WO2005043250B1 - Process for the use of bis-choline and tris-choline in the cleaning of quartz-coated polysilicon and other materials - Google Patents

Process for the use of bis-choline and tris-choline in the cleaning of quartz-coated polysilicon and other materials

Info

Publication number
WO2005043250B1
WO2005043250B1 PCT/US2004/035148 US2004035148W WO2005043250B1 WO 2005043250 B1 WO2005043250 B1 WO 2005043250B1 US 2004035148 W US2004035148 W US 2004035148W WO 2005043250 B1 WO2005043250 B1 WO 2005043250B1
Authority
WO
WIPO (PCT)
Prior art keywords
composition
weight
substrate
amount
choline
Prior art date
Application number
PCT/US2004/035148
Other languages
French (fr)
Other versions
WO2005043250A3 (en
WO2005043250A2 (en
Inventor
Richard William Charm
De-Ling Zhou
Robert J Small
Shihying Lee
Original Assignee
Ekc Technology Inc
Richard William Charm
De-Ling Zhou
Robert J Small
Shihying Lee
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ekc Technology Inc, Richard William Charm, De-Ling Zhou, Robert J Small, Shihying Lee filed Critical Ekc Technology Inc
Priority to JP2006536846A priority Critical patent/JP2007510173A/en
Priority to EP04796185A priority patent/EP1682944A2/en
Publication of WO2005043250A2 publication Critical patent/WO2005043250A2/en
Publication of WO2005043250A3 publication Critical patent/WO2005043250A3/en
Publication of WO2005043250B1 publication Critical patent/WO2005043250B1/en

Links

Classifications

    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03FPHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/26Processing photosensitive materials; Apparatus therefor
    • G03F7/42Stripping or agents therefor
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03FPHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/26Processing photosensitive materials; Apparatus therefor
    • G03F7/42Stripping or agents therefor
    • G03F7/422Stripping or agents therefor using liquids only
    • G03F7/425Stripping or agents therefor using liquids only containing mineral alkaline compounds; containing organic basic compounds, e.g. quaternary ammonium compounds; containing heterocyclic basic compounds containing nitrogen
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D11/00Special methods for preparing compositions containing mixtures of detergents ; Methods for using cleaning compositions
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22Organic compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22Organic compounds
    • C11D7/32Organic compounds containing nitrogen
    • C11D7/3218Alkanolamines or alkanolimines
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22Organic compounds
    • C11D7/32Organic compounds containing nitrogen
    • C11D7/3281Heterocyclic compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22Organic compounds
    • C11D7/34Organic compounds containing sulfur
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03FPHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/26Processing photosensitive materials; Apparatus therefor
    • G03F7/42Stripping or agents therefor
    • G03F7/422Stripping or agents therefor using liquids only
    • G03F7/426Stripping or agents therefor using liquids only containing organic halogen compounds; containing organic sulfonic acids or salts thereof; containing sulfoxides
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/04Manufacture or treatment of semiconductor devices or of parts thereof the devices having at least one potential-jump barrier or surface barrier, e.g. PN junction, depletion layer or carrier concentration layer
    • H01L21/18Manufacture or treatment of semiconductor devices or of parts thereof the devices having at least one potential-jump barrier or surface barrier, e.g. PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic System or AIIIBV compounds with or without impurities, e.g. doping materials
    • H01L21/30Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
    • H01L21/302Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26 to change their surface-physical characteristics or shape, e.g. etching, polishing, cutting
    • C11D2111/22

Abstract

A new cleaning chemistry based on bis-choline and tris-choline compounds, such as their hydroxides, is provided in order to address the removal of photoresist and flux while minimizing any etching of the substrate.

Claims

AMENDED CLAIMS [received by the International Bureau on 11 August 2005 (11.08.2005); new claims 26 and 27 added; remaining claims unchanged (1 page)]
19. The composition of claim 17, wherein the polar aprotio nitrogen- containing solvent is present in an, amount from about 15% to about 35% by weight.
20. The composition of claim 19, wherein the polar aprotic nitrogen- containing solvent is present in an amount from about 20% to about 30% by weight,
21. The composition of claim 17, wherein the choline derivative is present in an amount from about 0.5% to about 10% by weight.
22. The composition of claim 21 , wherein the choline derivative is present in an amount from about 1% to about 5% by weight 23. The composition of claim 17, wherein the sulfur-containing solvent comprises dimethyl sulfoxide, methyl sulfoxide, or a mixture thereof.
24. The composition of claim 23, wherein the sulfur-containing solvent is present in an amount from about 60% to about 84% by weight
25. The composition of claim 24, wherein the sulfur^-containing solvent is present in an amount from about 66% to about 76% by weight,
26. A method of removing one or more of photoresist, etching residue, and flux material from an integrated circuit substrate, comprising contacting the substrate with a composition of any of claims 1-25, wherein the composition contacts the substrate for a time between 1 minute and 60 minutes and is at a temperature of between 10° C and 100° C.
27. A method of removing one or more of photoresist, etching residue, and flux material from an integrated circuit substrate, comprising: A) providing an integrated circuit substrate comprising copper and a low- material; B) contacting the substrate with a composition comprising: a) between 1% and 70% by weight of a hydroxide or salt of bis-(2-hydroxy- ethyl)-dimethyl ammonium, a hydroxide or salt of tris-(2-hydroxy-ethyl>methyl ammonium, or rαixture thereof, b) water, c) between 0.2% and 20% by weight of an amine, wherein the composition contacts the substrate for a time between 1 minute and 60 minutes and is at a temperature of between 10° C and 100° C; and C) rinsing the substrate.
AMENDED SHEET (ARTICLE 19) 27
PCT/US2004/035148 2003-10-22 2004-10-22 Process for the use of bis-choline and tris-choline in the cleaning of quartz-coated polysilicon and other materials WO2005043250A2 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
JP2006536846A JP2007510173A (en) 2003-10-22 2004-10-22 Process of using bischoline and trischoline in cleaning quartz coated polysilicon and other materials
EP04796185A EP1682944A2 (en) 2003-10-22 2004-10-22 Process for the use of bis-choline and tris-choline in the cleaning of quartz-coated polysilicon and other materials

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US10/689,657 US7135445B2 (en) 2001-12-04 2003-10-22 Process for the use of bis-choline and tris-choline in the cleaning of quartz-coated polysilicon and other materials
US10/689,657 2003-10-22

Publications (3)

Publication Number Publication Date
WO2005043250A2 WO2005043250A2 (en) 2005-05-12
WO2005043250A3 WO2005043250A3 (en) 2005-08-11
WO2005043250B1 true WO2005043250B1 (en) 2005-10-20

Family

ID=34549851

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2004/035148 WO2005043250A2 (en) 2003-10-22 2004-10-22 Process for the use of bis-choline and tris-choline in the cleaning of quartz-coated polysilicon and other materials

Country Status (6)

Country Link
US (1) US7135445B2 (en)
EP (1) EP1682944A2 (en)
JP (1) JP2007510173A (en)
KR (1) KR20070003772A (en)
CN (1) CN1871553A (en)
WO (1) WO2005043250A2 (en)

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Also Published As

Publication number Publication date
JP2007510173A (en) 2007-04-19
US20040147421A1 (en) 2004-07-29
WO2005043250A3 (en) 2005-08-11
US7135445B2 (en) 2006-11-14
EP1682944A2 (en) 2006-07-26
CN1871553A (en) 2006-11-29
WO2005043250A2 (en) 2005-05-12
KR20070003772A (en) 2007-01-05

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