WO2005068519A3 - Catalyst compositions and polyolefins for extrusion coating applications - Google Patents

Catalyst compositions and polyolefins for extrusion coating applications Download PDF

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Publication number
WO2005068519A3
WO2005068519A3 PCT/US2005/000278 US2005000278W WO2005068519A3 WO 2005068519 A3 WO2005068519 A3 WO 2005068519A3 US 2005000278 W US2005000278 W US 2005000278W WO 2005068519 A3 WO2005068519 A3 WO 2005068519A3
Authority
WO
WIPO (PCT)
Prior art keywords
catalyst compositions
polyolefins
extrusion coating
coating applications
polymerization
Prior art date
Application number
PCT/US2005/000278
Other languages
French (fr)
Other versions
WO2005068519A2 (en
Inventor
Michael D Jensen
Max P Mcdaniel
Joel L Martin
Elizabeth A Benham
Randy Muninger
Gary Jerdee
Ashish M Sukhadia
Qing Yang
Matthew Thorn
Original Assignee
Chevron Phillips Chemical Co
Michael D Jensen
Max P Mcdaniel
Joel L Martin
Elizabeth A Benham
Randy Muninger
Gary Jerdee
Ashish M Sukhadia
Qing Yang
Matthew Thorn
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to ES05711277T priority Critical patent/ES2395403T3/en
Priority to JP2006549378A priority patent/JP5279188B2/en
Priority to AU2005205527A priority patent/AU2005205527B2/en
Priority to IN2629DEN2012 priority patent/IN2012DN02629A/en
Application filed by Chevron Phillips Chemical Co, Michael D Jensen, Max P Mcdaniel, Joel L Martin, Elizabeth A Benham, Randy Muninger, Gary Jerdee, Ashish M Sukhadia, Qing Yang, Matthew Thorn filed Critical Chevron Phillips Chemical Co
Priority to AT05711277T priority patent/ATE521643T1/en
Priority to CN2005800057494A priority patent/CN1922220B/en
Priority to BRPI0506769-3A priority patent/BRPI0506769B1/en
Priority to CA2552748A priority patent/CA2552748C/en
Priority to EP05711277A priority patent/EP1711543B1/en
Publication of WO2005068519A2 publication Critical patent/WO2005068519A2/en
Publication of WO2005068519A3 publication Critical patent/WO2005068519A3/en
Priority to EGPCTNA2006001295DA priority patent/EG26509A/en
Priority to EGNA2006000637 priority patent/EG25354A/en
Priority to HK07103955.0A priority patent/HK1097411A1/en
Priority to AU2010241413A priority patent/AU2010241413B2/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
    • C08F2410/07—Catalyst support treated by an anion, e.g. Cl-, F-, SO42-
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/04—Broad molecular weight distribution, i.e. Mw/Mn > 6
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/09—Long chain branches
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/941—Synthetic resins or natural rubbers -- part of the class 520 series having the transition metal bonded directly to carbon
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2913—Rod, strand, filament or fiber
    • Y10T428/2933—Coated or with bond, impregnation or core
    • Y10T428/2971—Impregnation

Abstract

This invention relates to the field of olefin polymerization catalyst compositions, and methods for the polymerization and copolymerization of olefins, including polymerization methods using a supported catalyst composition. In one aspect, the present invention encompasses a catalyst composition comprising the contact product of a first metallocene compound, a second metallocene compound, at least one chemically-treated solid oxide, and at least one organoaluminum compound. The new resins were characterized by useful properties in impact, tear, adhesion, sealing, extruder motor loads and pressures at comparable melt index values, and neck-in and draw-down.
PCT/US2005/000278 2004-01-09 2005-01-06 Catalyst compositions and polyolefins for extrusion coating applications WO2005068519A2 (en)

Priority Applications (13)

Application Number Priority Date Filing Date Title
CN2005800057494A CN1922220B (en) 2004-01-09 2005-01-06 Catalyst compositions and polyolefins for extrusion coating applications
AU2005205527A AU2005205527B2 (en) 2004-01-09 2005-01-06 Catalyst compositions and polyolefins for extrusion coating applications
IN2629DEN2012 IN2012DN02629A (en) 2004-01-09 2005-01-06
CA2552748A CA2552748C (en) 2004-01-09 2005-01-06 Catalyst compositions and polyolefins for extrusion coating applications
AT05711277T ATE521643T1 (en) 2004-01-09 2005-01-06 CATALYST COMPOSITIONS AND POLYOLEFINS FOR EXTRUSION COATING APPLICATIONS
JP2006549378A JP5279188B2 (en) 2004-01-09 2005-01-06 Polyolefins for catalyst compositions and extrusion coating applications
BRPI0506769-3A BRPI0506769B1 (en) 2004-01-09 2005-01-06 Olefin polymerization catalyst composition and matter composition
ES05711277T ES2395403T3 (en) 2004-01-09 2005-01-06 Catalyst and polyolefin compositions for extrusion coating applications
EP05711277A EP1711543B1 (en) 2004-01-09 2005-01-06 Catalyst compositions and polyolefins for extrusion coating applications
EGPCTNA2006001295DA EG26509A (en) 2004-01-09 2006-07-04 Ethylene polymer
EGNA2006000637 EG25354A (en) 2004-01-09 2006-07-04 Catalyst compositions and polyolefins for extrusion coating applications.
HK07103955.0A HK1097411A1 (en) 2004-01-09 2007-04-16 Catalyst compositions and polyolefins for extrusion coating applications
AU2010241413A AU2010241413B2 (en) 2004-01-09 2010-11-12 Catalyst compositions and polyolefins for extrusion coating applications

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US10/755,083 2004-01-09
US10/755,083 US7041617B2 (en) 2004-01-09 2004-01-09 Catalyst compositions and polyolefins for extrusion coating applications

Publications (2)

Publication Number Publication Date
WO2005068519A2 WO2005068519A2 (en) 2005-07-28
WO2005068519A3 true WO2005068519A3 (en) 2005-12-01

Family

ID=34739505

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2005/000278 WO2005068519A2 (en) 2004-01-09 2005-01-06 Catalyst compositions and polyolefins for extrusion coating applications

Country Status (15)

Country Link
US (5) US7041617B2 (en)
EP (2) EP2380919B1 (en)
JP (2) JP5279188B2 (en)
CN (2) CN1922220B (en)
AT (1) ATE521643T1 (en)
AU (2) AU2005205527B2 (en)
BR (1) BRPI0506769B1 (en)
CA (2) CA2552748C (en)
EG (2) EG26509A (en)
ES (2) ES2395403T3 (en)
HK (2) HK1097411A1 (en)
IN (1) IN2012DN02629A (en)
RU (1) RU2374272C2 (en)
SG (1) SG134332A1 (en)
WO (1) WO2005068519A2 (en)

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