WO2006073856A3 - Durable high index nanocomposites for ar coatings - Google Patents

Durable high index nanocomposites for ar coatings Download PDF

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Publication number
WO2006073856A3
WO2006073856A3 PCT/US2005/046526 US2005046526W WO2006073856A3 WO 2006073856 A3 WO2006073856 A3 WO 2006073856A3 US 2005046526 W US2005046526 W US 2005046526W WO 2006073856 A3 WO2006073856 A3 WO 2006073856A3
Authority
WO
WIPO (PCT)
Prior art keywords
functionality
reactive
copolymerizable
preferred over
surface modification
Prior art date
Application number
PCT/US2005/046526
Other languages
French (fr)
Other versions
WO2006073856A2 (en
Inventor
Christopher B Walker Jr
Brant U Kolb
Emily S Goenner
Vivian W Jones
Sharon Wang
Joan M Noyala
Original Assignee
3M Innovative Properties Co
Christopher B Walker Jr
Brant U Kolb
Emily S Goenner
Vivian W Jones
Sharon Wang
Joan M Noyala
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 3M Innovative Properties Co, Christopher B Walker Jr, Brant U Kolb, Emily S Goenner, Vivian W Jones, Sharon Wang, Joan M Noyala filed Critical 3M Innovative Properties Co
Priority to JP2007549490A priority Critical patent/JP2008527415A/en
Priority to EP05855137.5A priority patent/EP1838775B1/en
Priority to CN2005800456282A priority patent/CN101124273B/en
Priority to KR1020077017348A priority patent/KR101245897B1/en
Publication of WO2006073856A2 publication Critical patent/WO2006073856A2/en
Publication of WO2006073856A3 publication Critical patent/WO2006073856A3/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K9/00—Use of pretreated ingredients
    • C08K9/04—Ingredients treated with organic substances
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82B—NANOSTRUCTURES FORMED BY MANIPULATION OF INDIVIDUAL ATOMS, MOLECULES, OR LIMITED COLLECTIONS OF ATOMS OR MOLECULES AS DISCRETE UNITS; MANUFACTURE OR TREATMENT THEREOF
    • B82B3/00—Manufacture or treatment of nanostructures by manipulation of individual atoms or molecules, or limited collections of atoms or molecules as discrete units
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
    • C08J7/04—Coating
    • C08J7/0427—Coating with only one layer of a composition containing a polymer binder
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
    • C08J7/04—Coating
    • C08J7/043—Improving the adhesiveness of the coatings per se, e.g. forming primers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
    • C08J7/04—Coating
    • C08J7/046—Forming abrasion-resistant coatings; Forming surface-hardening coatings
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D1/00—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2433/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
    • G—PHYSICS
    • G02—OPTICS
    • G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/133—Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
    • G02F1/1333—Constructional arrangements; Manufacturing methods
    • G02F1/1335—Structural association of cells with optical devices, e.g. polarisers or reflectors
    • G02F1/133502—Antiglare, refractive index matching layers
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S977/00—Nanotechnology
    • Y10S977/70—Nanostructure
    • Y10S977/778—Nanostructure within specified host or matrix material, e.g. nanocomposite films
    • Y10S977/783—Organic host/matrix, e.g. lipid
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S977/00—Nanotechnology
    • Y10S977/70—Nanostructure
    • Y10S977/832—Nanostructure having specified property, e.g. lattice-constant, thermal expansion coefficient
    • Y10S977/834—Optical properties of nanomaterial, e.g. specified transparency, opacity, or index of refraction
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S977/00—Nanotechnology
    • Y10S977/902—Specified use of nanostructure
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24355—Continuous and nonuniform or irregular surface on layer or component [e.g., roofing, etc.]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/25—Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
    • Y10T428/256—Heavy metal or aluminum or compound thereof

Abstract

The present invention includes ultraviolet curable compositions preferably containing discrete, crystalline zirconia nanoparticles with reactive, or copolymerizable, surface modification, in a polymerizable monomer/oligomer resin mixture. It is believed that copolymerizable surface modification provides a functional group that enables the functionalized particle to co-polmerize with the reactive monomers, oligomers, and crosslinkers in the formulation. Relative to surface modifation of the nanoparticles, acrylate functionality is preferred over methacrylate functionality. On the other hand, methacrylate functionality is preferred over non-reactive, or nonpolymerizable, functionality. As the nanocomposite cures, the resultant network is heavily crosslinked by selection of raw materials with substantial acrylate functionality.
PCT/US2005/046526 2004-12-30 2005-12-21 Durable high index nanocomposites for ar coatings WO2006073856A2 (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
JP2007549490A JP2008527415A (en) 2004-12-30 2005-12-21 Durable high refractive index nanocomposite for AR coating
EP05855137.5A EP1838775B1 (en) 2004-12-30 2005-12-21 Durable high index nanocomposites for ar coatings
CN2005800456282A CN101124273B (en) 2004-12-30 2005-12-21 Durable high index nanocomposites for AR coatings
KR1020077017348A KR101245897B1 (en) 2004-12-30 2005-12-21 Durable high index nanocomposites for ar coatings

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US11/026,702 2004-12-30
US11/026,702 US7264872B2 (en) 2004-12-30 2004-12-30 Durable high index nanocomposites for AR coatings

Publications (2)

Publication Number Publication Date
WO2006073856A2 WO2006073856A2 (en) 2006-07-13
WO2006073856A3 true WO2006073856A3 (en) 2007-10-04

Family

ID=36570904

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2005/046526 WO2006073856A2 (en) 2004-12-30 2005-12-21 Durable high index nanocomposites for ar coatings

Country Status (8)

Country Link
US (1) US7264872B2 (en)
EP (1) EP1838775B1 (en)
JP (1) JP2008527415A (en)
KR (1) KR101245897B1 (en)
CN (1) CN101124273B (en)
MY (1) MY140673A (en)
TW (1) TW200630426A (en)
WO (1) WO2006073856A2 (en)

Families Citing this family (101)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20050272847A1 (en) * 2001-08-17 2005-12-08 Chyi-Shan Wang Method of forming nanocomposite materials
US20060079623A1 (en) * 2001-08-17 2006-04-13 Chenggang Chen Method of forming nanocomposite materials
US20050245665A1 (en) * 2001-08-17 2005-11-03 Chenggang Chen Method of forming nanocomposite materials
JP4779293B2 (en) * 2003-10-21 2011-09-28 Ｔｄｋ株式会社 Hard coating agent composition and optical information medium using the same
JP4945902B2 (en) * 2005-01-24 2012-06-06 大日本印刷株式会社 Cosmetic material
US10041176B2 (en) * 2005-04-07 2018-08-07 Momentive Performance Materials Inc. No-rinse pretreatment methods and compositions
KR20080104268A (en) * 2006-01-18 2008-12-02 스파크시스 비.브이. Novel monomeric and polymeric materials
DE102006012467A1 (en) * 2006-03-17 2007-09-20 Merck Patent Gmbh Redispersible nanoparticles
US7413807B2 (en) * 2006-04-14 2008-08-19 3M Innovative Properties Company Fluoroalkyl silicone composition
US7407710B2 (en) * 2006-04-14 2008-08-05 3M Innovative Properties Company Composition containing fluoroalkyl silicone and hydrosilicone
US7410704B2 (en) * 2006-04-14 2008-08-12 3M Innovative Properties Company Composition containing fluoroalkyl hydrosilicone
US20070285779A1 (en) * 2006-06-13 2007-12-13 Walker Christopher B Optical films comprising high refractive index and antireflective coatings
WO2008041976A2 (en) * 2006-09-29 2008-04-10 Momentive Performance Materials Inc. Storage stable composition of partial and/or complete condensate of hydrolyzable organofunctional silane
KR100899811B1 (en) * 2006-12-05 2009-05-27 한국전자통신연구원 Guided mode resonance filter including high refractive index organic material and optical biosensor having the same
JP5401989B2 (en) * 2007-01-16 2014-01-29 住友ベークライト株式会社 Medical particles, analytical particles, and methods for producing them
WO2008101806A2 (en) * 2007-02-20 2008-08-28 Basf Se High refractive index monomers, compositions and uses thereof
EP2147145A1 (en) * 2007-04-17 2010-01-27 HeiQ Materials AG Water-, oil-, and dirt-repellent finishes on fibers and textile fabrics
WO2008131063A1 (en) * 2007-04-19 2008-10-30 3M Innovative Properties Company Methods of use of solid support material for binding biomolecules
US20100209946A1 (en) * 2007-04-19 2010-08-19 Naiyong Jing Uses of water-dispersible silica nanoparticles for attaching biomolecules
US20080274352A1 (en) * 2007-05-04 2008-11-06 3M Innovative Properties Company Optical film comprising antistatic primer and antistatic compositions
US7879688B2 (en) 2007-06-29 2011-02-01 3M Innovative Properties Company Methods for making electronic devices with a solution deposited gate dielectric
US8179034B2 (en) * 2007-07-13 2012-05-15 3M Innovative Properties Company Light extraction film for organic light emitting diode display and lighting devices
US20090015142A1 (en) * 2007-07-13 2009-01-15 3M Innovative Properties Company Light extraction film for organic light emitting diode display devices
KR101009821B1 (en) * 2007-11-13 2011-01-19 주식회사 엘지화학 Coating composition for antireflection, antireflection film and method for preparing the same
JP5349838B2 (en) * 2007-11-30 2013-11-20 和光純薬工業株式会社 Small RNA acquisition carrier, acquisition method and acquisition reagent
US20100296167A1 (en) * 2007-12-19 2010-11-25 E. I. Du Pont De Nemours And Company Bilayer anti-reflective films containing non-oxide nanoparticles
CN101469250B (en) 2007-12-26 2012-09-19 3M创新有限公司 Removable antifogging coating, product, coating composition and method
EP2238182B1 (en) 2007-12-28 2012-08-15 3M Innovative Properties Company A coated sheet material having a release coating comprising a copolymer of nanoparticles, vinyl monomer and silicone macromer
JP2011508058A (en) 2007-12-28 2011-03-10 スリーエム イノベイティブ プロパティズ カンパニー Nanoparticle, vinyl monomer, and silicone copolymer
EP2242805A1 (en) * 2008-01-04 2010-10-27 Sparkxis B.V. Surface modification of metal oxide nanoparticles
JP5520237B2 (en) * 2008-03-03 2014-06-11 ユニバーシティ オブ フロリダ リサーチ ファンデーション インコーポレーティッド Transparent coating material of nanoparticle sol-gel composite hybrid
GB0808685D0 (en) * 2008-05-14 2008-06-18 Dow Corning Anti-friction coating compositions
WO2009151978A1 (en) 2008-06-11 2009-12-17 3M Innovative Properties Company Mixed solvent systems for deposition of organic semiconductors
US8343622B2 (en) * 2008-07-01 2013-01-01 3M Innovative Properties Company Flexible high refractive index hardcoat
US20100110551A1 (en) * 2008-10-31 2010-05-06 3M Innovative Properties Company Light extraction film with high index backfill layer and passivation layer
JP5330539B2 (en) 2008-12-15 2013-10-30 スリーエム イノベイティブ プロパティズ カンパニー High refractive index inorganic oxide nanoparticles containing a surface treatment agent, polymerizable resin composition, and article
DE102009054630B4 (en) * 2008-12-15 2013-02-14 Qimonda Ag Method for producing a photovoltaic device
US7957621B2 (en) * 2008-12-17 2011-06-07 3M Innovative Properties Company Light extraction film with nanoparticle coatings
US8445097B2 (en) * 2008-12-22 2013-05-21 E I Du Pont De Nemours And Company Multi-layer fluoropolymeric film and articles incorporating such films
US8362353B2 (en) 2008-12-22 2013-01-29 E I Du Pont De Nemours And Company Photovoltaic module with multi-layer fluoropolymeric film
CN102325718B (en) 2008-12-30 2013-12-18 3M创新有限公司 Method for making nanostructured surfaces
JP5940809B2 (en) * 2008-12-30 2016-06-29 スリーエム イノベイティブ プロパティズ カンパニー Nanostructured article and method for producing nanostructured article
EP2380045B1 (en) * 2008-12-30 2017-06-28 3M Innovative Properties Company Antireflective articles and methods of making the same
CN101941001B (en) 2009-07-03 2014-04-02 3M创新有限公司 Hydrophilic coating, product, coating composition and method
US8512464B2 (en) * 2009-12-02 2013-08-20 3M Innovative Properties Company Functionalized zirconia nanoparticles and high index films made therefrom
PL2534199T3 (en) * 2010-02-11 2019-04-30 3M Innovative Properties Co Resin system comprising dispersed multimodal surface-modified nanoparticles
KR20130061683A (en) 2010-04-29 2013-06-11 바텔리 메모리얼 인스티튜트 High refractive index composition
CN102241899B (en) 2010-05-11 2014-05-14 3M创新有限公司 Coating composition, method for modifying matrix surface, and product
KR101639082B1 (en) * 2010-10-20 2016-07-13 코오롱인더스트리 주식회사 Photopolymerizable composition and optical sheet
WO2012071243A2 (en) 2010-11-22 2012-05-31 3M Innovative Properties Company Assembly and electronic devices including the same
KR102010937B1 (en) * 2011-02-03 2019-08-14 쓰리엠 이노베이티브 프로퍼티즈 컴파니 Hardcoat
KR101445437B1 (en) * 2011-02-28 2014-09-26 동국대학교 산학협력단 Anti-Reflection Film and Method of Producing The Same
CN102655179A (en) * 2011-03-03 2012-09-05 苏州大学 Method for preparing black silicon
KR20140015443A (en) 2011-03-09 2014-02-06 쓰리엠 이노베이티브 프로퍼티즈 컴파니 Antireflective film comprising large particle size fumed silica
BR112013022051A2 (en) * 2011-03-14 2016-11-29 3M Innovative Properties Co multilayer nanostructured articles
EP2921521A1 (en) * 2011-08-17 2015-09-23 3M Innovative Properties Company of 3M Center Nanostructured articles and methods to make the same
SG11201404580QA (en) * 2012-02-01 2014-10-30 3M Innovative Properties Co Nanostructured materials and methods of making the same
US11133118B2 (en) 2012-05-22 2021-09-28 University Of Massachusetts Patterned nanoparticle structures
JP6066394B2 (en) * 2012-06-04 2017-01-25 日本化薬株式会社 Energy ray curable resin composition for optical lens sheet and cured product thereof
US9938185B2 (en) 2012-07-02 2018-04-10 Owens-Brockway Glass Container Inc. Antireflective coating for glass containers
CN102827500B (en) * 2012-07-16 2015-09-16 长兴（中国）投资有限公司 A kind of anti-scratch and wear-resisting composition and method of making the same and application
US9423532B2 (en) * 2013-03-12 2016-08-23 Intermolecular, Inc. Anti-reflection coatings with aqueous particle dispersions and methods for forming the same
EP2980163B1 (en) * 2013-03-29 2019-12-11 Hoya Corporation Coating composition
CA2908399C (en) * 2013-03-29 2018-02-06 Hoya Corporation Coating composition
US8922895B1 (en) 2013-07-03 2014-12-30 3M Innovative Properties Company Optical body with fresnel-rendering of complex topographical surface
US20150159036A1 (en) * 2013-12-11 2015-06-11 Momentive Performance Materials Inc. Stable primer formulations and coatings with nano dispersion of modified metal oxides
JP2017507803A (en) 2013-12-19 2017-03-23 スリーエム イノベイティブ プロパティズ カンパニー Multilayer composite article
CN105899623B (en) * 2014-01-15 2018-08-10 3M创新有限公司 Include the hard coat film of alkoxylated more (methyl) acrylate monomers and surface treated nano-particle
US10336650B2 (en) 2014-02-04 2019-07-02 3M Innovative Properties Company Anti-soiling compositions for dry and wet soil
TWI543938B (en) 2014-05-13 2016-08-01 國立中央大學 Metal oxide nanoparticle material
CN106413951B (en) * 2014-05-30 2019-05-03 韩国化学研究院 Metal nanoparticle and preparation method thereof
US9994676B2 (en) 2014-06-23 2018-06-12 3M Innovative Properties Company Silicon-containing polymer and method of making a silicon-containing polymer
CN105440933B (en) * 2015-02-15 2018-10-09 广东天安新材料股份有限公司 Electron beam curable coatings
CN106458766B (en) * 2015-03-13 2020-02-14 华为技术有限公司 Zirconium dioxide ceramic appearance piece and manufacturing method thereof
US10330832B2 (en) 2015-06-25 2019-06-25 Apple Inc. High-luminance surface
KR102107736B1 (en) 2015-08-03 2020-05-07 주식회사 엘지화학 Coating composition for flexible plastic film
KR101862252B1 (en) 2015-08-03 2018-05-29 주식회사 엘지화학 Flexible plastic film
KR102094450B1 (en) 2015-08-03 2020-03-27 주식회사 엘지화학 Flexible plastic film
US10684397B2 (en) * 2015-09-08 2020-06-16 Apple Inc. Refractive coatings for a colored surface of an electronic device
US10527765B2 (en) 2015-09-29 2020-01-07 Apple Inc. Surfaces having structured optical appearances
CN105281043B (en) * 2015-11-18 2018-07-27 上海理工大学 A kind of ultra-wideband THz wave anti-reflection component and ultra-wideband THz wave absorber
CN105514188B (en) * 2015-12-25 2017-10-03 中国科学院上海高等研究院 A kind of antireflective self-cleaning film and preparation method thereof
JP2019052196A (en) * 2016-01-27 2019-04-04 Ａｇｃ株式会社 Curable composition, cured article, manufacturing method therefor and article
CN106019428B (en) * 2016-08-08 2019-02-22 北京富兴凯永兴光电技术有限公司 A kind of low-refraction optical filming material
US10114237B2 (en) 2016-08-29 2018-10-30 Apple Inc. Surfaces with photonic crystal coatings and methods of customizing the visual appearance thereof
US10377913B2 (en) * 2016-09-16 2019-08-13 Corning Incorporated High refractive index nanocomposites
US11034843B2 (en) * 2016-12-29 2021-06-15 3M Innovative Properties Company Flexible nanoparticle optical coating compositions
JP6997390B2 (en) * 2017-10-18 2022-01-17 ダイキン工業株式会社 Coating
KR20200096528A (en) * 2017-12-08 2020-08-12 쓰리엠 이노베이티브 프로퍼티즈 컴파니 Flexible hard coat
WO2019169595A1 (en) * 2018-03-08 2019-09-12 Henkel Ag & Co. Kgaa Photocurable adhesive composition
SI3628706T1 (en) * 2018-09-26 2022-09-30 Roehm Gmbh Reaction resin sealing for multi-function markings
WO2020106884A1 (en) * 2018-11-20 2020-05-28 Pixelligent Technologies Llc Solvent-free formulations and nanocomposites
CN111324014A (en) * 2018-12-17 2020-06-23 乐凯华光印刷科技有限公司 Purple laser photopolymerization lithographic printing plate precursor
CN111427103A (en) * 2020-04-08 2020-07-17 六安屹珹新材料科技有限公司 Optical film, preparation method thereof and application structure of optical film
EP4200365A1 (en) 2020-08-21 2023-06-28 Basf Se Uv-curable coatings having high refractive index
KR20220059812A (en) * 2020-11-03 2022-05-10 주식회사 엘지화학 Optical laminate
CN113429719A (en) * 2021-06-29 2021-09-24 李明伟 High-refractive-index nano-zirconia composite resin and preparation method thereof
CN113897064B (en) * 2021-09-17 2022-10-28 山东亿隆薄膜材料有限责任公司 Plastic optical transparent protective film and preparation method thereof
CN114230864B (en) * 2021-12-14 2023-03-24 南京大学 Modified zirconia nanoparticle alcohol dispersion system, preparation method and application thereof, and ultraviolet-curable resin material
CN114250020B (en) * 2021-12-29 2022-08-09 山东玉马遮阳科技股份有限公司 Acrylic coating, preparation method and application thereof, cured product and outdoor building
WO2024019705A1 (en) * 2022-07-19 2024-01-25 Hewlett-Packard Development Company, L.P. Device cover with topcoat layer

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6416838B1 (en) * 1999-10-28 2002-07-09 3M Innovative Properties Company Compositions and articles made therefrom
US20040058614A1 (en) * 1998-12-23 2004-03-25 3M Innovative Properties Company Method for precise molding and alignment of structures on a substrate using a stretchable mold
WO2006007286A2 (en) * 2004-06-17 2006-01-19 3M Innovative Properties Company Polymerizable compositions comprising nanoparticles

Family Cites Families (42)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4396476A (en) * 1979-02-01 1983-08-02 Dentsply Research & Development Corporation Blend of cross-linked polymer, swelling monomer and cross-linking agent and curing process
US4873140A (en) 1988-04-27 1989-10-10 Minnesota Mining And Manufacturing Company Articles having low adhesion articles having coatings thereon
JPH05215902A (en) 1992-02-06 1993-08-27 Mitsubishi Rayon Co Ltd Plastic lens material
JPH0834768A (en) 1994-07-25 1996-02-06 Mitsubishi Rayon Co Ltd New dimethacrylate
US5677050A (en) * 1995-05-19 1997-10-14 Minnesota Mining And Manufacturing Company Retroreflective sheeting having an abrasion resistant ceramer coating
WO1997032226A1 (en) * 1996-02-29 1997-09-04 Minnesota Mining And Manufacturing Company Brightness enhancement film
US6005137A (en) * 1997-06-10 1999-12-21 3M Innovative Properties Company Halogenated acrylates and polymers derived therefrom
US6788463B2 (en) * 1998-01-13 2004-09-07 3M Innovative Properties Company Post-formable multilayer optical films and methods of forming
US6277485B1 (en) * 1998-01-27 2001-08-21 3M Innovative Properties Company Antisoiling coatings for antireflective surfaces and methods of preparation
US6800378B2 (en) * 1998-02-19 2004-10-05 3M Innovative Properties Company Antireflection films for use with displays
US6589650B1 (en) * 2000-08-07 2003-07-08 3M Innovative Properties Company Microscope cover slip materials
US6680125B1 (en) * 1998-05-01 2004-01-20 Hoya Corporation Coating composition and method for preparing the same, and scuff-resistant plastic lense
DE19823732A1 (en) * 1998-05-27 1999-12-02 Inst Neue Mat Gemein Gmbh Process for the production of optical multilayer systems
WO2000022461A1 (en) * 1998-10-14 2000-04-20 Tomoegawa Paper Co., Ltd. Antireflection material and polarizing film using the same
JP3900506B2 (en) * 1998-11-06 2007-04-04 Ｊｓｒ株式会社 Liquid curable resin composition, cured product thereof and antireflection film
EP1014113A3 (en) 1998-12-21 2001-05-09 Dsm N.V. Photo curable resin composition and optical parts
US6261700B1 (en) * 1998-12-30 2001-07-17 3M Innovative Properties Co Ceramer containing a brominated polymer and inorganic oxide particles
KR100667467B1 (en) * 1999-02-15 2007-01-10 코닌클리즈케 디에스엠 엔.브이. Resin composition and cured product
US6238798B1 (en) * 1999-02-22 2001-05-29 3M Innovative Properties Company Ceramer composition and composite comprising free radically curable fluorochemical component
JP2000248975A (en) * 1999-03-01 2000-09-12 Komatsu Ltd Engine speed control device for working vehicle
US6194481B1 (en) * 1999-05-19 2001-02-27 Board Of Regents Of The University Of Texas System Mechanically strong and transparent or translucent composites made using zirconium oxide nanoparticles
DE19924674C2 (en) * 1999-05-29 2001-06-28 Basf Coatings Ag Coating material curable thermally and with actinic radiation and its use
DE19933098A1 (en) * 1999-07-15 2001-01-18 Herberts Gmbh & Co Kg Binder modified with nanoparticles for coating agents and their use
US6677028B1 (en) * 1999-09-10 2004-01-13 3M Innovative Properties Company Retroreflective articles having multilayer films and methods of manufacturing same
US6376590B2 (en) * 1999-10-28 2002-04-23 3M Innovative Properties Company Zirconia sol, process of making and composite material
US6663978B1 (en) * 2000-06-28 2003-12-16 3M Innovative Properties Company High refractive index pressure-sensitive adhesives
US6706403B1 (en) * 2000-05-12 2004-03-16 3M Innovative Properties Company Rigid substrate lamination adhesive
US6788753B1 (en) * 2000-05-12 2004-09-07 Oak Technology, Inc. Maintenance of data synchronization across large gaps in a data stream
DE10049803A1 (en) 2000-10-09 2002-04-18 Bayer Ag Composite particles used e.g. for pigmenting paint or plastics comprise unagglomerated primary pigment particles adhering to colorless carrier particles and separated from one another by a minimum distance
US6541591B2 (en) * 2000-12-21 2003-04-01 3M Innovative Properties Company High refractive index microreplication resin from naphthyloxyalkylmethacrylates or naphthyloxyacrylates polymers
US6656258B2 (en) * 2001-03-20 2003-12-02 3M Innovative Properties Company Compositions comprising fluorinated silanes and compressed fluid CO2
JP4530565B2 (en) 2001-03-29 2010-08-25 大阪瓦斯株式会社 Monoacrylate fluorene compound, composition containing the compound, and cured product thereof
US6656990B2 (en) * 2001-07-11 2003-12-02 Corning Incorporated Curable high refractive index compositions
US6778753B2 (en) * 2001-07-25 2004-08-17 E. I. Du Pont De Nemours And Company Halogenated optical polymer composition
JP2003119207A (en) * 2001-10-11 2003-04-23 Jsr Corp Photocuring composition, cured product thereof, and laminated product
AU2003232437A1 (en) * 2002-05-29 2003-12-19 Inphase Technologies, Inc. High reflective index photoactive compound for optical applications
US6818680B2 (en) * 2002-09-23 2004-11-16 Corning Incorporated Curable adhesive compositions
US6653425B1 (en) * 2002-11-27 2003-11-25 Corning Incorporated High refractive index and high photosensitive optical materials and method for preparing the same
US6844950B2 (en) * 2003-01-07 2005-01-18 General Electric Company Microstructure-bearing articles of high refractive index
JP2004271735A (en) * 2003-03-06 2004-09-30 Fuji Photo Film Co Ltd Manufacturing method of curable coating composition, cured film, anti-reflection film, polarizer, and image display apparatus
US7074463B2 (en) * 2003-09-12 2006-07-11 3M Innovative Properties Company Durable optical element
US6998425B2 (en) 2003-12-23 2006-02-14 General Electric Company UV curable coating compositions and uses thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20040058614A1 (en) * 1998-12-23 2004-03-25 3M Innovative Properties Company Method for precise molding and alignment of structures on a substrate using a stretchable mold
US6416838B1 (en) * 1999-10-28 2002-07-09 3M Innovative Properties Company Compositions and articles made therefrom
WO2006007286A2 (en) * 2004-06-17 2006-01-19 3M Innovative Properties Company Polymerizable compositions comprising nanoparticles

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