WO2005064647A1 - Method and apparatus for cleaning semiconductor wafers using compressed and/or pressurized foams, bubbles, and/or liquids - Google Patents
Method and apparatus for cleaning semiconductor wafers using compressed and/or pressurized foams, bubbles, and/or liquids Download PDFInfo
- Publication number
- WO2005064647A1 WO2005064647A1 PCT/US2004/042831 US2004042831W WO2005064647A1 WO 2005064647 A1 WO2005064647 A1 WO 2005064647A1 US 2004042831 W US2004042831 W US 2004042831W WO 2005064647 A1 WO2005064647 A1 WO 2005064647A1
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- semiconductor wafer
- foam
- jammed
- semiconductor
- pressure
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Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having at least one potential-jump barrier or surface barrier, e.g. PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having at least one potential-jump barrier or surface barrier, e.g. PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic System or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/30—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
- H01L21/302—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26 to change their surface-physical characteristics or shape, e.g. etching, polishing, cutting
- H01L21/304—Mechanical treatment, e.g. grinding, polishing, cutting
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B08—CLEANING
- B08B—CLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
- B08B3/00—Cleaning by methods involving the use or presence of liquid or steam
- B08B3/003—Cleaning involving contact with foam
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/67—Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere
- H01L21/67005—Apparatus not specifically provided for elsewhere
- H01L21/67011—Apparatus for manufacture or treatment
- H01L21/67017—Apparatus for fluid treatment
- H01L21/67028—Apparatus for fluid treatment for cleaning followed by drying, rinsing, stripping, blasting or the like
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/67—Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere
- H01L21/67005—Apparatus not specifically provided for elsewhere
- H01L21/67011—Apparatus for manufacture or treatment
- H01L21/67017—Apparatus for fluid treatment
- H01L21/67028—Apparatus for fluid treatment for cleaning followed by drying, rinsing, stripping, blasting or the like
- H01L21/6704—Apparatus for fluid treatment for cleaning followed by drying, rinsing, stripping, blasting or the like for wet cleaning or washing
- H01L21/67046—Apparatus for fluid treatment for cleaning followed by drying, rinsing, stripping, blasting or the like for wet cleaning or washing using mainly scrubbing means, e.g. brushes
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S134/00—Cleaning and liquid contact with solids
- Y10S134/902—Semiconductor wafer
Definitions
- the present invention relates to the field of semiconductor wafers. More particularly, the invention relates to a method and apparatus for Cleaning Semiconductor Wafers Using Compressed and/or Pressurized Foams, Bubbles, and/or Liquids.
- the sensitivity is due to the submicron feature sizes as well as the decreasing thickness of the deposited layers on the wafer surface.
- the minimum feature size being designed at present in dense integrated circuits is about 0.11 microns. This will soon shrink to less than a tenth of a micron.
- the allowable contaminant particle size also must be controlled to smaller and smaller dimensions. In general, the contaminant particle size should be about 10 times smaller than the minimum feature size, therefore requiring control of contaminant particulate matter to better than one-one hundredth of a micron (i.e. better than 10 nm).
- semiconductor wafers are manufactured in batch processes and then stored until later processing, rather than being fabricated in a continuous process, they are even more susceptible to this contaminant particulate matter from the environment being introduced to the surface.
- semiconductor wafers are dried at the end of each batch process so that they can be safely transported and stored safely, use of isopropyl alcohol, a solvent generally employed during drying of the semiconductor wafer, has become problematic due to its volatile emissions as well as other reasons.
- Substances other than Dl water and isopropyl alcohol may also be conduits for introducing contaminants to the semiconductor wafer.
- the contaminants on semiconductor wafer surfaces exist as films, discrete particles or groups of particles and adsorbed gases. These surface films and particles can be molecular compounds, ionic materials or atomic species.
- Contaminants in the form of molecular compounds are mostly condensed organic vapors from lubricants, greases, photo resists, solvent residues, organic components from deionized water or plastic storage containers, and metal oxides or hydroxides.
- Contaminants in the form of ionic materials may be cations and anions, mostly from inorganic compounds that may be physically adsorbed or chemically bonded, such as ions of sodium, fluorine and chlorine.
- Contaminants in the form of atomic or elemental species may be metals, such as copper, aluminum or gold, which may be chemically bonded to the semiconductor surface, or silicon particles or metal debris from equipment used in the processes.
- Another well known problem of megasonic cleaning is that of cavitation, where bubbles in the megasonic fluid collapse on the surface of the semiconductor wafer and thereby impart energy to the surface of the semiconductor wafer. This energy may destroy delicate/fine structures on the surface or may destroy the surface itself when the bubbles repeatedly collapse at the same location on the surface. In addition to these problems, such conventional techniques may not be able to remove enough contaminants in the future. [0008] Another technology that may be used to clean semiconductor wafers involves using foam rather than a hard surface (brush scrubbing) or megasonic waves to contact the semiconductor surface.
- a semiconductor wafer 100 enclosed within an apparatus 102, has a foam 106 containing bubbles 108 and liquid introduced to the surface of the semiconductor wafer 100 through a port 104.
- the foam 106 decays and drains from the surface of the semiconductor wafer 100, the mass of bubbles 106 scrubs particles from the surface of the semiconductor waler 100.
- Such a foam process may be improved to provide cleaning to the extent necessary for current or future semiconductor processing.
- the instant disclosure provides an apparatus and method for effectively removing contaminants or otherwise treating the semiconductor wafer using an improved foam process involving a pressurized, or "jammed" foam.
- the apparatus includes a support configured to support the semiconductor wafer.
- a foam manifold is configured to introduce foam to the semiconductor wafer while the semiconductor wafer is supported by the support.
- a form provides pressure to the foam disposed on a surface of the semiconductor wafer to produce a jammed foam.
- An actuator effects relative movement between the form and the semiconductor wafer while the jammed foam is in contact with the surface of the semiconductor wafer to remove undesired particles from the surface of the semiconductor wafer.
- the form may include a platen disposed on the foam.
- the platen may have an area at least that of the semiconductor wafer such that the pressure is provided to the foam over the entire surface of the semiconductor wafer.
- the form may include a pressure structure that is smaller than the entire surface of the semiconductor wafer such that the pressure is provided to the foam in a local area over the surface of the semiconductor wafer.
- a pressure structure may be a mandrel or a wheel.
- the foam may include bubbles having a diameter of at most a largest linear dimension of the particles on the surface of the semiconductor wafer.
- the foam may have a density (the number of bubbles per unit volume) sufficient to permit the bubbles to be rearranged into a first energy state when pressure is applied rather than rupture, in which the first energy state is lower than a second energy state of the foam existing before the pressure was applied.
- the apparatus may be configured to provide an additional layer of jammed foam between the semiconductor wafer and the support.
- the foam may include a liquid and bubbles, the liquid containing a chemical providing a chemical treatment to the semiconductor wafer.
- the liquid may be configured to etch the semiconductor wafer or a layer disposed on the semiconductor wafer, the liquid may contain cleaning agents suitable to clean the semiconductor wafer, or the liquid may include at least one of HCl, ammonium hydroxide, SC1 (standard clean 1 - an ammonium hydroxide- hydrogen peroxide-water mixture typically 0.25:1:5), SC2 (standard clean 2 - a hydrochloric acid-hydrogen peroxide-water mixture typically 1:1:5), and HF.
- the foam may include bubbles that contain a reactive gas.
- the actuator may be configured to move the form while a position of the semiconductor wafer is maintained.
- the actuator may also be configured to vertically oscillate the form such that a distance between the form and the surface of the semiconductor wafer is varied, configured to laterally oscillate the form in the plane of the semiconductor wafer, configured to laterally oscillate the form in a plurality of non-parallel directions, configured to rotate the form, or configured to move the form in a plurality of non-parallel directions.
- the actuator may be configured to move the semiconductor wafer while a position of the form is maintained.
- the actuator may be configured to laterally oscillate the semiconductor wafer, configured to laterally oscillate the semiconductor wafer in a plurality of non-parallel directions, configured to rotate the semiconductor wafer, or configured to move the semiconductor wafer in a plurality of non-parallel directions.
- the apparatus may further include a container housing the support, the foam manifold, the form, and the actuator or may include a channel through which liquid resulting from collapse of the jammed foam is removed from the surface of the semiconductor wafer.
- the apparatus may further include a plurality of manifolds configured to introduce the foam to the semiconductor wafer, one or more manifolds configured to dry the semiconductor wafer after the semiconductor wafer has been subjected to the jammed foam, one or more manifolds configured to create the foam prior to the foam being supplied to the foam manifold, or one or more manifolds configured to dispense the foam to the foam manifold.
- Fig. 1 illustrates a view of a known foam apparatus.
- FIG. 2 shows a view of a cleaning apparatus according to a first aspect of the present invention.
- FIGs. 3A and 3B show views of the bubbles before and after rearrangement in an aspect of the present invention.
- FIG. 4 shows a view of a cleaning apparatus according to a second aspect of the present invention.
- FIG. 5 shows a view of a cleaning apparatus according to a third aspect of the present invention.
- FIG. 6 shows a view of a cleaning apparatus according to a fourth aspect of the present invention.
- FIG. 7 shows a view of a cleaning apparatus according to a fifth aspect of the present invention.
- FIG. 8 shows a view of a cleaning apparatus according to a sixth aspect of the present invention.
- foam-based cleaning system is capable of removing more particles than it generates, unlike other systems whose particle count may increase in successive processing steps.
- the process of creating a foam is relatively simple: a suitable liquid is transformed into foam by mixing a gas with the liquid.
- a suitable liquid is one in which the desired foam can be produced and provides the desired chemical treatment to the semiconductor wafer as the liquid phase of the foam is substantially identical to the original liquid used to create the foam.
- Foam can be produced by mixing of non-soluble gases, like air, or by decompression of solutions containing soluble gases into the liquid. In either case, energy is added to the mixture to form the foam.
- Foams are in a metastable state when generated. This means that immediately following production, the foam starts to decay, thereby essentially reproducing the gas and the original liquid. This decay process is called draining.
- the rate of draining, called the drain time varies depending on the foam. For example, the drain time for foams having the consistency of shaving cream may be hours while that of foams having the consistency of shampoo may be minutes or less.
- the drain time can be controlled by altering the type of liquid composing the foam and the density of the foam, for example, as desired to aid in the treatment of the semiconductor wafer.
- the foam may be created or stored in a pressurized environment. Once released from this pressurized environment, e.g. from a storage facility through a manifold, the foam expands in volume. When applied through the manifold to the semiconductor wafer, such a foam reduces the volume of reactants and solvents in the liquid that contact the semiconductor wafer. However, the foam also reduces the exposure of the semiconductor wafer to contaminants in the conduits through which the foam has been transferred to the semiconductor wafer as less material passes through the conduits. Foams also exhibit thixotropic flow properties, and thus flow best under shear. Some foams, such as those having properties similar to shaving cream, spread easily under high shear but remain substantially stationary when the shear force is removed.
- an agent that reduces surface tension such as soaps, detergents, isopropyl alcohol, nitrous oxide, isobufane, or carbon dioxide may also be added to the liquid when forming the foam.
- an agent that reduces surface tension such as soaps, detergents, isopropyl alcohol, nitrous oxide, isobufane, or carbon dioxide may also be added to the liquid when forming the foam.
- the temperature of the liquid used can be adjusted to optimize foaming behavior.
- the drain time of a suitable foam may be less than one or two minutes. Accordingly, it is possible to use relatively fast-draining foams. In fact the use of somewhat fast-draining foams may be desirable in that few, if any, additional such foams avoid the need for additional measures to remove it.
- the technique suggested to clean the semiconductor wafer has been to immerse the semiconductor wafer in the foam or otherwise allow the foam to move over the surface of the substrate through decay and drainage. Decompression of the foam during the drainage transfers energy to the surface of the semiconductor wafer as the bubbles collapse. However, this technique releases too little energy when the foam bubble collapses to remove the contamination from the surface of the semiconductor wafer.
- the embodiment of the present invention illustrated in Fig. 2 uses a so-called “jammed” foam to clean or otherwise treat the semiconductor wafer.
- the semiconductor wafer 10 is disposed between two platens 12, 14 and foam 16 is disposed on one or both sides of the semiconductor wafer 10 (as shown in the figure, on both sides). Any of a number of types of semiconductor wafers may be treated using the embodiments of the present invention, for example, silicon or other group IV substrates or III-V or ll-VI compound semiconductor substrates.
- the bottom platen 14 provides a support on which the semiconductor wafer 10 is disposed, whether foam exists or not.
- the foam 16 is disposed over substantially the entire surface of the semiconductor wafer 10 on which it is present.
- the foam can be applied and spread on by any appropriate means such as one or more manifolds. As shown, uniform pressure is applied to the foam 16 through the top platen 12 and perhaps bottom platen 14. This pressure creates a jammed foam 16 that transfers energy to the semiconductor wafer 10 primarily through the rearrangement of the bubbles in the foam 16, rather than primarily through the collapse of the bubbles.
- the manner in which this is believed to occur is: as the pressure increases, the foam first enters a metastable high energy state in which no rearrangement occurs and then, at a critical stress level, the foam relaxes into a low energy state in which the energy is released not by the bubbles rupturing, but by rearranging the bubbles.
- the foam layer gets thinner and thinner until it reaches a minimum thickness.
- the minimum thickness is dependent on the liquid and gas components used, however as typically bubbles 10-50 ⁇ m in diameter may be used to treat the semiconductor surface, the layer thickness may not be less than the bubble diameter.
- the density of the foam is too small, gravity will pull the bubbles apart and rupture the bubbles before they reach the interface and are able to be rearranged.
- providing a foam with smaller bubbles may enhance the treatment efficiency by increasing the number of bubbles being rearranged at the interface.
- the upper surface of the semiconductor wafer 10 contains the patterned structures that require cleaning or other chemical treatment.
- the bottom platen 14 may be removed and replaced with a fixed support structure that merely supports the semiconductor wafer 10 and does not provide pressure to the semiconductor wafer 10.
- the foam 16 may not be disposed on the lower surface of the semiconductor wafer 10.
- the supporting surface may be stationary or moving, similar to a conveyer belt.
- the platen meanwhile, can be formed using any suitable material that is strong enough to withstand energy transferred to the platen by the repeated exposure to the collapsing bubbles.
- FIG. 2A A typical rearrangement is illustrated in Figs. 2A and 2B.
- Fig. 2B A typical rearrangement is illustrated in Figs. 2A and 2B.
- the foam 16 is disposed on the surface of the semiconductor wafer 10 without pressure being applied.
- Figure 2B shows the rearrangement of the foam 16 as pressure is applied (the platen or other pressing structure is not shown in this figure).
- energy is released when the foam 16 proceeds from a higher-energy, more disordered state, to a lower energy, more ordered state.
- the spherical nature of the bubbles shown in the figures tends to induce the foam to rearrange in a hexagonal close-packed structure.
- the foam may be removed (or rinsed off) using Dl water or may also require an additional liquid chemical rinse before the Dl water rinse, for example.
- the remaining Dl water may then be removed in a controlled manner by applying nitrogen or other inert gasses to the semiconductor wafer surface.
- An uncontrolled drying process i.e. permitting the semiconductor wafer to dry without removing the foam, can leave the contaminants removed by the foam or unwanted residue and chemicals of the foam itself. Further processing can then take place, and, if desired a new foam may be later introduced onto the surface of the semiconductor wafer.
- the new foam may have the same or a different chemistry as the original foam as appropriate.
- the foam is generally not recycled after it has been used as it contains contaminants and resultants of reactions with the surface of the semiconductor wafer.
- the semiconductor wafer 20 and foam 26 is disposed between one or more forms 22, 24.
- pressure is applied to the foam 26 only over a small portion of the surface of the semiconductor wafer 20 through the forms 22, 24.
- the forms 22, 24 of this embodiment do not cover substantially the entirety of the surface of the semiconductor wafer 20 to which they are opposed. Similar to the previous embodiment, only one form may be applied to the semiconductor wafer 20.
- This single form as the single platen, is disposed over the upper surface of the semiconductor wafer 20, where the patterns that require cleaning or other treatment are present.
- multiple forms may be disposed on one surface of the semiconductor wafer 20.
- the foam 26 in the embodiment of Fig.4 may or may not be disposed over the entirety of the surface of the semiconductor wafer 20. In the latter case, the foam 26 may be disposed over only that portion of the semiconductor wafer 20 that requires cleaning or treatment.
- the forms 22, 24 may be moved across the surface of the semiconductor wafer 20 at least once or back and forth.
- the forms may be moved across the surface(s) of the semiconductor wafer in unison or separately, as desired.
- the forms 22, 24 may be mandrels, rollers, wheels, or any other pressure structure that covers only a portion of the semiconductor wafer 20.
- the forms may be flat or curved.
- curved forms may also be easier to implement than flat forms.
- the time needed to clean or treat the semiconductor surface may make an impact on whether the form is flat or not. In this case, if only a short time is needed, a narrow line of contact with high pressure can be used and thus the form can roll along the foam. Conversely, if a long time is required, flat surface is probably better.
- the drain time is relatively fast, any reactant contained within the foam will be applied to the semiconductor wafer as a liquid.
- FIG. 5 illustrates one manner in which the foam 38 is formed and moved.
- the platen 32 has multiple holes 34, 36 formed that extend through the platen 32.
- the foam 38 is introduced to the surface of the semiconductor 30 and through at least another of these holes 36, the foam 38 exits from the semiconductor surface 30.
- the foam 38 may be deposited from the entrance hole 34 towards the exit hole 36 through drainage or, as shown, through the use of a non-reactive gas such as nitrogen. The nitrogen may push the foam 38 that is located on the surface of the semiconductor wafer 30 towards the exit hole 36.
- the movement of the foam 38 along with the rearrangement caused by the applied pressure cleans or treats the semiconductor surface 30.
- a vacuum or other pressure differential may be applied to the exit hole 36 to force the foam 34 or liquid from the decompressed foam to exit from the semiconductor surface 30.
- the holes 34, 36 may be positioned at any point along the platen 32, but are preferably disposed such that the foam is supplied over the entire surface of the semiconductor surface 30. Liquid is supplied through the entrance hole 34 and aerated by a gas (as shown O 3 ) to form the foam 38.
- FIG. 6 illustrates an embodiment in which the foam is present on both sides of the semiconductor wafer (although the foam on the upper surface and pressure structure are not shown).
- Foam 46 is introduced to the platen 42 (or other support) prior to the semiconductor wafer 40 being disposed on the foam 46.
- the semiconductor wafer 40 is then placed on three or more stands 44 of the support 42.
- the stands 44 are identical in size and shape and extend from the support 42 through the foam 46.
- the stands 44 may be retracted into the support 42 so that the semiconductor wafer 40 lies on the foam 46.
- An additional layer of foam may be applied to the opposing surface of the semiconductor wafer before or after the stands are retracted. After the foam is injected, the semiconductor wafer 40 may then be treated.
- FIG. 7 illustrates another embodiment of the present invention.
- the foam 56 may be disposed on both opposing surfaces of the semiconductor wafer 50 or multiple pressure mechanisms may be used, for simplicity, the foam 56 is shown as being disposed on only one surface of the semiconductor wafer 50 and a platen 52 to which pressure is applied is disposed on the foam 56.
- foams flow best under shear.
- the platen 52 or platen 52 and semiconductor wafer 50 may be moved the increase the effectiveness of the foam 56 on the semiconductor wafer 50.
- the semiconductor wafer 50 and platen 52 can be translated in one or more directions, laterally (i.e. in the plane of the semiconductor) or vertically, with respect to each other.
- the foam 56 can be compressed and expanded by vertical movement, i.e. the semiconductor wafer 50 and platen 52 can be moved towards or away from each other.
- the foam 56 can be sheared by lateral movement, i.e. the semiconductor wafer 50 and platen 52 can be moved to adjust the overlap between the two. This movement is preferably repeated, i.e. the semiconductor wafer 50 and platen 52 are oscillated in one or more directions to induce more efficient treatment.
- the semiconductor wafer 50 and/or platen 52 may be rotated to effect movement rather than the positions of the two being adjusted relative to each other.
- oscillation may give better processing results.
- the semiconductor wafer location may remain constant and the form moved, the form location may remain constant and the semiconductor wafer moved, or both the semiconductor wafer and the form may be simultaneously or sequentially moved.
- the foam is comprised of a liquid and gas- filied bubbles.
- the foam can be a delivery medium for other materials as well as being useful themselves due to rearrangement. Besides merely applying energy to and cleaning the surface of the semiconductor wafer, other chemistries may be present in the foam.
- the foam can be formed from treatment fluids used in conventional semiconductor processes to enhance the process.
- treatment fluids include HCl, ammonium hydroxide , SC1, SC2, HF for stripping and undercutting oxide present on the surface of the semiconductor wafer to remove particles embedded in oxide, nitric acid, ammonium hydroxide and hydrogen peroxide.
- Other fluids may be used that aid in the cleaning of the surface. For example, when using a fluid with a high ph, with a negatively charged semiconductor surface, a particle that is positively charged and attached to surface, once removed by foam, becomes negatively charged, thereby inhibiting readhesion of the particle.
- the a reactive gas may be used to form the foam rather than an inert gas such as nitrogen, argon, air, or carbon dioxide.
- an inert gas such as nitrogen, argon, air, or carbon dioxide.
- Figure 8 shows one embodiment of an apparatus using the foam treatment process.
- the semiconductor wafer 60 is supported by a support 62.
- the containment system 64 may have one or more chambers through which the semiconductor wafer 60 passes (only one is shown in the drawing). Multiple manifolds are present. At least one manifold creates the foam as shown in Fig. 4 for example. At least one manifold 67 introduces or dispenses the foam 66 to the semiconductor wafer 60. Gas and liquid supply lines (with appropriate valves) provide the ingredients for producing foam to the manifold.
- One or more manifolds 68 rinse the semiconductor wafer 60 in Dl water after the foam 66 has been applied and the form 65 has acted on the foam.
- one or more manifolds dry the semiconductor wafer 60.
- the same or different manifolds may distribute different foams, which are then pressurized to apply a jammed foam to the semiconductor.
- a drying process that uses foam can also be used. In such a process, a carbon dioxide gas/DI water mixture may provide the desired foam.
- the cleaning, chemical treatment and drying can take place either in the same or different chambers. Normally, the cleaning and chemical processing steps take place sequentially without any intermediate drying steps, and drying is carried out only as a final step when the semiconductor wafers are to be removed from the system. However, the cleaning and chemical treatment may be carried out alternately with drying in the same chamber.
Abstract
Description
Claims
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2006547238A JP4511555B2 (en) | 2003-12-23 | 2004-12-17 | Method and apparatus for cleaning semiconductor wafers using compressed and / or pressurized foams, bubbles and / or liquids |
EP04814960A EP1704584A1 (en) | 2003-12-23 | 2004-12-17 | Method and apparatus for cleaning semiconductor wafers using compressed and/or pressurized foams, bubbles, and/or liquids |
KR1020067012587A KR101122377B1 (en) | 2003-12-23 | 2004-12-17 | Method and apparatus for cleaning semiconductor wafers using compressed and/or pressurized foam, bubbles, and/or liquids |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
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US10/746,114 | 2003-12-23 | ||
US10/746,114 US7568490B2 (en) | 2003-12-23 | 2003-12-23 | Method and apparatus for cleaning semiconductor wafers using compressed and/or pressurized foams, bubbles, and/or liquids |
Publications (1)
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WO2005064647A1 true WO2005064647A1 (en) | 2005-07-14 |
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PCT/US2004/042831 WO2005064647A1 (en) | 2003-12-23 | 2004-12-17 | Method and apparatus for cleaning semiconductor wafers using compressed and/or pressurized foams, bubbles, and/or liquids |
Country Status (8)
Country | Link |
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US (4) | US7568490B2 (en) |
EP (1) | EP1704584A1 (en) |
JP (1) | JP4511555B2 (en) |
KR (1) | KR101122377B1 (en) |
CN (2) | CN100421210C (en) |
MY (2) | MY140370A (en) |
TW (1) | TWI397103B (en) |
WO (1) | WO2005064647A1 (en) |
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US20090078282A1 (en) | 2009-03-26 |
US7568490B2 (en) | 2009-08-04 |
EP1704584A1 (en) | 2006-09-27 |
MY144394A (en) | 2011-09-15 |
TW200527487A (en) | 2005-08-16 |
CN1898776B (en) | 2011-04-20 |
CN1898775A (en) | 2007-01-17 |
JP2007517401A (en) | 2007-06-28 |
US7625452B2 (en) | 2009-12-01 |
MY140370A (en) | 2009-12-31 |
US20050133061A1 (en) | 2005-06-23 |
TWI397103B (en) | 2013-05-21 |
CN1898776A (en) | 2007-01-17 |
US20090000044A1 (en) | 2009-01-01 |
JP4511555B2 (en) | 2010-07-28 |
CN100421210C (en) | 2008-09-24 |
KR20060110335A (en) | 2006-10-24 |
US8535451B2 (en) | 2013-09-17 |
US20050133060A1 (en) | 2005-06-23 |
US7441299B2 (en) | 2008-10-28 |
KR101122377B1 (en) | 2012-03-27 |
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