WO2007093526A3 - Adsorptionsmasse und verfahren zur entfernung von co aus stoffströmen - Google Patents

Adsorptionsmasse und verfahren zur entfernung von co aus stoffströmen Download PDF

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Publication number
WO2007093526A3
WO2007093526A3 PCT/EP2007/051140 EP2007051140W WO2007093526A3 WO 2007093526 A3 WO2007093526 A3 WO 2007093526A3 EP 2007051140 W EP2007051140 W EP 2007051140W WO 2007093526 A3 WO2007093526 A3 WO 2007093526A3
Authority
WO
WIPO (PCT)
Prior art keywords
copper
material streams
removal
adsorption composition
adsorption
Prior art date
Application number
PCT/EP2007/051140
Other languages
English (en)
French (fr)
Other versions
WO2007093526A2 (de
Inventor
Stephan Schlitter
Stephan Hatscher
Michael Hesse
Heiko Urtel
Original Assignee
Basf Ag
Stephan Schlitter
Stephan Hatscher
Michael Hesse
Heiko Urtel
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basf Ag, Stephan Schlitter, Stephan Hatscher, Michael Hesse, Heiko Urtel filed Critical Basf Ag
Priority to ES07704398.2T priority Critical patent/ES2681896T3/es
Priority to JP2008553754A priority patent/JP5095633B2/ja
Priority to EP07704398.2A priority patent/EP1986772B1/de
Priority to PL07704398T priority patent/PL1986772T3/pl
Priority to US12/279,368 priority patent/US7781368B2/en
Publication of WO2007093526A2 publication Critical patent/WO2007093526A2/de
Publication of WO2007093526A3 publication Critical patent/WO2007093526A3/de
Priority to US12/833,431 priority patent/US7884048B2/en

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/80—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with zinc, cadmium or mercury
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86—Catalytic processes
    • B01D53/8643—Removing mixtures of carbon monoxide or hydrocarbons and nitrogen oxides
    • B01D53/8646—Simultaneous elimination of the components
    • B01D53/865—Simultaneous elimination of the components characterised by a specific catalyst
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/06—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/3007—Moulding, shaping or extruding
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/3078—Thermal treatment, e.g. calcining or pyrolizing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
    • B01J20/3231—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the coating or impregnating layer
    • B01J20/3234—Inorganic material layers
    • B01J20/3236—Inorganic material layers containing metal, other than zeolites, e.g. oxides, hydroxides, sulphides or salts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/34—Regenerating or reactivating
    • B01J20/3433—Regenerating or reactivating of sorbents or filter aids other than those covered by B01J20/3408 - B01J20/3425
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/34—Regenerating or reactivating
    • B01J20/345—Regenerating or reactivating using a particular desorbing compound or mixture
    • B01J20/3458—Regenerating or reactivating using a particular desorbing compound or mixture in the gas phase
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/34—Regenerating or reactivating
    • B01J20/3483—Regenerating or reactivating by thermal treatment not covered by groups B01J20/3441 - B01J20/3475, e.g. by heating or cooling
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/207—Transition metals
    • B01D2255/20715—Zirconium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/207—Transition metals
    • B01D2255/20761—Copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/50—Carbon oxides
    • B01D2257/502—Carbon monoxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2220/00—Aspects relating to sorbent materials
    • B01J2220/50—Aspects relating to the use of sorbent or filter aid materials
    • B01J2220/56—Use in the form of a bed

Abstract

Kohlenmonoxid wird aus Stoffströmen entfernt durch Adsorption an einer Kupfer-, Zink- und Zirkonoxide enthaltenden Adsorptionsmasse, deren Kupfer enthaltender Anteil einen Reduktionsgrad, ausgedrückt als Gewichtsverhältnis von metallischem Kupfer zur Summe aus metallischem Kupfer und Kupferoxiden, gerechnet als CuO, von mindestens 45 % und höchstens 75 % aufweist.
PCT/EP2007/051140 2006-02-14 2007-02-07 Adsorptionsmasse und verfahren zur entfernung von co aus stoffströmen WO2007093526A2 (de)

Priority Applications (6)

Application Number Priority Date Filing Date Title
ES07704398.2T ES2681896T3 (es) 2006-02-14 2007-02-07 Masa de adsorción y procedimiento para la eliminación de CO a partir de corrientes de material
JP2008553754A JP5095633B2 (ja) 2006-02-14 2007-02-07 吸着組成物および流体からのｃｏの除去方法
EP07704398.2A EP1986772B1 (de) 2006-02-14 2007-02-07 Adsorptionsmasse und verfahren zur entfernung von co aus stoffströmen
PL07704398T PL1986772T3 (pl) 2006-02-14 2007-02-07 Masa adsorpcyjna i sposób usuwania co ze strumieni materiałowych
US12/279,368 US7781368B2 (en) 2006-02-14 2007-02-07 Adsorption composition and method of removing CO from streams
US12/833,431 US7884048B2 (en) 2006-02-14 2010-07-09 Adsorption composition and process for removal of CO from material streams

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP06101654 2006-02-14
EP06101654.9 2006-02-14

Related Child Applications (2)

Application Number Title Priority Date Filing Date
US12/279,368 A-371-Of-International US7781368B2 (en) 2006-02-14 2007-02-07 Adsorption composition and method of removing CO from streams
US12/833,431 Division US7884048B2 (en) 2006-02-14 2010-07-09 Adsorption composition and process for removal of CO from material streams

Publications (2)

Publication Number Publication Date
WO2007093526A2 WO2007093526A2 (de) 2007-08-23
WO2007093526A3 true WO2007093526A3 (de) 2007-11-08

Family

ID=38283984

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2007/051140 WO2007093526A2 (de) 2006-02-14 2007-02-07 Adsorptionsmasse und verfahren zur entfernung von co aus stoffströmen

Country Status (10)

Country Link
US (2) US7781368B2 (de)
EP (1) EP1986772B1 (de)
JP (1) JP5095633B2 (de)
CN (2) CN101384356A (de)
ES (1) ES2681896T3 (de)
HU (1) HUE039308T2 (de)
PL (1) PL1986772T3 (de)
RU (1) RU2008136689A (de)
WO (1) WO2007093526A2 (de)
ZA (1) ZA200807784B (de)

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JP5198441B2 (ja) 2006-06-21 2013-05-15 ビーエーエスエフ ソシエタス・ヨーロピア 液体プロピレン流からｃｏを除去するための方法
JP2010510879A (ja) * 2006-12-01 2010-04-08 ビーエーエスエフ ソシエタス・ヨーロピア 物質流からｃｏを除去するための吸着体及びその除去方法
EP2006011A1 (de) * 2007-06-22 2008-12-24 Total Petrochemicals Research Feluy Verfahren zur Reduktion von Kohlenmonoxid in olefinhaltigen Kohlenwasserstoffeinsätzen
WO2009019238A1 (de) * 2007-08-09 2009-02-12 Basf Se Katalysator und verfahren zur entschwefelung von kohlenwasserstoffhaltigen gasen
WO2010069851A1 (de) * 2008-12-17 2010-06-24 Basf Se Verfahren zur entfernung von verunreinigungen aus wasserhaltigen gasströmen
CN103097016B (zh) * 2010-09-09 2016-05-25 巴斯夫欧洲公司 再生包含铜氧化物、锌氧化物和锆氧化物的吸附组合物的方法
US8637724B2 (en) 2010-09-09 2014-01-28 Basf Se Process for the regeneration of a copper, zinc and zirconium oxide-comprising adsorption composition
US8637723B2 (en) 2010-09-09 2014-01-28 Guido Henze Process for the activation of a copper-, zinc- and zirconium oxide-comprising adsorption composition
KR20130114133A (ko) * 2010-09-09 2013-10-16 바스프 에스이 구리, 아연 및 지르코늄 옥사이드 함유 흡착 조성물의 활성화 방법
RU2014137951A (ru) 2012-02-20 2016-04-10 Басф Се СМЕСИ CuO/ZnO В КАЧЕСТВЕ СТАБИЛИЗАТОРОВ ОГНЕСТОЙКИХ ПОЛИАМИДОВ
CN102773103A (zh) * 2012-08-09 2012-11-14 上海化工研究院 低温深度脱除co的催化剂及其制备方法、活化方法和应用
US8940263B2 (en) * 2013-04-10 2015-01-27 Air Products And Chemicals, Inc. Removal of hydrogen and carbon monoxide impurities from gas streams
CN105879656B (zh) * 2015-11-24 2020-01-07 上海超硅半导体有限公司 单晶硅生长尾气固相处理技术
RU2020132505A (ru) * 2018-03-05 2022-04-06 Басф Корпорейшн Адсорбирующие композиции для удаления монооксида углерода
CN111229159A (zh) * 2020-01-15 2020-06-05 武汉世林福幸科技发展有限公司 一种乙烯吸附剂及其制备方法
CN111437821B (zh) * 2020-04-30 2023-04-07 上海化工研究院有限公司 一种低温脱除一氧化碳的逆负载型催化剂及其制备方法

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Publication number Priority date Publication date Assignee Title
US3676516A (en) * 1970-05-18 1972-07-11 Phillips Petroleum Co Purification of ethylene or propylene streams containing carbon monoxide
US4552861A (en) * 1984-03-02 1985-11-12 Institut Francais Du Petrole Process for manufacturing catalysts containing copper, zinc, aluminum and at least one metal from the group formed of rare earths and zirconium and the resultant catalysts for reactions involving a synthesis gas
US4835132A (en) * 1986-01-29 1989-05-30 Dyson Refractories Limited Catalyst and method of making a precursor for the catalyst
EP0296734A1 (de) * 1987-06-22 1988-12-28 Imperial Chemical Industries Plc Kupferkatalysator für die Umwandlung von Kohlenoxid
US5328672A (en) * 1991-09-03 1994-07-12 Ford Motor Company Method for purification of lean-burn engine exhaust gas
WO1995021146A1 (en) * 1994-02-07 1995-08-10 Exxon Chemical Patents Inc. Removal of carbon monoxide from hydrocarbon streams
WO1996014280A1 (en) * 1994-11-07 1996-05-17 Shell Internationale Research Maatschappij B.V. Process and catalyst for the direct hydrogenation of carboxylic esters
DE19848595A1 (de) * 1998-10-21 2000-04-27 Basf Ag Hochtemperaturstabile Katalysatoren zur Zersetzung von N¶2¶0
DE19950325A1 (de) * 1999-10-19 2001-04-26 Basf Ag Spinellmonolith-Katalysator und Verfahren zu seiner Herstellung
DE10241529A1 (de) * 2002-09-05 2004-03-11 Basf Ag Adsorptionsmasse und Verfahren zur Entfernung von Kohlenmonoxid aus Stoffströmen

Also Published As

Publication number Publication date
US7884048B2 (en) 2011-02-08
JP5095633B2 (ja) 2012-12-12
CN103861552A (zh) 2014-06-18
EP1986772B1 (de) 2018-05-30
RU2008136689A (ru) 2010-03-20
ZA200807784B (en) 2009-12-30
US20100273640A1 (en) 2010-10-28
US7781368B2 (en) 2010-08-24
ES2681896T3 (es) 2018-09-17
US20090098037A1 (en) 2009-04-16
HUE039308T2 (hu) 2018-12-28
CN101384356A (zh) 2009-03-11
PL1986772T3 (pl) 2018-10-31
EP1986772A2 (de) 2008-11-05
JP2009526627A (ja) 2009-07-23
WO2007093526A2 (de) 2007-08-23

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