coating material (in liquid or molten form) are subjected to high thermal energy.
- the uniformity and extent of coating(s) are controlled by varying operating parameters, such as temperature, feeding rate and proportions (of the starting materials or precursors), and the pressure of the process.
- ⁇ number of coated layers will depend simply on the feed composition and their concentration.
- One of the important advantages of the gas phase coating process is that it does not allow any gases or static charges to get adsorbed on the particle surface, thereby maintaining phase purity.
- the liquid phase process is typically a chemical synthesis route in which the coating is established by reduction of the precursor (or starting material) while the favorable reaction site is the surface of the particles.
- this technique proves useful only in materials, which readily undergo reduction in a solution phase.
- One of the primary advantages of this technique is that coating is established in stages, which gives precise control over the coating thickness and uniformity of layers in a multilayered system.
- the solution route may be similar to a core-shell polymerization while the gas phase would relate to a thermally assisted free radical polymerization reaction.
- the type of polymer hydrophilic, i.e., water-loving, or hydrophobic, i.e., insoluble in water
- carrier fluid such as water, oil, or the like
- one to ten coatings are provided, and each has a thickness range of about 1 nm to 500 ⁇ m, and preferably 1 nm to 10 ⁇ m.
- the coatings can have generally the same or varying thicknesses. It is noted that it is within the scope of the present invention to provide more than ten coatings of a different range of thickness.
- the coating can be made of metal, polymer, ceramic material, intermetallic material, alloy, or a combination thereof.
- the metal include iron, cobalt, nickel, copper, gold, silver, chromium, tungsten, silicon, aluminum, zinc, magnesium, titanium, molybdenum, tin, indium, bismuth, vanadium, magnesium, germanium, zirconium, niobium, rhenium, iridium, cadmium, indium, hafnium, tantalum, platinum, neodymium, gallium, zinc, and a combination thereof.
- polymer examples include polyethylene glycol, sorbitol, manitol, starch, dextran, polymethyl methacrylate, polyaniline, polystyrene, poly pyrolle, N- isopropyl acrylamide, acrylamide, lecithin, and a combination thereof.
- the ceramic material include iron oxide, zinc ferrite, manganese ferrite, zinc oxide, aluminum oxide, silicon dioxide, silicon carbide, boron carbide, carbon and its types, indium oxide, titania, aluminum nitride, zirconia, tin oxide, chromium oxide, yttrium oxide, niobium oxide, hafnium oxide, tantalum oxide, tungsten oxide, magnesium oxide, boron nitride, silicon nitride, hafnium nitride, tantalum nitride, tungsten nitride, iron nitride, vanadium nitride, titanium, silicon carbide, chromium carbide, vanadium carbide, titanium carbide, iron carbide, zirconium carbide, niobium carbide, hafnium carbide, tungsten carbide, tantalum carbide, titanium diboride, vanadium boride, iron boride, zirconium di
- the intermetallic material include titanium aluminide, niobium aluminide, iron aluminide, nickel aluminide, ruthenium aluminide, iridium aluminide, chromium aluminide, titanium silicide, niobium silicide, zirconium silicide, molybdenum silicide, hafnium silicide, tantalum silicide, tungsten silicide, iron silicide, cobalt silicide, nickel silicide, magnesium silicide, yttrium silicide, cadmium silicide, berryllium oxide, nickel berryllide, niobium berryllide, tantalum berryllide, yttrium berryllide, tantalum berryllide, zirconium berryllide, and a combination thereof.
- the alloy include indium tin oxide, cadmium selenide, iron-cobalt, ferro-nickel, ferro-silicon, ferro-manganese, ferro-magnesium, brass, bronze, steel, a combination of two or more of the aforementioned metals, and a combination thereof.
- the final property of the fluid will preferably depend upon the nature and type of carrier medium.
- water alone can be used.
- water miscible organic solvents such as ethanol, glycerol, ethylene glycol, propanol, dimethyl formamide, and the like can be used.
- Water-based carrier fluids may also be used in various biological applications, such as imaging or drug targeting.
- oil may be used. The coated particle, when dispersed in a high viscosity fluid, would reduce their natural Brownian motion, thereby rendering a higher level of stability to the system.
- a non-limiting example of the carrier fluid that may be used in the present invention includes water, mineral oil, hydraulic oil, silicone oil, vegetable oil (corn oil, peanut oil and the like), ethanol, glycerol, ethylene glycol, propanol, dimethyl formamide, paraffin wax, and a combination thereof.
- the particles and their respective coatings essentially define the properties for the entire fluid.
- properties such as optical, thermal or magnetic, are all dependent upon the force distribution between the particles, which is closely related to the interparticle distance.
- microscopic properties are strongly affected by the force fields and the interracial contact area.
- the particles do not agglomerate.
- the present invention therefore utilizes a dispersant (or surfactant) stabilized system, wherein the agent assists the particles in remaining dispersed and reduces their tendency to get settled.
- surfactants include: dextran, starch, lecithin, glycol, glycerol, sorbitol, manitol, oleic acid, polyethylene glycol, and a combination thereof.
- Figures 2-4 illustrate an embodiment of a multifunctional particle MFP made in accordance with the present invention.
- a core particle 10 made of a magnetic material (iron)
- a core particle 18 is provided with two layers 20 and 22 of the same thickness
- Figure 4 illustrates a multifunctional particle MFP, which includes a core particle 24 provided with two layers 26 and 28 of different thicknesses.
- Figure 5 illustrates a fluid wherein multifunctional particles
- MFP each including a core particle 30 with two layers 32 and 34, are dispersed in a suitable carrier medium 36 to form a multifunctional fluid or composition.
- the present invention provides fluids which can exhibit multifunctional characteristics. These include optical, magnetic, thermal, electrical, rheological and biological properties that can be controlled (or altered) by one or more external stimuli.
- the core particle represents the main properties, while the coatings and the carrier medium contribute to other accompanying functionalities.
- the fluid according to the present invention preferably contains all the components, which are non-interactive and the properties do not interact with each other.
- Magnetic particles preferably of Fe, Co, Ni, Fe 2 O 3 or ferrites (about 2% to 90 vol% concentrations, i.e., about 2 to 90 vol% of the fluid is comprised of the magnetic particles, dispersed in various media, such as water, mineral oil, glycerol, elastomers, polymeric liquids, organic solvents and the like, exhibit a change in viscosity upon interaction with a magnetic field ( Figure 6).
- the change in rheology can be controlled by intrinsically altering the magnetic properties of the particles or by variation in the magnitude of the external magnetic field.
- the magnetic properties, such as magnetic saturation and coercivity, of the particles are dependent upon the shape and size of the particle, which can be precisely controlled and varied in the present invention (see Tables 2 and 3 below).
- the use of a mixture of particles, such as a mixture of iron and cobalt, mixture of iron and samarium- cobalt alloy, with different magnetic moments is preferred over a single component fluid.
- One example is coating of magnetic particles with thermally conducting metal, such as copper, aluminum, silica, aluminum oxide, and tungsten. This can be introduced via a conventionally known reverse miceller procedure, wherein the coating is established in a solution phase. The thermal coating would absorb any heat, which may have been generated due to the motion of particles in the medium.
- thermally conducting metal such as copper, aluminum, silica, aluminum oxide, and tungsten.
- magnetic particles are dispersed in an optically clear matrix, such a polymethyl methacrylate (PMMA), polycarbonate, indium oxide, or the like polymer.
- PMMA polymethyl methacrylate
- Optically clear materials in general are transparent to white light and have very low coefficient of absorption. The turbidity (or transparency) would be a function of the loading level of the particles. However, at constant solid's content, the application of magnetic field would align the particles, thereby forming a layered structure ( Figure 7). When the distance between the layers is about one-half the order of magnitude of visible light, 400-800 nm, classical Bragg diffraction will result in forbidden bands at typical frequencies.
- coated polymer magnetic particles exhibited sharp magnetic switching effects. This is believed to be due to the dipolar contribution of the polymer that directly influences the inter- particle interactions. Magnetic bistability and switching at low fields obtained in polymer-coated particles would be desirable in systems where the impedance in response to electrical or magnetic stimuli needs to be monitored with high precision. These compositions would therefore be of interest in, for example, RF switching and EMI shielding applications.
- the above-noted fluids can be slightly modified to obtain magnetically controlled conductive composites, wherein magnetic particles, such as ferrites, are doped in conductive polymers, such as polyaniline, or polyphenylene vinylenes (PPV). As the particles are aligned in chains, an increase in electrical pathway is seen ( Figure 8). Hence, a magnetically tunable composite fluid can be produced in accordance with the present invention.
- magnetic particles such as ferrites
- conductive polymers such as polyaniline, or polyphenylene vinylenes (PPV).
- PVP polyphenylene vinylenes
- a biological fluid is produced.
- This fluid includes biocompatible magnetic particles.
- the biocompatibility is due of the coating of polymers, such as dextran, starch, polyethylene glycol, sorbitol, or the like.
- the fluid can be injected inside the body to arrest internal hemorrhage or seal off blood vessels in order to inhibit angiogenesis.
- the sealing action is a result of a reversible viscosity increase in the presence of an externally positioned magnet.
- magnetic particles 38 coated with a biocompatible surfactant and/or surface attached with desirable reagent/medicine/drug, are dispersed in a blood vessel 40.
- the particles 38 are aligned to form a blockage 42 upon application of a magnetic field by magnets 44, thereby arresting hemorrhage 46.
- Figure 10 illustrates the use of magnetic particles 38 in inhibiting angiogenesis. As shown, particles 38 are carried through the blood vessel 48 that feeds the target organ 50. The application of a magnetic field by magnets 52 causes agglomeration 54 of the particles carrying the desired drug.
- a fluid which exhibits optical multifunctionality is disclosed.
- This fluid is capable of transmitting visible light at a broad range of temperature range.
- the optical properties of fluids seem to drastically change as a function of increasing temperature, typically increasing their attenuation.
- optically clear ceramic particles such as ZnO or InO
- ZnO or InO are coated with a thin layer of copper having a thickness of about 10 nm to 100 nm. The coating thickness is limited by the optical clarity of the fluid.
- semiconductor nanocrystals such as gallium arsenide, silicon carbide, silicon, germanium, cadmium selenide, and a combination thereof, are dispersed in an index matching liquid, such as water, oil, mixture of water and oil, polyethylene glycol, polymethylmethacrylate, polyacrylamide, polystyrene, and a combination thereof.
- the fluid is subjected to a laser impulse of fixed wavelength.
- the refractive index mismatch increases, thereby lowering the transparency of the medium ( Figure 11 ).
- the transparency of the medium is a function of the intensity of the incident light source. Changing the size and loading levels of the nanocrystals can be used to tune the optical limiting frequency.
- Cu-coated ceramic particles are dispersed in a conducting matrix.
- the transparency of this fluid changes from clear (about 100% transmittance) to opaque (0% transmittance), as a function of the varying electric field (OA to 1000A) ( Figure 12).
- OA to 1000A varying electric field
- the present invention further discloses luminescent particles of gold and silver, which have a characteristic size on the order of the wavelength of visible light. These particles are embedded in a thermally switchable polymer matrix, such as N-isoproplylacrylamide, polyvinyl alcohol, polyethylene glycol, polyalkelene glycol, and a combination thereof. These polymeric gels possess a lower critical solution temperature of about room temperature. Above and below this temperature, there are significant differences between the excluded free volumes, which change the configuration of the encapsulated particles resulting in change in color (Figure 13). This property could be used in the fabrication of, for example, a temperature sensor. [0058] The embodiment of Figure 13, could be slightly modified to fabricate an optical sensing fluid. Colloidal particles of gold or silver, coated with molecular recognition species, are dispersed in an aqueous or clear organic carrier medium. The interaction of molecules with a chemical or biological stimuli would alter the local configuration of the particles, thereby changing their reflecting color ( Figure 14).
- a thermally switchable polymer matrix such as N-
- Electro-responsive Functional Fluids An electrically tunable fluid is disclosed. This includes silica particles coated with Cu (about 10 nm to 10 ⁇ m thickness) in a dielectric solvent, such as water, mineral oil, polypyrole, polyaniline, ethylene glycol, and a combination thereof. As the electric potential increases, 0-10KV/mm, the rheology (change in viscosity ranging from 1.0 cP to 200,000 cP) of the medium changes. In addition, the electric current increases the thermal energy of the entire system ( Figure 15). However, in the fluid of the present invention, the copper coating absorbs all the excess thermal energy produced. Thus, simultaneous rheology and thermal control can be affected. This fluid would be found to be highly useful in applications demanding instantaneous change in viscosity under severe temperature conditions, such as in aircraft seals, automobile clutches and brakes, and vibration isolation in structures. Multifunctional Biological Fluid
- a fluid capable of delivering drugs to a targeted body site is disclosed.
- the selected drug is attached to a magnetic core of iron or ferrites, cobalt or nickel coated with an optical layer of fluorescent Au or Ag molecules.
- the fluid particles are then magnetically driven to the target site where the drug is desorbed.
- Optical capturing which is a consequence of the fluorescent molecules, assists in the magnetic localization.
- the fluid of the previous embodiment can be extended to magnetic bioseparation and detection.
- magnetic particles can be functionalized with a bioligand, which specifically binds to a target molecule, cell, toxin, pathogen, DNA, RNA, proteins, and other biochemicals. This would isolate the required biomolecule from a mixture and the number of separated magnetic particles can be detected with the help of highly sensitive magnetic field sensors, such as HGMS (high gradient magnetic separators), or SQUID (Superconducting Quantum Interface Design).
- HGMS high gradient magnetic separators
- SQUID Superconducting Quantum Interface Design
- All of these modules can be miniaturized and placed on a microchip where micropumps would inject the sample fluid into various microchambers/ microreactors.
- the microreactors will contain a multifunctional biological fluid with different anylate specificity. Embedded in the reactors would be highly sensitive magnetic particle sensors, which will transduce the signal in to a user-friendly output.
- gas sensors for CO, CO 2 , O 2 , and the like chemical sensors for water and other liquids, and biological sensors for glucose, DNA, and the like can be easily made.
- the core can be either magnetic, such as Fe, Co, Ni, etc., or conducting, such as Cu, Ag, Au, polymers, such as polyaniline, polypyrolle, etc., and the encapsulating polymer matrix can be polystyrene or PMMA. Variations in electric or magnetic field will cause local permeability variations to effect RF limiting features.
- indium tin oxide in a silica, alumina or titanium oxide matrix are subjected to varying electric fields.
- the electric field changes the oxidation state of the metal oxide particles, thereby exhibiting an electrochromic effect.
- semiconductor nanocrystals such as CdSe are dispersed in a polymer matrix containing a dye. As the intensity of the light changes, a photochromic effect is observed. This is due to optical nonlinearity possessed by semiconductor species.
- These photochromic fluids may be made to form a flexible polymer sheet, which would be useful in making, for example, automatic automobile sunshades, etc.
- Multifunctionality in fluids is highly desirable.
- SiC-based particles used as abrasives generate a lot of heat, which may severely damage the surface they are acting on.
- the present invention addresses this by coating SiC particles with a coating of Au, Ag, Cu, Ni, or the like.
- An abrasive fluid, including SiC coated particles can be used in sensitive applications, such as in microelectronics where heat is a big deterrent and causes damage to microelectronic circuitry.
- abrasive particles that can likewise be coated with a heat-absorbing material, include those made of boron carbide, iron carbide, aluminum oxide, zirconium oxide, titanium diboride, silica, yttrium-aluminum-garnet, or a combination thereof.
- SiC particles are coated with a pre-ceramic polymer, such as polysilsesquioxane or polycarbosilane. These are structural materials useful in flame-resistance and high temperature applications, where the pre-ceramic polymer turns into a ceramic with applied heat ( Figure 16).
- a polymer in structures generally gives the benefits of adhesion and aesthetics, while ceramics are used for high temperature stability.
- a self-lubricating high temperature functional fluid is disclosed.
- the core particle can be made of Cu, while the coatings can be of graphite, bismuth, indium or Teflon ® .
- the coated copper particles are dispersed in oils, such as hydraulic oil or mineral oil. These fluids can be used in various engineering structures, such as engines and transmission housing.
- a quenching fluid used in heat-treating operation of metals such as quenching, tempering, austempering and martempering.
- the fluid removes heat from the heated metal.
- the cooling rate determines the microstructure, such as grain size, grain shape and phase (alpha, gamma, beta, delta, austenite, matensite, bainite, pearlite, cementite) composition of the part being made.
- the cooling rate can be adjusted by adjusting the thermal conductivity of the fluid. By incorporating polymer-coated particles with desired thermal conductivities in the quenching fluid, the cooling rate can be adjusted or controlled.
- the coating thickness preferably varies from 1nm to 100 ⁇ m with the number of layers ranging preferably from one to ten.
- the polymer coating is preferably based on polyalkylene glycol, polyvinyl alcohol, or a combination thereof.
- the particles can be metals (aluminum, titanium, copper, silicon, zinc, iron, cobalt, nickel, chromium, bismuth, silver, tungsten, molybdenum, or a combination thereof), ceramics (graphite, aluminum oxide, silicon oxide, beryllium oxide, titanium boride, molybdenum boride, silicon carbide, boron carbide, zirconium boride, hafnium boride, aluminium nitride, iron oxide, or a combination thereof) intermetallics (molybdenum silicide, titanium aluminides, nickel aluminides, berrylides, or a combination thereof), or a combination thereof.
- the coated particles can be dispersed in water, oil (mineral oil, silicone oil, hydraulic oil, synthetic oil, or a combination thereof) or an emulsion (sodium dodecyl sulfate in water, polyethylene glycol in water, polyvinyl alcohol in water, oil in water, polystyrene in water, polyacrylamide in water, or a combination thereof).
- the composition of the particles can be tailored to obtain different thermal conductivities (0 - 400 W/m.°K) in the fluid. Similarly, by adjusting the quantity of the particles (1- 90 volume %) in the fluid, thermal conductivities can be adjusted.
- Example 1 Powder particles of iron with particle size of about 20 nm were synthesized from iron pentacarbonyl using microwave plasma synthesis technique. Argon was used as the plasma gas. The iron powders were subsequently coated with a layer of copper measuring with variable thickness (about 1 nm to 1000 nm) using a chemical synthesis technique. These powders were coated with sodium hexametaphosphate for dispersion in hydraulic oil for use as magneto-rheological fluids with a thermal control. The viscosity of the fluid could be changed by the application of a magnetic field to effect damping in shock absorbers used in automobiles and machinery. The copper coating will dissipate the heat generated from the motion of the moving parts in the damper.
- Table 4 below shows the effect of the applied magnetic field on the yield stress.
- the magnetic field is varied by varying the current that is applied.
- the change in yield stress is effected as a result in the change of viscosity. In other words, an increase in yield stress signifies a higher viscosity.
- Example 2 Ultrafine particles of aluminum oxide with a particle size of about 1 nm to 200 nm were prepared using microwave plasma synthesis of aluminum hydroxide using oxygen as the plasma gas. The nanoparticles were coated with a layer of cetyl trimethyl ammonium bromide with a coating thickness from about 1 nm to 20 nm. The coated particles were dispersed in a polyetherimide (PEI) polymer. The particles increased the inherent flame retardancy of the polymer while the fillers increased the mechanical properties and resistance to wear.
- PEI polyetherimide
- Example 3 Powder particles of iron with particle size ranging from about 1nm to 40 ⁇ m were synthesized by microwave plasma synthesis using iron pentacarbonyl as the source and argon as the plasma gas.
- the powder particles were coated with a layer of polystyrene.
- the polystyrene coating was carried out in the gas phase in the microwave plasma synthesis.
- the thickness of the polystyrene ranges from about 1nm to 100nm.
- the coated particles are dispersed in a carrier fluid such as saline solution, water or blood for injection into a human body.
- These particles may be surface modified with various procoagulants such as thrombin, factor 7A and like for arresting internal hemorrhage.
- the particles may be attached with various antibodies/drugs/antigens for toxin, purification, isolation of biomolecules, water and chemical pollution and like.
- Example 4 Aluminum nitride powders with a particle size of about 1 nm to 10 ⁇ m were coated with an about 1nm to 100 nm layer of ethyl cyano acrylate using microwave plasma technique.
- the aluminum nitride powders were prepared using microwave plasma synthesis of trimethyl aluminum and ammonia.
- the coated aluminum nitride particles are then dispersed in an adhesive resin for mounting heat sinks to electronic substrates.
- the aluminum nitride provides effective heat dissipation due to its high thermal conductivity as well as provide good mechanical strength to the adhesive.
- Example 5 Copper powders with a particle size of about 1nm to 50 ⁇ m were mixed in a solution of ethylene glycol and water. The concentration of the copper powders in the ethylene glycol solution varied from about 10 vol% to 60 vol%. This fluid is used for heat transfer in furnaces, pumps and engines. The ethylene glycol acts as a rust inhibitor while the copper powders help in the removal of heat.
Abstract
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CN108863371A (en) * | 2017-05-15 | 2018-11-23 | 山东大学 | Al2O3The adaptive texture gradient sintex of/TiC/VN and its preparation process |
CN111482177A (en) * | 2020-05-07 | 2020-08-04 | 江苏新河农用化工有限公司 | Catalyst for preparing hydrogenated terphenyl and preparation method and application thereof |
Also Published As
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US20040105980A1 (en) | 2004-06-03 |
WO2004049358A3 (en) | 2005-03-17 |
CA2473450C (en) | 2010-10-05 |
AU2003259026B9 (en) | 2008-03-13 |
AU2003259026A1 (en) | 2004-06-18 |
US7560160B2 (en) | 2009-07-14 |
AU2003259026B2 (en) | 2007-06-07 |
AU2003259026B8 (en) | 2004-06-18 |
CA2473450A1 (en) | 2004-06-10 |
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