WO2005090427A3 - Catalyst composition comprising shuttling agent for ethylene multi-block copolymer formation - Google Patents

Catalyst composition comprising shuttling agent for ethylene multi-block copolymer formation Download PDF

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Publication number
WO2005090427A3
WO2005090427A3 PCT/US2005/008917 US2005008917W WO2005090427A3 WO 2005090427 A3 WO2005090427 A3 WO 2005090427A3 US 2005008917 W US2005008917 W US 2005008917W WO 2005090427 A3 WO2005090427 A3 WO 2005090427A3
Authority
WO
WIPO (PCT)
Prior art keywords
block copolymer
shuttling agent
catalyst composition
copolymer formation
ethylene multi
Prior art date
Application number
PCT/US2005/008917
Other languages
French (fr)
Other versions
WO2005090427A2 (en
Inventor
Daniel J Arriola
Edmund M Carnahan
Yunwa W Cheung
David D Devore
David D Graf
Phillip D Hustad
Roger L Kuhlman
Pi Shan Colin Li
Benjamin C Poon
Gordon R Roof
James C Stevens
Pamela J Stirn
Timothy T Wenzel
Original Assignee
Dow Global Technologies Inc
Daniel J Arriola
Edmund M Carnahan
Yunwa W Cheung
David D Devore
David D Graf
Phillip D Hustad
Roger L Kuhlman
Pi Shan Colin Li
Benjamin C Poon
Gordon R Roof
James C Stevens
Pamela J Stirn
Timothy T Wenzel
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Global Technologies Inc, Daniel J Arriola, Edmund M Carnahan, Yunwa W Cheung, David D Devore, David D Graf, Phillip D Hustad, Roger L Kuhlman, Pi Shan Colin Li, Benjamin C Poon, Gordon R Roof, James C Stevens, Pamela J Stirn, Timothy T Wenzel filed Critical Dow Global Technologies Inc
Priority to AT05730993T priority Critical patent/ATE461231T1/en
Priority to US11/376,956 priority patent/US7714071B2/en
Priority to AU2005224259A priority patent/AU2005224259B2/en
Priority to BRPI0508148-3A priority patent/BRPI0508148B1/en
Priority to US10/589,377 priority patent/US7858706B2/en
Priority to JP2007504111A priority patent/JP5133050B2/en
Priority to EP14176345.8A priority patent/EP2792690B1/en
Priority to CA2559576A priority patent/CA2559576C/en
Priority to DE602005019988T priority patent/DE602005019988D1/en
Priority to NZ549261A priority patent/NZ549261A/en
Priority to PCT/US2005/008917 priority patent/WO2005090427A2/en
Priority to CN2005800148192A priority patent/CN1976965B/en
Priority to EP05730993A priority patent/EP1727841B1/en
Publication of WO2005090427A2 publication Critical patent/WO2005090427A2/en
Publication of WO2005090427A3 publication Critical patent/WO2005090427A3/en
Priority to CN2006800084231A priority patent/CN101356207B/en
Priority to TW095108734A priority patent/TWI388574B/en
Priority to US11/376,863 priority patent/US7897689B2/en
Priority to BRPI0609839-8A priority patent/BRPI0609839B1/en
Priority to CN2006800083737A priority patent/CN101277987B/en
Priority to CA002601245A priority patent/CA2601245A1/en
Priority to PCT/US2006/009407 priority patent/WO2006101929A2/en
Priority to MX2007011343A priority patent/MX2007011343A/en
Priority to AT06738470T priority patent/ATE449802T1/en
Priority to TW095108754A priority patent/TWI394760B/en
Priority to BRPI0609837-1A priority patent/BRPI0609837A2/en
Priority to CA002601241A priority patent/CA2601241A1/en
Priority to ARP060101002A priority patent/AR055045A1/en
Priority to JP2008502120A priority patent/JP4975730B2/en
Priority to ZA200707867A priority patent/ZA200707867B/en
Priority to JP2008502122A priority patent/JP4881370B2/en
Priority to MYPI20061148A priority patent/MY148607A/en
Priority to TW095108735A priority patent/TWI378107B/en
Priority to US11/376,971 priority patent/US7582716B2/en
Priority to ZA200707866A priority patent/ZA200707866B/en
Priority to KR1020077021220A priority patent/KR101319124B1/en
Priority to JP2008502123A priority patent/JP5231988B2/en
Priority to ZA200707875A priority patent/ZA200707875B/en
Priority to JP2008502017A priority patent/JP5227785B2/en
Priority to CA002601248A priority patent/CA2601248A1/en
Priority to KR1020077021178A priority patent/KR101319131B1/en
Priority to AU2006227665A priority patent/AU2006227665B2/en
Priority to BRPI0609852-5A priority patent/BRPI0609852B1/en
Priority to JP2008502020A priority patent/JP2008545066A/en
Priority to EP06748394.1A priority patent/EP1858962B1/en
Priority to TW095108758A priority patent/TW200635961A/en
Priority to AU2006227663A priority patent/AU2006227663A1/en
Priority to MX2007011341A priority patent/MX2007011341A/en
Priority to JP2008502124A priority patent/JP5107889B2/en
Priority to ES06738857.9T priority patent/ES2673179T3/en
Priority to JP2008502023A priority patent/JP5214434B2/en
Priority to ES06738470T priority patent/ES2337395T3/en
Priority to DE602006021560T priority patent/DE602006021560D1/en
Priority to DE602006010682T priority patent/DE602006010682D1/en
Priority to ARP060101016A priority patent/AR056640A1/en
Priority to CA002601337A priority patent/CA2601337A1/en
Priority to PCT/US2006/009406 priority patent/WO2006101928A2/en
Priority to BRPI0609842-8A priority patent/BRPI0609842B1/en
Priority to RU2007134344/04A priority patent/RU2007134344A/en
Priority to BRPI0609850-9A priority patent/BRPI0609850B1/en
Priority to US11/376,774 priority patent/US7687442B2/en
Priority to CN2006800083826A priority patent/CN101578307B/en
Priority to EP06738468A priority patent/EP1858943B1/en
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Priority to CN2006800084087A priority patent/CN101365733B/en
Priority to JP2008502015A priority patent/JP5231984B2/en
Priority to TW095108753A priority patent/TWI375683B/en
Priority to ARP060101008A priority patent/AR055879A1/en
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Priority to KR1020077021185A priority patent/KR101425227B1/en
Priority to RU2007134342/05A priority patent/RU2408622C2/en
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Priority to TW095108766A priority patent/TWI375685B/en
Priority to TW095108749A priority patent/TWI375682B/en
Priority to PCT/US2006/009591 priority patent/WO2006102016A2/en
Priority to EP06738466.9A priority patent/EP1861441B1/en
Priority to CN2006800083807A priority patent/CN101305027B/en
Priority to TW095108730A priority patent/TWI377214B/en
Priority to US11/376,833 priority patent/US7741397B2/en
Priority to RU2007134417/04A priority patent/RU2007134417A/en
Priority to ZA200707871A priority patent/ZA200707871B/en
Priority to BRPI0609829-0A priority patent/BRPI0609829B1/en
Priority to AU2006227344A priority patent/AU2006227344A1/en
Priority to AT06738548T priority patent/ATE507251T1/en
Priority to BR122016029989A priority patent/BR122016029989B1/en
Priority to BR122017012540-0A priority patent/BR122017012540B1/en
Priority to AU2006227669A priority patent/AU2006227669B2/en
Priority to EP06738467A priority patent/EP1871931B1/en
Priority to EP06738860.3A priority patent/EP1871817B1/en
Priority to JP2008502021A priority patent/JP5221334B2/en
Priority to EP11178905.3A priority patent/EP2392611B1/en
Priority to EP06739033.6A priority patent/EP1861454B1/en
Priority to ZA200707869A priority patent/ZA200707869B/en
Priority to US11/376,980 priority patent/US7666918B2/en
Priority to RU2007134424/04A priority patent/RU2007134424A/en
Priority to RU2007134346/04A priority patent/RU2007134346A/en
Priority to RU2007134343/04A priority patent/RU2007134343A/en
Priority to CA002601286A priority patent/CA2601286A1/en
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Priority to TW095108729A priority patent/TW200643164A/en
Priority to CN200680008379.4A priority patent/CN101351582B/en
Priority to US11/908,948 priority patent/US8084537B2/en
Priority to CN200680008430.1A priority patent/CN101553512B/en
Priority to RU2007134347/04A priority patent/RU2007134347A/en
Priority to KR1020077021186A priority patent/KR101286896B1/en
Priority to KR1020077021161A priority patent/KR101315567B1/en
Priority to EP06748405A priority patent/EP1716190B1/en
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Priority to TW095108733A priority patent/TW200643044A/en
Priority to AU2006227352A priority patent/AU2006227352A1/en
Priority to ARP060101017A priority patent/AR053830A1/en
Priority to PCT/US2006/009411 priority patent/WO2006101932A2/en
Priority to CA002601296A priority patent/CA2601296A1/en
Priority to CA002601376A priority patent/CA2601376A1/en
Priority to RU2007134419/04A priority patent/RU2007134419A/en
Priority to JP2008502056A priority patent/JP5231985B2/en
Priority to ZA200707879A priority patent/ZA200707879B/en
Priority to MX2007011324A priority patent/MX2007011324A/en
Priority to ZA200707872A priority patent/ZA200707872B/en
Priority to PCT/US2006/009852 priority patent/WO2006102150A2/en
Priority to AU2006227668A priority patent/AU2006227668A1/en
Priority to MX2007011386A priority patent/MX2007011386A/en
Priority to KR1020077021049A priority patent/KR101413315B1/en
Priority to ZA200707883A priority patent/ZA200707883B/en
Priority to US11/908,949 priority patent/US7947367B2/en
Priority to AU2006225106A priority patent/AU2006225106A1/en
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Priority to ZA200707874A priority patent/ZA200707874B/en
Priority to PCT/US2006/009408 priority patent/WO2006101930A2/en
Priority to BRPI0609841-0A priority patent/BRPI0609841B1/en
Priority to KR1020137013544A priority patent/KR101506824B1/en
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Priority to ARP060101001A priority patent/AR055044A1/en
Priority to BRPI0609825-8A priority patent/BRPI0609825B1/en
Priority to EP06738855.3A priority patent/EP1858945B1/en
Priority to RU2007134425/04A priority patent/RU2007134425A/en
Priority to BR122017015865-1A priority patent/BR122017015865B1/en
Priority to EP06748414.7A priority patent/EP1858937B1/en
Priority to PCT/US2006/009501 priority patent/WO2006113000A2/en
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Priority to MYPI20061138A priority patent/MY142049A/en
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Priority to CN200680008425.0A priority patent/CN101296957A/en
Priority to CN200680008351.0A priority patent/CN101360769B/en
Priority to PCT/US2006/009404 priority patent/WO2006101926A2/en
Priority to DE602006019556T priority patent/DE602006019556D1/en
Priority to US11/378,657 priority patent/US7795321B2/en
Priority to AU2006227349A priority patent/AU2006227349A1/en
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Priority to RU2007134422/04A priority patent/RU2007134422A/en
Priority to US11/377,046 priority patent/US7622529B2/en
Priority to MX2007011321A priority patent/MX2007011321A/en
Priority to EP06738854A priority patent/EP1859083B1/en
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Priority to US11/908,950 priority patent/US7989543B2/en
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Priority to DE602006021550T priority patent/DE602006021550D1/en
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Priority to JP2008502012A priority patent/JP5199064B2/en
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Priority to PCT/US2006/009559 priority patent/WO2006101999A2/en
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Priority to SG201001861-2A priority patent/SG160416A1/en
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Priority to CN2006800084142A priority patent/CN101346498B/en
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Priority to CN2006800083455A priority patent/CN101313015B/en
Priority to US11/377,007 priority patent/US7671106B2/en
Priority to BRPI0609812-6A priority patent/BRPI0609812B1/en
Priority to ARP060101011A priority patent/AR055049A1/en
Priority to TW095108768A priority patent/TWI375686B/en
Priority to CA002601273A priority patent/CA2601273A1/en
Priority to CA002601265A priority patent/CA2601265A1/en
Priority to ARP060101006A priority patent/AR055046A1/en
Priority to ZA200707885A priority patent/ZA200707885B/en
Priority to ARP060101015A priority patent/AR056281A1/en
Priority to EP06738464.4A priority patent/EP1858942B1/en
Priority to CA002601263A priority patent/CA2601263A1/en
Priority to EP06738859.5A priority patent/EP1871816B1/en
Priority to CN2006800084157A priority patent/CN101291964B/en
Priority to CA002601293A priority patent/CA2601293A1/en
Priority to AU2006227347A priority patent/AU2006227347A1/en
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Priority to US11/376,834 priority patent/US7662881B2/en
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Priority to US11/377,725 priority patent/US7504347B2/en
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Priority to TW095108750A priority patent/TW200641115A/en
Priority to US11/908,953 priority patent/US7737061B2/en
Priority to CN200680008352.5A priority patent/CN101321853A/en
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Priority to TW095109165A priority patent/TW200635962A/en
Priority to TW095109167A priority patent/TWI429706B/en
Priority to ZA2006/07170A priority patent/ZA200607170B/en
Priority to NO20064122A priority patent/NO20064122L/en
Priority to KR1020067019103A priority patent/KR101266331B1/en
Priority to US11/686,444 priority patent/US8273838B2/en
Priority to ZA200707870A priority patent/ZA200707870B/en
Priority to HK07105169.7A priority patent/HK1098771A1/en
Priority to US12/032,474 priority patent/US7732052B2/en
Priority to US12/509,017 priority patent/US7842770B2/en
Priority to US12/558,234 priority patent/US7893166B2/en
Priority to US12/838,876 priority patent/US8067319B2/en
Priority to US12/962,822 priority patent/US8198374B2/en
Priority to US12/962,800 priority patent/US8785551B2/en
Priority to US13/031,406 priority patent/US8211982B2/en
Priority to US13/031,339 priority patent/US8318864B2/en
Priority to US13/562,600 priority patent/US8710143B2/en
Priority to JP2012184235A priority patent/JP5859401B2/en
Priority to JP2012184616A priority patent/JP5859931B2/en
Priority to JP2012184596A priority patent/JP5859402B2/en
Priority to JP2012185567A priority patent/JP5859403B2/en
Priority to JP2012184827A priority patent/JP5863601B2/en
Priority to JP2012185699A priority patent/JP5860363B2/en
Priority to JP2012190893A priority patent/JP5860367B2/en
Priority to JP2012242081A priority patent/JP5425290B2/en
Priority to JP2012241746A priority patent/JP5619107B2/en
Priority to US13/683,596 priority patent/US8609779B2/en
Priority to JP2013058369A priority patent/JP5798587B2/en
Priority to US14/156,692 priority patent/US9352537B2/en
Priority to US14/278,472 priority patent/US9243090B2/en

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/32Layered products comprising a layer of synthetic resin comprising polyolefins
    • B32B27/327Layered products comprising a layer of synthetic resin comprising polyolefins comprising polyolefins obtained by a metallocene or single-site catalyst
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/32Layered products comprising a layer of synthetic resin comprising polyolefins
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
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    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/31504Composite [nonstructural laminate]
    • Y10T428/31551Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
    • Y10T428/31573Next to addition polymer of ethylenically unsaturated monomer
    • Y10T428/31587Hydrocarbon polymer [polyethylene, polybutadiene, etc.]

Abstract

A composition for use in forming a multi-block copolymer, said copolymer containing therein two or more segments or blocks differing in chemical or physical properties, a polymerization process using the same, and the resulting polymers, wherein the composition comprises the admixture or reaction product resulting from combining: (A) a first metal complex olefin polymerization catalyst, (B) a second metal complex olefin polymerization catalyst capable of preparing polymers differing in chemical or physical properties from the polymer prepared by catalyst (A) under equivalent polymerization conditions, and (C) a chain shuttling agent.
PCT/US2005/008917 2004-03-17 2005-03-17 Catalyst composition comprising shuttling agent for ethylene multi-block copolymer formation WO2005090427A2 (en)

Priority Applications (382)

Application Number Priority Date Filing Date Title
AT05730993T ATE461231T1 (en) 2004-03-17 2005-03-17 CATALYST COMPOSITION WITH SHUTTERING AGENT FOR PRODUCING ETHYLENE MULTIBLOCK COPOLYMER
US11/376,956 US7714071B2 (en) 2004-03-17 2005-03-17 Polymer blends from interpolymers of ethylene/α-olefins and flexible molded articles made therefrom
AU2005224259A AU2005224259B2 (en) 2004-03-17 2005-03-17 Catalyst composition comprising shuttling agent for ethylene multi-block copolymer formation
BRPI0508148-3A BRPI0508148B1 (en) 2004-03-17 2005-03-17 ETHYLENE INTERPOLYMER IN MULTI-BLOCK, CROSS-LINKED DERIVATIVE AND COMPOSITION”
US10/589,377 US7858706B2 (en) 2004-03-17 2005-03-17 Catalyst composition comprising shuttling agent for ethylene multi-block copolymer formation
JP2007504111A JP5133050B2 (en) 2004-03-17 2005-03-17 Catalyst composition comprising a shuttling agent for forming an ethylene multiblock copolymer
EP14176345.8A EP2792690B1 (en) 2004-03-17 2005-03-17 Catalyst composition comprising shuttling agent for ethylene multi-block copolymer formation
CA2559576A CA2559576C (en) 2004-03-17 2005-03-17 Catalyst composition comprising shuttling agent for ethylene multi-block copolymer formation
DE602005019988T DE602005019988D1 (en) 2004-03-17 2005-03-17 CATALYST COMPOSITION WITH SHUTTERING AGENT FOR THE PRODUCTION OF ETHYLENE MULTIBLOCK COPOLYMER
NZ549261A NZ549261A (en) 2004-03-17 2005-03-17 Catalyst composition comprising shuttling agent for ethylene multi-block copolymer formation
PCT/US2005/008917 WO2005090427A2 (en) 2004-03-17 2005-03-17 Catalyst composition comprising shuttling agent for ethylene multi-block copolymer formation
CN2005800148192A CN1976965B (en) 2004-03-17 2005-03-17 Catalyst composition comprising shuttling agent for ethylene multi-block copolymer formation
EP05730993A EP1727841B1 (en) 2004-03-17 2005-03-17 Catalyst composition comprising shuttling agent for ethylene multi-block copolymer formation
CN2006800084231A CN101356207B (en) 2005-03-17 2006-03-15 Interpolymers of ethylene/alpha-olefins blends and profiles and gaskets made therefrom
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US11/376,863 US7897689B2 (en) 2004-03-17 2006-03-15 Functionalized ethylene/α-olefin interpolymer compositions
BRPI0609839-8A BRPI0609839B1 (en) 2005-03-17 2006-03-15 vulcanized thermoplastic and manufactured article
CN2006800083737A CN101277987B (en) 2005-03-17 2006-03-15 Polymer blends from interpolymers of ethylene/alpha-olefins and flexible molded articles made therefrom
CA002601245A CA2601245A1 (en) 2005-03-17 2006-03-15 Interpolymers of ethylene/alpha-olefins blends and profiles and gaskets made therefrom
PCT/US2006/009407 WO2006101929A2 (en) 2005-03-17 2006-03-15 Three-dimensional random looped structures made from interpolymers of ethylene/alpha-olefins and uses thereof
MX2007011343A MX2007011343A (en) 2005-03-17 2006-03-15 Soft foams made from interpolymers of ethylene/alpha-olefins.
AT06738470T ATE449802T1 (en) 2005-03-17 2006-03-15 FILM-SUITABLE COMPOSITIONS OF ETHYLENE/ALPHA-OLEFIN MULTIBLOCK BLEND POLYMER
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BRPI0609837-1A BRPI0609837A2 (en) 2005-03-17 2006-03-15 lubricant composition
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ARP060101002A AR055045A1 (en) 2005-03-17 2006-03-15 POLYMER COMPOSITIONS FILLED PREPARED FROM ETHYLENE / ALFA-OLEFIN INTERPOLYMERS AND THEIR USES
JP2008502120A JP4975730B2 (en) 2005-03-17 2006-03-15 Fibers made from ethylene / α-olefin copolymers
ZA200707867A ZA200707867B (en) 2005-03-17 2006-03-15 Fibers made from copolymers of ethylene/alpha-olefins
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JP2008502017A JP5227785B2 (en) 2005-03-17 2006-03-15 Copolymers of ethylene / α-olefin blends and profiles and gaskets made therefrom
CA002601248A CA2601248A1 (en) 2005-03-17 2006-03-15 Fibers made from copolymers of propylene/alpha-olefins
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DE602006010682T DE602006010682D1 (en) 2005-03-17 2006-03-15 FILLABLE COMPOSITIONS OF ETHYLENE / ALPHA OLEFINE MULTICOLOUR MIXED POLYMER
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PCT/US2006/009406 WO2006101928A2 (en) 2005-03-17 2006-03-15 THERMOPLASTIC VULCANIZATE COMPRISING INTERPOLYMERS OF ETHYLENE/α-OLEFINS
BRPI0609842-8A BRPI0609842B1 (en) 2005-03-17 2006-03-15 POLYMER MIXTURE
RU2007134344/04A RU2007134344A (en) 2005-03-17 2006-03-15 THERMOPLASTIC VOLCANISATE CONTAINING INTERPOLYMERS OF ETHYLENE / α-OLEFINS
BRPI0609850-9A BRPI0609850B1 (en) 2005-03-17 2006-03-15 POLYMER MIX, PROFILE, GASKET, FOAM AND THERMOFORMED ARTICLE
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CN2006800083826A CN101578307B (en) 2005-03-17 2006-03-15 Ethylene/alpha-olefins block interpolymers
EP06738468A EP1858943B1 (en) 2005-03-17 2006-03-15 Thermoplastic vulcanizate comprising interpolymers of ethylene/ -olefins
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BRPI0609829-0A BRPI0609829B1 (en) 2005-03-17 2006-03-15 COMPOSITION
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EP06739033.6A EP1861454B1 (en) 2005-03-17 2006-03-15 FOAMS MADE FROM INTERPOLYMERS OF ETHYLENE/ alpha-OLEFINS
ZA200707869A ZA200707869B (en) 2005-03-17 2006-03-15 Adhesive and marking compositions made from interpolymers of ethylene/alpha-olefins
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BRPI0609841-0A BRPI0609841B1 (en) 2005-03-17 2006-03-15 COMPOSITION OF ETHYLENE/A-OLEFIN INTERPOLYMER AND ARTICLE
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BRPI0609825-8A BRPI0609825B1 (en) 2005-03-17 2006-03-15 COMPOSITION AND ARTICLE
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JP2008502119A JP5054668B2 (en) 2005-03-17 2006-03-15 Viscosity index improver for lubricating compositions
BRPI0609833A BRPI0609833B1 (en) 2005-03-17 2006-03-15 soft foam, foamable composition and foam article
BRPI0609828-2A BRPI0609828A2 (en) 2005-03-17 2006-03-15 film and composition suitable for films
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EP09179528.6A Previously-Filed-Application EP2221328B1 (en) 2004-03-17 2005-03-17 Catalyst composition comprising shuttling agent for ethylene multi-block copolymer formation
EP20090179946 Previously-Filed-Application EP2221329B1 (en) 2004-03-17 2005-03-17 Catalyst composition comprising shuttling agent for ethylene multi-block copolymer formation
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US12/376,956 Continuation-In-Part US8077661B2 (en) 2006-09-13 2006-09-13 Access gateway apparatus, base station apparatus, communication control system and communication control method
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US12/962,800 Continuation US8785551B2 (en) 2004-03-17 2010-12-08 Catalyst composition comprising shuttling agent for ethylene multi-block copolymer formation

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