WO2008099154A1 - Methods of completing wells for controlling water and particulate production - Google Patents

Methods of completing wells for controlling water and particulate production Download PDF

Info

Publication number
WO2008099154A1
WO2008099154A1 PCT/GB2008/000476 GB2008000476W WO2008099154A1 WO 2008099154 A1 WO2008099154 A1 WO 2008099154A1 GB 2008000476 W GB2008000476 W GB 2008000476W WO 2008099154 A1 WO2008099154 A1 WO 2008099154A1
Authority
WO
WIPO (PCT)
Prior art keywords
resin
fluid
hydrocarbon
composition
water
Prior art date
Application number
PCT/GB2008/000476
Other languages
French (fr)
Inventor
Philip Duke Nguyen
Original Assignee
Halliburton Energy Services, Inc.
Curtis, Philip, Anthony
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Halliburton Energy Services, Inc., Curtis, Philip, Anthony filed Critical Halliburton Energy Services, Inc.
Publication of WO2008099154A1 publication Critical patent/WO2008099154A1/en

Links

Classifications

    • EFIXED CONSTRUCTIONS
    • E21EARTH DRILLING; MINING
    • E21BEARTH DRILLING, e.g. DEEP DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
    • E21B43/00Methods or apparatus for obtaining oil, gas, water, soluble or meltable materials or a slurry of minerals from wells
    • E21B43/32Preventing gas- or water-coning phenomena, i.e. the formation of a conical column of gas or water around wells
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K8/00Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
    • C09K8/50Compositions for plastering borehole walls, i.e. compositions for temporary consolidation of borehole walls
    • C09K8/502Oil-based compositions
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K8/00Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
    • C09K8/50Compositions for plastering borehole walls, i.e. compositions for temporary consolidation of borehole walls
    • C09K8/504Compositions based on water or polar solvents
    • C09K8/506Compositions based on water or polar solvents containing organic compounds
    • C09K8/508Compositions based on water or polar solvents containing organic compounds macromolecular compounds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K8/00Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
    • C09K8/50Compositions for plastering borehole walls, i.e. compositions for temporary consolidation of borehole walls
    • C09K8/504Compositions based on water or polar solvents
    • C09K8/506Compositions based on water or polar solvents containing organic compounds
    • C09K8/508Compositions based on water or polar solvents containing organic compounds macromolecular compounds
    • C09K8/512Compositions based on water or polar solvents containing organic compounds macromolecular compounds containing cross-linking agents

Definitions

  • the present disclosure relates to methods of completing wells in subterranean formations, such as in unconsolidated subterranean formations. More particularly, the present disclosure relates to methods of completing wells in unconsolidated subterranean formations for controlling water and particulate production.
  • Well completions may involve a number of stages, including the installation of additional equipment into the well and the performance of procedures to prepare the well for production.
  • well completions may include perforating casing that is cemented into the well bore so that fluids can flow, for example, from the formation and into the well bore.
  • Completing the well may also include the installation of production tubing inside the well bore through which fluids may be produced from the bottom of the well bore to the surface.
  • Well completions also may involve a number of other procedures performed in the well and to the surrounding formation, for example, to address issues related to undesired particulate and water production.
  • unconsolidated subterranean formation refers to a subterranean formation that contains loose particulates and/or particulates bonded with insufficient bond strength to withstand forces created by the production (or injection) of fluids through the formation.
  • particulates present in the unconsolidated subterranean formation may include, for example, sand, crushed gravel, crushed proppant, fines, and the like. When the well is placed into production, these particulates may migrate out of the formation with the fluids produced by the wells.
  • the presence of such particulates in produced fluids may be undesirable in that the particulates may, for example, abrade downhole and surface equipment (e.g., pumps, flow lines, etc.) and/or reduce the production of desired fluids from the well.
  • the migrating particulates may clog flow paths, such as formation pores, perforations, and the like, thereby reducing production.
  • a number of well completion techniques have been developed to control particulate production in unconsolidated subterranean formations.
  • One technique of controlling particulate production includes placing a filtration bed containing gravel (e.g., a "gravel pack") near the well bore to provide a physical barrier to the migration of particulates with the production (or injection) of fluids.
  • a filtration bed containing gravel e.g., a "gravel pack”
  • Such "gravel-packing operations” involve the pumping and placement of a quantity of gravel into the unconsolidated formation in an area adjacent to a well bore.
  • One common type of gravel-packing operation involves placing a screen in the well bore and packing the surrounding annulus between the screen and the well bore with gravel of a specific size designed to prevent the passage of formation sand.
  • the screen is generally a filter assembly used to retain the gravel placed during the gravel- pack operation.
  • a consolidating fluid e.g., resins, tackiflers, etc.
  • the consolidating fluid should enhance the grain-to-grain (or grain-to-formation) contact between particulates in the treated portion of the subterranean formation so that the particulates are stabilized, locked in place, or at least partially immobilized such that they are resistant to flowing with produced or injected fluids.
  • the undesired production of water may constitute a major expense in the production of hydrocarbons from subterranean formations, for example, due to the energy expended in producing, separating, and disposing of the water.
  • the water when produced through unconsolidated subterranean formations, the water may also have an undesirable effect on the migration of formation sands. While wells are typically completed in hydrocarbon-producing formations, a water-bearing zone may occasionally be adjacent to the hydrocarbon-producing formation. In some instances, the water may be communicated with the hydrocarbon-producing formation by way of fractures and/or high-permeability streaks.
  • undesired water production may be caused by a variety of other occurrences, including, for example, water coning, water cresting, bottom water, channeling at the well bore (e.g., channels behind casing formed by imperfect bonding between cement and casing), and the like.
  • well completions may include procedures to address issues that may be encountered with the undesired production of water.
  • One attempt to address these issues has been to inject sealing compositions into the formation to form an artificial barrier between the water-bearing zone and the hydrocarbon-producing formation.
  • a gelable fluid may be introduced into the formation in a flowable state and thereafter form a gel in the formation that plugs off formation flow paths to eliminate, or at least reduce, the flow of water.
  • Crosslinkable gels have also been used in a similar manner.
  • certain polymers commonly referred to as "relative-permeability modifiers”
  • the use of relative- permeability modifiers may be desirable, for example, where hydrocarbons will be produced from the treated portion of the formation.
  • the present disclosure relates to methods of completing wells in subterranean formations, such as in unconsolidated subterranean formations. More particularly, the present disclosure relates to methods of completing wells in unconsolidated subterranean formations for controlling water and particulate production.
  • An exemplary embodiment of the present invention provides a method of completing a well.
  • the method comprises forming an artificial barrier to water flow, wherein the artificial barrier is located at or above a hydrocarbon-water interface between a waterbearing formation zone and a hydrocarbon-bearing formation zone.
  • the method further comprises consolidating a portion of the hydrocarbon-bearing formation zone, wherein the artificial barrier is located between the consolidated portion of the hydrocarbon-bearing formation zone and the water-bearing formation zone.
  • Another exemplary embodiment of the present invention provides a method of completing a well for controlling water and particulate production.
  • the method comprises identifying a hydrocarbon-water interface between a hydrocarbon-bearing formation zone and a water-bearing formation zone.
  • the method further comprises perforating a first interval of a casing, and introducing a sealing composition into one or more subterranean formations surrounding the first interval to form an artificial barrier to water flow.
  • the artificial barrier is located either at or above the hydrocarbon-water interface.
  • the method further comprises perforating a second interval of the casing, wherein the second interval is located above the first interval.
  • the method further comprises introducing a consolidating fluid into one or more subterranean formations surrounding the second interval so as to consolidate at least a portion of the one or more subterranean formations.
  • Another exemplary embodiment of the present invention provides a method of completing a well for controlling water and particulate production.
  • the method comprises positioning a jetting tool at a first location in a well bore and perforating a first interval of casing at the first location.
  • the perforating of the first interval comprises using the jetting tool to form one or more perforations that penetrate through the casing.
  • the method further comprises introducing a sealing composition through the jetting tool and into one or more subterranean formations surrounding the first interval to form an artificial barrier to water flow.
  • the method further comprises positioning the jetting tool in the well bore at a second location above the first location, and perforating a second interval of casing at the second location in the well bore.
  • the perforating of the second interval comprises using the jetting tool to form one or more perforations that penetrate through the casing.
  • the method further comprises introducing a consolidating fluid through the jetting tool and into one or more subterranean formations surrounding the second interval so as to consolidate at least a portion of the one or more subterranean formations.
  • Figure 1 is a cross-sectional, side view of a subterranean formation that is penetrated by a cased well bore, in accordance with exemplary embodiments of the present invention
  • Figure 2 is a cross-sectional, side view of the subterranean formation of Figure 1 after treatment with a sealing composition to form an artificial barrier, in accordance with exemplar ⁇ ' embodiments of the present invention
  • Figure 3 is a cross-sectional, top view of the treated subterranean formation of Figure 2 taken along line 3-3, in accordance with exemplary embodiments of the present invention
  • Figure 4 is a cross-sectional, side view of the treated subterranean formation of Figure 2 after additional treatment with a consolidating fluid, in accordance with exemplary embodiments of the present invention
  • Figure 5 is a cross-sectional, top view of the treated subterranean formation of Figure 4 taken along line 5-5, in accordance with exemplary embodiments of the present invention.
  • Figure 6 is a cross-sectional, top view of the treated subterranean formation of Figure 4 taken along line 5-5, after an additional fracturing treatment, in accordance with exemplary embodiments of the present invention.
  • the present disclosure relates to methods of completing wells in subterranean formations, such as in unconsolidated subterranean formations. More particularly, the present disclosure relates to methods of completing wells in unconsolidated subterranean formations for controlling water and particulate production.
  • a well bore 10 is shown that penetrates a hydrocarbon-bearing zone 12 and a water-bearing zone 14. Even though Figure 1 depicts the well bore 10 as a vertical well bore, the methods of the present invention may be suitable for use in deviated or otherwise formed portions of wells. Moreover, as those of ordinary skill in the art will appreciate, exemplary embodiments of the present invention are applicable for the treatment of both production and injection wells.
  • well bore 10 is lined with casing 16 that is cemented to the subterranean formation by cement 18.
  • casing 16 that is cemented to the subterranean formation by cement 18.
  • At least a portion of the hydrocarbon-bearing zone 12 may be an unconsolidated formation that contains loose particulates and/or particulates bonded with insufficient bond strength to withstand forces created by the production of fluids through the formation. Accordingly, when the well is completed and the hydrocarbon-bearing zone 12 is placed into production, these particulates may undesirably migrate out of the formation with the fluids produced by the well. Moreover, as illustrated, the hydrocarbon-bearing zone 12 may be adjacent to a water-bearing zone 14.
  • exemplary embodiments of the present invention generally address these issues of particulate and water production through successive treatments of different formation intervals with a sealing composition to form an artificial barrier that prevents water flow and with a consolidating fluid to control particulate production.
  • completion of the well may include identifying the location of the hydrocarbon- water interface 20, perforating a first interval 22 of the well bore 10, and introducing a sealing composition into the portion of the subterranean formation surrounding the first interval 22 so that an artificial barrier 24 to water flow is formed.
  • identification of the hydrocarbon-water interface 20 may include identifying the location of the water-bearing zone 14 so that the location of the hydrocarbon-water interface 20 may be identified.
  • the location of the waterbearing zone 14 and the location of the hydrocarbon- water interface 20 may be identified using any suitable technique, including, for example, logging after a well bore is drilled or logging while drilling.
  • Figure 2 depicts the first interval 22 as being above the hydrocarbon- water interface 20
  • the first interval 22 may be at any suitable location for the formation of the artificial barrier 24 to water flow.
  • the artificial barrier 24 may be formed at the hydrocarbon- water interface.
  • the bottom of the artificial barrier 24 may be located about five feet, about ten feet or even greater above the hydrocarbon-water interface 20, for example, to effectively control water coning or cresting.
  • placing the top of the artificial barrier 24 above the hydrocarbon-water interface 20 should prevent the flow of water from the water-bearing zone 14 to the hydrocarbon-bearing zone 12.
  • the artificial barrier 24 may overlap the hydrocarbon water interface 20. Accordingly, the first interval 22 may be located at a distance above (e.g., within about five feet, ten feet or greater) the hydrocarbon- water interface 20. Moreover, the first interval 22 may have any suitable length (L) for the desired treatment. By way of example, the first interval 22 may have a length (L) in the range of from about 1 foot to about 50 feet.
  • exemplary embodiments of the present invention may include perforating a first interval 22 of the well bore 10.
  • perforations 26 may be formed that penetrate through the casing 16 and the cement sheath 18 and into the formation.
  • the portion of the hydrocarbon-bearing zone 12 surrounding the first interval 22 may then be treated through the perforations 26 with a sealing composition to form an artificial barrier 24 to prevent, or at least substantially reduce, the migration of water from the water-bearing zone 14 to the hydrocarbon-bearing zone 12.
  • Jetting tool 28 may be any suitable assembly for use in subterranean operations through which a fluid may be jetted at high pressures.
  • the jetting tool 28 should be configured to jet a fluid against the casing 16 and the cement sheath 18 such that perforations 26 may be formed.
  • jetting tool 28 may contain ports 30 for discharging a fluid from the jetting tool 28.
  • the ports 30 form discharge jets as a result of a high pressure fluid forced out of relatively small ports.
  • fluid jet forming nozzles ma ⁇ ' be connected within the ports 30.
  • suitable jetting tools are described in U.S. Pat. Nos. 5,765,642 and 5,499,678, the disclosures of which are incorporated herein by reference.
  • the jetting tool 28 may be positioned in the well bore 10 adjacent the portion of the well bore 10 to be perforated, such as the first interval 22.
  • the jetting tool 28 may be coupled to a work string 32 (e.g., piping, coiled tubing, etc.) and lowered into the well bore 10 to the desired position.
  • a work string 32 e.g., piping, coiled tubing, etc.
  • a fluid may be pumped down through the work string 32, into the jetting tool 28, out through the ports 30, and against the interior surface of the casing 16 causing perforations 26 to be formed through the casing 16 and the cement sheath 18.
  • abrasives e.g., sand
  • a sealing composition may be introduced into the portion of the subterranean formation surrounding the first interval 22 so that an artificial barrier 24 to water flow is formed.
  • the sealing composition may be any suitable composition suitable for forming an artificial barrier (such as artificial barrier 24) to water flow in the treated portion of the subterranean formation such that the flow of water therethrough is eliminated or at least substantially reduced.
  • the sealing composition should form a substantially impenetrable barrier that eliminates, or at least partially reduces, the migration of any fluids between the water-bearing zone 14 and the hydrocarbon-bearing zone 12, or vice versa.
  • the sealing composition should be able to penetrate into the formation and form an artificial barrier therein that plugs off pore spaces to water flow. Examples of suitable sealing compositions are described in more detail below.
  • any suitable technique may be used for the delivery of the sealing composition into the portion of the hydrocarbon-bearing zone 12 surrounding the first interval 22.
  • bull heading, coil tubing or jointed pipe e.g., with straddle packers, jetting tools, etc.
  • the sealing composition may be injected into the hydrocarbon- bearing formation 12 by the jetting tool 28 while the jetting tool 28 is still in position in the well bore 10.
  • the jetting tool 28 may be used for the delivery of the sealing composition into the portion of the hydrocarbon-bearing formation 12 that surrounds the first interval 22.
  • Utilization of jetting tool 28 may reduce the need for equipment, such as packers, to isolate the treated interval (e.g., first interval 22).
  • the sealing composition may be injected through the amulus 42 between the work string 32 and the casing 16.
  • the sealing composition may be introduced into the hydrocarbon-bearing formation 12 at matrix flow rates.
  • the sealing composition may be introduced at a flow rate in the range of from about 0.25 barrels to about 3 barrels per minute, depending, for example, on the length of the first interval 22.
  • these flow rates are merely exemplary, and the present invention is applicable to flow rates outside these ranges.
  • a sufficient amount of the sealing composition should be introduced such that the sealing composition has the desired penetration into the formation.
  • a sufficient amount of the sealing composition may be introduced such that it penetrates in the range of from about 5 feet to about 50 feet into the formation.
  • the depth of penetration of the sealing composition into the formation will vary, for example, based on the particular application.
  • exemplary embodiments of the present invention may comprise perforating a second interval 34 of the well bore 10, and introducing a consolidating fluid into the portion of the subterranean formation surrounding the . second interval 34.
  • the second interval 34 may be located above the first interval 22 so that the artificial barrier 24 prevents, or at least substantially reduces, water flow from the water-bearing formation 14 to the portion of the hydrocarbon bearing zone 12 surrounding the second interval 34. In this manner, the undesired production of water and particulates may be controlled once the well is put on production, in accordance with exemplary embodiments.
  • the second interval 34 may have any suitable length (L) for the desired consolidation and production rate. Those of ordinary skill in the art will appreciate that the (L) of the second interval 34 will vary based on a number of factors, including, for example, costs and the desired production rate.
  • exemplar ⁇ ' embodiments of the present invention may include perforating the second interval 34 of the well bore 10.
  • perforations 36 may be formed in the second interval 34 that penetrate through the casing 16 and the cement sheath 18 and into the formation.
  • the portion of the hydrocarbon-bearing zone 12 surrounding the second interval 34 may then be treated through the perforations 36 with a consolidating fluid for controlling particulate production.
  • the second interval 34 may be perforated using any suitable technique
  • an exemplary embodiment utilizes the jetting tool 28. Exemplary embodiments of the jetting tool 28 are described above with respect to perforating the first interval 22.
  • the jetting tool 28 may be positioned in the well bore 10 adjacent the portion of the well bore 10 to be perforated, such as the second interval 34.
  • the jetting tool 28 may be raised from the first interval 22 to the second interval 34.
  • a fluid may be pumped down through the work string 32, into the jetting tool 28, out through the ports 30, and against the interior surface of the casing 16 causing the perforations 36 to be formed through the casing 16 and the cement sheath 18.
  • abrasives e.g., sand
  • sand may be included in the jetted fluid.
  • a consolidating fluid may be introduced into the portion of the subterranean formation surrounding the second interval 34 to consolidate the treated portion of the formation into a consolidated region 38.
  • the consolidating fluid should be any suitable fluid for enhancing the grain-to-grain (or grain- to-formation) contact between particulates in the treated portion of the subterranean formation so that the particulates are stabilized, locked in place, or at least partially immobilized such that they are resistant to flowing with produced or injected fluids. Accordingly, after treatment with the consolidating fluid, the particulates in the consolidated region 38 should be inhibited from migrating with any subsequently produced or injected fluids.
  • any suitable technique may be used for the deliver ⁇ ' of the consolidating fluid into the second interval 34, for example, bull heading, coil tubing or jointed pipe (e.g., with straddle packers, jetting tools, etc.), or any other suitable technique may be used.
  • the jetting tool 28 may be used for the delivery of the consolidating fluid into the portion of the hydrocarbon-bearing zone 12 that surrounds the second interval 34. Utilization of the jetting tool 28 may reduce the need for additional equipment (e.g., packers) to isolate the second interval 34.
  • the consolidating fluid may be introduced into the hydrocarbon-bearing formation 12 at matrix flow rates.
  • the consolidating fluid may be introduced at a flow rate in the range of from about 0.25 barrels to about 3 barrels per minute, depending on, for example, the length of perforated interval.
  • these flow rates are merely exemplary, and the present invention is applicable to flow rates outside these ranges.
  • the consolidating fluid should achieve sufficient penetration into the formation for the particular application.
  • the consolidating fluid may be introduced into the near well bore portion of the formation surrounding the second interval 34.
  • consolidation of the near well bore portion of the formation may alleviate potential problems associated with particulate production and thus help to control such undesired particulate production.
  • the "near well bore portion" of a formation generally refers to the portion of a subterranean formation surrounding a well bore.
  • the “near well bore portion” may refer to the portion of the formation surrounding a well bore and having a depth of penetration of from about 1 to about 3 well bore diameters.
  • the depth of penetration of the consolidating fluid into the formation may vary based on the particular application.
  • this invention is not limited to such order of treatment.
  • the order of treatment may be reversed in that treatment of the second interval 34 with the consolidating fluid may occur prior to treatment of the first interval 22 with the sealing composition.
  • the well bore 10 optionally may be shut in for a period of time.
  • the shutting in of the well bore 10 for a period of time may, inter alia, enhance the coating of the consolidating fluid onto the particulates and minimize the washing away of the consolidating fluid during any later subterranean operations.
  • the necessary shut-in time period is dependent, among other things, on the composition of the consolidating fluid used and the temperature of the formation. Generally, the chosen period of time may be between about 0.5 hours and about 72 hours or longer. Determining the proper period of time to shut in the formation is within the ability of one skilled in the art with the benefit of this disclosure.
  • fracturing step may be used to reconnect the well bore 10 with portions of the formation outside the consolidated region 38.
  • one or more fractures 40 may be created or enhanced through the consolidated region 38 and into the surrounding formation to at least partially restore effective permeability to the consolidated region.
  • enhancing refers to the extension or enlargement of a natural or previously created fracture in the formation.
  • the fracturing step may be accomplished by any suitable methodology.
  • a hydraulic-fracturing treatment may be used that includes introducing a fracturing fluid into the consolidated region 38 at a pressure sufficient to create or enhance one or more fractures 40.
  • the fracturing step may utilize the j etting tool 28.
  • the j etting tool 28 may be used to initiate one or more fractures 40 in the consolidated region 38 by way of jetting a fluid through the perforations 36 and against the consolidated region 38.
  • a fracturing fluid may also be pumped down through the annulus 42 between the work string 32 and the casing 16 and then into the consolidated region 38 at a pressure sufficient to create or enhance the one or more fractures 40.
  • the fracturing fluid may be pumped down through the annulus 42 concurrently with the jetting of the fluid.
  • a suitable fracturing treatment is CobraMax M Fracturing Service, available from Halliburton Energy Services, Inc.
  • the fracturing fluid may comprise a viscosified fluid (e.g., a gel or a crosslinked gel).
  • the fracturing fluid further may comprise proppant 44 that is deposited in the one or more fractures 40 to generate propped fractures.
  • the proppant 44 majr be coated with a consolidating agent (e.g., a curable resin, a tackifying agent, etc.) so that the coated proppant forms a bondable, permeable mass in the one or more fractures 40, for example, to mitigate proppant flow back when the well is placed into production.
  • the proppant may be coated with an ExpediteTM resin system, available from Halliburton Energy Services, Inc.
  • one or more after- flush fluids may be used to at least partially restore permeability to the consolidated region 38, if desired.
  • the after-flush fluid may be introduced into the consolidated region 38 while the consolidating fluid is still in a flowing state.
  • the after-flush fluid generally acts to displace at least a portion of the consolidating fluid from flow paths in the consolidated region 38 and to force the displaced portions of the consolidating fluid further into the formation where it may have negligible impact on subsequent production.
  • sufficient amounts of the consolidating fluid should remain in the consolidated region 38 to provide effective stabilization of the particulates therein.
  • the after-flush fluid may be any fluid that does not undesirably react with the other components used or the subterranean formation.
  • the after-flush fluid may be an aqueous-based fluid, a non-aqueous based fluid (e.g., kerosene, toluene, diesel, or crude oil), or a gas (e.g., nitrogen or carbon dioxide).
  • one or more pre-flush fluids may be introduced into the portion of the hydrocarbon-bearing zone 12 surrounding second interval 34.
  • the pre-flush fluid may be introduced into the formation to, for example, cleanout undesirable substances (e.g., oil, residue, or debris) from pore spaces in the matrix of the formation and/or to prepare the formation for subsequent placement of the consolidating fluid.
  • an acidic pre-flush fluid may be used to, for example, dissolve undesirable substances in the formation.
  • pre-flush fluids examples include aqueous-based fluid, a non-aqueous based fluid (e.g., kerosene, xylene, toluene, diesel, or crude oil), or a gas (e.g., nitrogen or carbon dioxide).
  • Aqueous-based fluids may comprise fresh water, salt water, brines, sea water, or combinations thereof.
  • one or more surfactants may be present in the pre-flush fluid, e.g., to aid a consolidating fluid in flowing to contact points between adjacent particulates in the formation.
  • a sealing composition may be introduced into a portion of a subterranean formation to form an artificial barrier to water flow.
  • the artificial barrier typically may be located between the waterbearing zone and the hydrocarbon-bearing zone so as to minimize the undesired production of water from the hydrocarbon-bearing zone
  • the sealing composition may be any composition suitable for forming an artificial barrier in the treated portion of the subterranean formation such that the flow of water therethrough is eliminated or at least substantially reduced.
  • suitable sealing compositions may include tackifying fluids, resin compositions, and gelable compositions.
  • suitable sealing compositions may include fluids that comprise relative-permeability modifiers.
  • the phrase "relative-permeability modifier" refers to compounds that should reduce a formation's effective permeability to water without a comparable reduction in the formation's effective permeability to hydrocarbons.
  • these sealing compositions are merely exemplary, and the present invention is applicable to other compositions for forming a suitable artificial barrier to the flow of water. Examples of suitable sealing compositions will be described in more detail as follows.
  • an exemplary embodiment of the sealing compositions used in the present invention may comprise a tackifying agent.
  • Suitable tackifying agents are substances that are (or may be activated to become) tacky and thus adhere to unconsolidated particulates in the subterranean formation. In this manner, the tackifying agent may form a barrier in the treated portion of the formation.
  • Suitable tackifying agents may not be significantly tacky when placed into the formation, but may be capable of being "activated" (that is destabilized, coalesced and/or reacted) to transform into a tacky compound at a desirable time. Such activation may occur before, during, or after the introduction of the tackifying fluid into the subterranean formation.
  • One type of tackifying agent suitable for use includes a non-aqueous tackifying agent.
  • An example of a suitable non-aqueous tackifying agent comprises polyamides that are liquids or in solution at the temperature of the formation such that they are, by themselves, non-hardening when introduced into the subterranean formation.
  • One exemplary embodiment of a suitable tackifying agent comprises a condensation reaction product that comprises commercially available polyacids and a polyamine. Such commercial products include compounds such as mixtures of C 36 dibasic acids containing some trimer and higher oligomers and also small amounts of monomer acids that are reacted with polyamines.
  • polyacids include trimer acids, synthetic acids produced from fatty acids, maleic anhydride, acrylic acid, and the like.
  • acid compounds are commercially available from companies such as Witco Corporation, Union Camp, Chemtall, and Emery Industries.
  • the reaction products are available from, for example, Champion Technologies, Inc. and Witco Corporation.
  • An example of a suitable non- aqueous tackifying agent is Sand Wedge Enhancement System, available from Halliburton Energy Sendees, Inc.
  • non-aqueous tackifying agents include liquids and solutions of, for example, polyesters, polycarbonates and polycarbamates, natural resins such as shellac and the like.
  • suitable non-aqueous tackifying agents are described in U.S. Pat. Nos. 5,853,048 and 5,833,000, the disclosures of which are incorporated herein by reference.
  • Non-aqueous tackifying agents may be either used such that they form a non- hardenitig coating or they may be combined with a multifunctional material capable of reacting with the tackifying compound to form a hardened coating.
  • a “hardened coating” as used in this disclosure means that the reaction of the tackifying compound with the multifunctional material will result in a substantially non-flowable reaction product that exhibits a higher compressive strength in a consolidated agglomerate than the tackifying compound alone with the particulates.
  • the tackifying agent may function similarly to a hardenable resin.
  • Multifunctional materials suitable for use in the present invention include aldehydes, dialdehydes such as glutaraldehyde, hemiacetals or aldehyde releasing compounds, diacid halides, dihalides such as dichlorides and dibromides, polyacid anhydrides such as citric acid, epoxides, furfuraldehyde, glutaraldehyde, aldehyde condensates, and silyl-modified polyamide compounds and the like, and combinations thereof.
  • dialdehydes such as glutaraldehyde, hemiacetals or aldehyde releasing compounds
  • diacid halides dihalides such as dichlorides and dibromides
  • polyacid anhydrides such as citric acid, epoxides, furfuraldehyde, glutaraldehyde, aldehyde condensates, and silyl-modified polyamide compounds and the like, and combinations thereof.
  • Suitable silyl-modified polyamide compounds that may be used in exemplary embodiments of the present invention include those that are substantially self-hardening compositions capable of at least partially adhering to particulates in the unhardened state, and that are further capable of self hardening themselves to a substantially non-tacky state to which individual particulates such as formation fines will not adhere to, for example, in formation or proppant pack pore throats.
  • Such silyl-modified polyamides may be based, for example, on the reaction product of a silating compound with a polyamide or a mixture of polyamides.
  • the polyamide or mixture of polyamides may be one or more polyamide intermediate compounds obtained, for example, from the reaction of a polyacid (e.g., diacid or higher) with a polyamine (e.g., diamine or higher) to form a polyamide polymer with the elimination of water.
  • a polyacid e.g., diacid or higher
  • a polyamine e.g., diamine or higher
  • the multifunctional material may be mixed with the tackifying agent in an amount of from about 0.01 to about 50 percent by weight of the tackifying agent to effect formation of the reaction product. In some exemplary embodiments, the multifunctional material may be present in an amount of from about 0.5 to about 1 percent by weight of the tackifying compound. Suitable multifunctional materials are described in U.S. Pat. No. 5,839,510, the disclosure of which is incorporated herein by reference. [0048] Solvents suitable for use with the tackifying agents include any solvent that is compatible with the tackifying agent and achieves the desired viscosity effect.
  • the solvents that can be used in exemplary embodiments of the present invention preferably include those having high flash points (e.g., above about 125°F).
  • solvents suitable for use in exemplary embodiments of the present invention include butylglycidyl ether, dipropylene glycol methyl ether, butyl bottom alcohol, dipropylene glycol dimethyl ether, diethyleneglycol methyl ether, ethyl enegly col butyl ether, methanol, butyl alcohol, isopropyl alcohol, diethyleneglycol butyl ether, propylene carbonate, d'limonene, 2-butoxy ethanol, butyl acetate, furfuryl acetate, butyl lactate, dimethyl sulfoxide, dimethyl formamide, fatty acid methyl esters, and combinations thereof. It is within the ability of one skilled in the art, with the benefit of this disclosure, to determine whether a solvent is needed to achieve a viscosity suitable to the subterran
  • aqueous tackifying agent refers to a tackifying agent that is soluble in water.
  • suitable aqueous tackifying agents generally comprise charged polymers, that when in an aqueous solvent or solution, enhance the grain-to-grain contact between the individual particulates within the formation (e.g., proppant, gravel particulates, formation particulates, or other particulates), and may help bring about the consolidation of the particulates into a cohesive, flexible, and permeable mass.
  • aqueous tackifying agents suitable for use in an exemplary embodiment of the present invention include acrylic acid polymers, acrylic acid ester polymers, acrylic acid derivative polymers, acrylic acid homopolymers, acrylic acid ester homopolymers (such as poly(methyl acrylate), poly (butyl acrylate), and poly(2-ethylhexyl acrylate)), acrylic acid ester copolymers, methacrylic acid derivative polymers, methacrylic acid homopolymers, methacrylic acid ester homopolymers (such as poly(methyl methacrylate), poly(butyl methacrylate), and poly(2-ethylhexyl methacrylate)), acrylamido-methyl-propane sulfonate polymers, acrylamido-methyl-propane sulfonate derivative polymers, acrylamido-methyl-propane sulfonate copolymers, and acrylic acid/acrylamido-methyl-propane sulfonate copo
  • aqueous tackifying agents examples include FDP-S706-3 and FDP-S800-05, which are available from Halliburton Energy Services, Inc.
  • suitable aqueous tackifying agents are described in U.S. Pat. No. 7,131,491 and U.S. Pat App. Pub. No. 2005/0277554, the disclosures of which are incorporated herein by reference.
  • aqueous tackifying agent comprises a benzyl coco di-(hydroxyethyl) quaternary amine, p-T-amyl-phenol condensed with formaldehyde, or a copolymer comprising from about 80% to about 100% Ci -30 alkylmethacrylate monomers and from about 0% to about 20% hydropbilic monomers.
  • the aqueous tackifying agent may comprise a copolymer that comprises from about 90% to about 99.5% 2-ethylhexylacrylate and from about 0.5% to about 10% acrylic acid.
  • Suitable hydrophilic monomers may be any monomer that will provide polar oxygen-containing or mixogen-containing groups.
  • Suitable hydrophilic monomers include dialJkyl amino alkyl (meth) acrylates and their quaternary addition and acid salts, acrylamide, N-(dialkyl amino alkyl) acrylamide, methacrylamides and their quaternary addition and acid salts, hydroxy alkyl (meth)acrylates, unsaturated carboxylic acids such as methacrylic acid or acrylic acid, hydroxyethyl acrylate, acrylamide, and the like.
  • These copolymers can be made by any suitable emulsion polymerization technique. Examples of suitable tackifying agents are described in U.S. Pat. No. 5,249,627, the disclosure of which is incorporated herein by reference. Methods of producing these copolymers are disclosed in U.S. Pat. No. 4,670,501, the disclosure of which is incorporated herein by reference.
  • Resins suitable for use may include any suitable resin that is capable of forming a hardened, consolidated mass in the treated formation.
  • the term "resin” as used herein includes any of numerous physically similar polymerized synthetics or chemically modified natural resins, including but not limited to thermoplastic materials and thermosetting materials.
  • resins are commonly used in subterranean consolidation operations, and some suitable resins include two-component epoxy based resins, novolak resins, polyepoxide resins, phenol-aldehyde resins, urea-aldehyde resins, urethane resins, phenolic resins, furan resins, furan/furfuryl alcohol resins, phenolic/latex resins, phenol formaldehyde resins, polyester resins and hybrids and copolymers thereof, polyurethane resins and hybrids and copolymers thereof, acrylate resins, and combinations thereof.
  • suitable resins include two-component epoxy based resins, novolak resins, polyepoxide resins, phenol-aldehyde resins, urea-aldehyde resins, urethane resins, phenolic resins, furan resins, furan/furfuryl alcohol resins, phenolic/latex resins, phenol formaldehyde resins
  • suitable resins such as epoxy resins
  • suitable resins such as furan resins generally require a time-delayed catalyst or an external catalyst to help activate the polymerization of the resins if the cure temperature is low (e.g., less than 250° F) but will cure under the effect of time and temperature if the formation temperature is above about 250 0 F 5 preferably above about 300 0 F. It is within the ability of one skilled in the art, with the benefit of this disclosure, to select a suitable resin for use in exemplary embodiments of the present invention and to determine whether a catalyst is needed to trigger curing.
  • An example of a suitable resin is Sand Trap ® Formation Consolidation Service, available from Halliburton Energy Services, Inc.
  • Selection of a suitable resin may be affected by the temperature of the subterranean formation to which the fluid will be introduced.
  • a bottom hole static temperature BHST
  • two-component epoxy-based resins comprising a hardenable resin component and a hardening agent component containing specific hardening agents may be preferred.
  • a furan-based resin may be preferred.
  • a phenolic-based resin or a one-component HT epoxy-based resin may be suitable.
  • a phenol/phenol formaldehyde/furfuryl alcohol resin may also be suitable.
  • any solvent that is compatible with the chosen resin and achieves the desired viscosity effect may be suitable for use with the resin.
  • Some exemplary solvents are those having high flash points (e.g., about 125 0 F) because of, among other things, environmental and safety concerns; such solvents include butyl lactate, butylglycidyl ether, dipropylene glycol methyl ether, dipropylene glycol dimethyl ether, dimethyl formamide, diethyleneglycol methyl ether, ethyleneglycol butyl ether, diethyleneglycol butyl ether, propylene carbonate, methanol, butyl alcohol, d-limonene, fatty acid methyl esters, and combinations thereof.
  • Suitable solvents include aqueous dissolvable solvents such as, methanol, isopropanol, butanol, glycol ether solvents, and combinations thereof.
  • Suitable glycol ether solvents include, but are not limited to, diethylene glycol methyl ether, dipropylene glycol methyl ether, 2-butoxy ethanol, ethers of a C 2 to C 6 dihydric alkanol containing at least one C 1 to C 6 alkyl group, mono ethers of dihydric alkanols, methoxypropanol, butoxyethanol, hexoxyethanol, and isomers thereof. Selection of an appropriate solvent is dependent on the resin chosen and is within the ability of one skilled in the art with the benefit of this disclosure.
  • suitable gelable compositions should cure to form a gel.
  • Gelable compositions suitable for use in exemplary embodiments of the present invention include those compositions that cure to form a semi-solid, immovable, gel-like substance. Prior to curing, the gelable compositions should have low viscosities and be capable of flowing in pipe and into the subterranean formation.
  • the gelable composition may be any gelable liquid composition capable of converting into a gelled substance that substantially plugs the permeability of the formation. Accordingly, once placed into the formation, the gelable composition should form the desired artificial barrier.
  • suitable gelable compositions include gelable aqueous silicate compositions, crosslinkable aqueous polymer compositions, gelable resins and polymerizable organic monomer compositions. Examples of suitable gelable compositions will be described in more detail as follows.
  • the gelable compositions may comprise a gelable aqueous silicate composition.
  • Suitable gelable aqueous silicate compositions for barrier formation generally comprise aqueous alkali metal silicate solution and a catalyst (e.g., a temperature-activated catalyst) for gelling the aqueous alkali metal silicate solution.
  • a catalyst e.g., a temperature-activated catalyst
  • An example of a suitable gelable aqueous silicate composition is InjectrolTM, which is available from Halliburton Energy Services, Inc.
  • suitable gelable aqueous silicate compositions are described in U.S. Pat. No. 4,466,831, the disclosure of which is incorporated herein by reference.
  • the aqueous alkali metal silicate solution component of the gelable aqueous silicate compositions generally may comprise an aqueous liquid and an alkali metal silicate.
  • the aqueous liquid component of the aqueous alkali metal silicate solution generally may be fresh water, salt water (e.g., water containing one or more salts dissolved therein), brine (e.g., saturated salt water), seawater, or any other aqueous liquid that does not adversely react with the other components used in accordance with this invention or with the subterranean formation.
  • suitable alkali metal silicates include one or more of sodium silicate, potassium silicate, lithium silicate, rubidium silicate, or cesium silicate.
  • the sodium silicate that may be used in the aqueous alkali metal silicate solution may have a Na 2 OtO-SiO 2 weight ratio in the range of from about 1 :2 to about 1 :4.
  • the sodium silicate may have a Na 2 CMo-SiO 2 weight ratio in the range of about 1 :3.2.
  • the alkali metal silicate ma ⁇ ' be present in the aqueous alkali metal silicate solution component in an amount in the range of from about 0.1% to about 10% by weight of the aqueous alkali metal silicate solution component.
  • the temperature-activated catalyst component of the gelable aqueous silicate compositions is used, inter alia, to convert the gelable aqueous silicate compositions into the desired semi-solid, gel-like substance described above. Selection of a temperature-activated catalyst is related, at least in part, to the temperature of the subterranean formation to which the gelable aqueous silicate composition will be introduced.
  • the temperature-activated catalysts that can be used in the gelable aqueous silicate compositions of exemplary embodiments of the present invention include, but are not limited to, ammonium sulfate (which is most suitable in the range of from about 60°F to about 24O 0 F); sodium acid pyrophosphate (which is most suitable in the range of from about 6O 0 F to about 240 0 F); citric acid (which is most suitable in the range of from about 6O 0 F to about 120 0 F); and ethyl acetate (which is most suitable in the range of from about 6O 0 F to about 120 0 F).
  • the temperature-activated catalyst may be present in the gelable aqueous silicate composition in the range of from about 0.1% to about 5% by weight of the gelable aqueous silicate composition.
  • the gelable compositions may comprise a crosslinkable aqueous polymer composition.
  • Suitable crosslinkable aqueous polymer compositions for barrier formation generally comprise an aqueous solvent, a crosslinkable polymer, and a crosslinking agent.
  • Such compositions are similar to those used to form gelled treatment fluids, such as fracturing fluids, but, according to the methods of exemplary embodiments of the present invention, they are not exposed to breakers or de-linkers so they retain their viscous nature over time.
  • suitable compositions should generally be resistant to breaking, for example, due to formation temperatures.
  • An example of a suitable crosslinkable polymer composition is H2-ZeroTM, which is commercially available from Halliburton Energy Services, Lac. Examples of suitable crosslinkable aqueous polymer compositions are described in U.S. Pat. Nos. 5,836,392, 6,192,986, and 6,196,317, the disclosures of which are incorporated herein by reference.
  • the aqueous solvent may be any aqueous solvent in which the crosslinkable composition and the crosslinking agent may be dissolved, mixed, suspended, or dispersed therein to facilitate gel formation.
  • the aqueous solvent used may be fresh water, salt water, brine, seawater, or any other aqueous liquid that does not adversely react with the other components used in accordance with exemplary embodiments of the present invention or with the subterranean formation.
  • crosslinkable polymers that can be used in the crosslinkable aqueous polymer compositions include carboxylate-containing polymers and acrylamide- containing polymers.
  • suitable acrylamide-containing polymers include polyacrylamide, partially hydrolyzed polyacrylamide, copolymers of acrylamide and acrylate, copolymers of acrylamide and 2-acrylamido-2-methylpropanesulfonic acid, carboxylate- containing terpolymers and tetrapolymers of acrylate.
  • Suitable crosslinkable polymers include hydratable polymers comprising polysaccharides and derivatives thereof and that contain one or more of the monosaccharide unit's galactose, mannose, glucoside, glucose, xylose, arabinose, fructose, glucuronic acid, or pyranosyl sulfate.
  • Suitable natural hydratable polymers include, but are not limited to, guar gum, locust bean gum, tara, konjak, tamarind, starch, cellulose, karaya, xanthan, tragacanth, and carrageenan, and derivatives of all of the above.
  • Suitable hydratable synthetic polymers and copolymers that may be used in the crosslinkable aqueous polymer compositions include polyacrylates, polymethacrylates, polyacrylamides, maleic anhydride, methylvinyl ether polymers, polyvinyl alcohols, and polyvinylpyrrolidone.
  • the crosslinkable polymer used should be included in the crosslinkable aqueous polymer composition in an amount sufficient to form the desired gelled substance in the subterranean formation.
  • the crosslinkable polymer may be included in the crosslinkable aqueous polymer composition in an amount in the range of from about 1% to about 30% by weight of the aqueous solvent.
  • the crosslinkable polymer may be included in the crosslinkable aqueous polymer composition in an amount in the range of from about 1% to about 20% by weight of the aqueous solvent.
  • the crosslinkable aqueous polymer compositions of exemplary embodiments of the present invention further comprise a crosslinking agent for crosslinking the crosslinkable polymers to form the desired gelled substance.
  • the crosslinking agent may be a molecule or complex containing a reactive transition metal cation.
  • An exemplary crosslinking agent comprises trivalent chromium cations complexed or bonded to anions, atomic oxygen, or water.
  • suitable crosslinking agents include compounds or complexes containing chromic acetate and/or chromic chloride.
  • Other suitable transition metal cations include chromium VI within a redox system, aluminum III, iron II, iron III, and zirconium IV.
  • Organic crosslinkers may also be suitable, in certain exemplary embodiments. Examples of suitable organic crosslinkers include polyalkyleneimines, polyalkylenepolyamines (e.g., polyethyleneimine), chitosan, and mixtures thereof.
  • the crosslinking agent should be present in the crosslinkable aqueous polymer compositions of exemplary embodiments of the present invention in an amount sufficient to provide, inter alia, the desired degree of crosslinking.
  • the crosslinking agent may be present in the crosslinkable aqueous polymer compositions of the present invention in an amount in the range of from about 0.01% to about 5% by weight of the crosslinkable aqueous polymer composition.
  • the exact type and amount of crosslinking agent or agents used depends upon the specific crosslinkable polymer to be crosslinked, formation temperature conditions, and other factors known to those individuals skilled in the art.
  • the crosslinkable aqueous polymer compositions may further comprise a crosslinking delaying agent, such as a polysaccharide crosslinking delaying agent derived from guar, guar derivatives, or cellulose derivatives.
  • the crosslinking delaying agent may be included in the crosslinkable aqueous polymer compositions, inter alia, to delay crosslinking of the crosslinkable aqueous polymer compositions until desired, such as after placement into the formation.
  • a crosslinking delaying agent such as a polysaccharide crosslinking delaying agent derived from guar, guar derivatives, or cellulose derivatives.
  • the crosslinking delaying agent may be included in the crosslinkable aqueous polymer compositions, inter alia, to delay crosslinking of the crosslinkable aqueous polymer compositions until desired, such as after placement into the formation.
  • One of ordinary skill in the art, with the benefit of this disclosure, will be able to determine appropriate amount of the crosslinking delaying agent to
  • Certain exemplary embodiments of the gelable compositions comprise gelable resin compositions that cure to form flexible gels. Unlike the curable resin compositions described below with respect to the consolidating fluids, which cure into hardened masses, the gelable resin compositions cure into flexible, gelled substances that form resilient gelled substances between the particulates of the treated zone of the unconsolidated formation.
  • the gelable resin compositions useful in accordance with exemplary embodiments of the present invention comprise a curable resin, a solvent, and a catalyst.
  • the compositions typically may form the semi-solid, gelled substances described above.
  • the curable resin compositions may further comprise one or more "flexibilizer additives" (described in more detail below) to provide flexibility to the cured compositions.
  • gelable resins examples include organic resins such as polyepoxide resins (e.g., Bisphenol a- epichlorohydrin resins), polyester resins, urea-aldehyde resins, furan resins, urethane resins, and mixtures thereof.
  • organic resins such as polyepoxide resins (e.g., Bisphenol a- epichlorohydrin resins), polyester resins, urea-aldehyde resins, furan resins, urethane resins, and mixtures thereof.
  • any solvent that is compatible with the gelable resin and achieves the desired viscosity effect is suitable for use in exemplary embodiments of the present invention.
  • solvents that may be used in the gelable resin compositions of the present invention include phenols, formaldehydes, furfuryl alcohols, furfurals, alcohols, ethers such as butyl glycidyl ether and cresyl glycidyl etherphenyl glycidyl ether, and combinations thereof.
  • the solvent comprises butyl lactate.
  • the solvent may be used to reduce the viscosity of the gelable resin composition from about 3 to about 3,000 centipoises ("cP") at 8O 0 F.
  • the solvent acts to provide flexibility to the cured composition.
  • the solvent may be included in the gelable resin composition in an amount sufficient to provide the desired viscosity effect.
  • the solvent used is included in the gelable resin composition in amount in the range of from about 5% to about 75% by weight of the curable resin.
  • any catalyst that may be used to cure an organic resin is suitable for use in exemplary embodiments of the present invention.
  • Suitable catalysts include internal and external catalysts.
  • the catalyst chosen is an amide or a polyamide
  • no flexibilizer additive should be required because, inter alia, such catalysts should cause the gelable resin composition to convert into the desired semi-solid, gelled substance.
  • Other suitable catalysts such as an amine, a polyamine, methylene dianiline, and other curing agents known in the art
  • the catalyst used is included in the gelable resin composition, whether a flexibilizer additive is included or not, in an amount in the range of from about 5% to about 75% by weight of the curable resin. In some exemplary embodiments of the present invention, the catalyst used is included in the gelable resin composition in an amount in the range of from about 20% to about 75% by weight of the curable resin.
  • flexibilizer additives may be used, inter alia, to provide flexibility to the gelled substances formed from the curable resin compositions.
  • Flexibilizer additives may be used where the catalyst chosen would cause the gelable resin composition to cure into a hard and brittle material rather than a desired gelled substance.
  • flexibilizer additives may be used where the catalyst chosen is not an amide or polyamide.
  • suitable flexibilizer additives include an organic ester, an oxygenated organic solvent, an aromatic solvent, and combinations thereof. Of these, ethers, such as diburyl phthalate, may be used in certain exemplary embodiments.
  • the flexibilizer additive may be included in the gelable resin composition in an amount in the range of from about 5% to about 80% by weight of the curable resin. In some embodiments of the present invention, the flexibilizer additive may be included in the curable resin composition in an amount in the range of from about 20% to about 45% by weight of the curable resin. 4.
  • suitable polymerizable organic monomer compositions for use in the sealing compositions generally comprise an aqueous solvent, a water-soluble polymerizable organic monomer, an oxygen scavenger, and a primary initiator.
  • An example of a suitable polymerizable organic monomer composition is Perm-SealTM, which is available from Halliburton Energy Sendees, Inc.
  • Examples of suitable polymerizable organic monomer compositions are described in U.S. Pat. Nos. 5,358,051 and 5,335,726, the disclosures of which are incorporated herein by reference.
  • the aqueous solvent component of the polymerizable organic monomer composition generally may be fresh water, salt water, brine, seawater, or any other aqueous liquid that does not adversely react with the other components used in accordance with this invention or with the subterranean formation.
  • a variety of monomers are suitable for use as the water-soluble polymerizable organic monomers in exemplary embodiments of the present invention.
  • suitable monomers include acrylic acid, methacrylic acid, acrylamide, methacrylamide, 2- methacrylamido-2-methylpropane sulfonic acid, 2-dimethylacrylamide, vinyl sulfonic acid, N,N-dimethylaminoethyhnethacrylate, 2-triethylammoniumethylmethacrylate chloride, N,N- dimethyl-aminopropylmethacryl-arnide, memacrylainidepropyltriemylammonium chloride, N-vinyl pyrrolidone, vinyl-phosphonic acid, and methacryloyloxyethyl trimethylammonium sulfate, and mixtures thereof.
  • the water-soluble polymerizable organic monomer may be self-crosslinking.
  • suitable monomers which are self- crosslinking include hydroxyethylacrylate, hydroxymethylacrylate, hydroxyethylmethacrylate, N-hydroxymethylacrylamide, N-hydroxymethyl-methacrylamide, polyethylene glycol acrylate, polyethylene glycol methacrylate, polypropylene gylcol acrylate, polypropylene glycol methacrylate, and mixtures thereof.
  • hydroxyethylacrylate may be used in certain exemplary embodiments.
  • One example particular of a suitable monomer is hydroxyethylcelh ⁇ lose- vinyl phosphoric acid.
  • the water-soluble polymerizable organic monomer (or monomers where a mixture thereof is used) should be included in the polymerizable organic monomer composition in an amount sufficient to form the desired gelled substance after placement of the polymerizable organic monomer composition into the subterranean formation.
  • the water-soluble polymerizable organic monomer is included in the polymerizable organic monomer composition in an amount in the range of from about 1% to about 30% by weight of the aqueous-base fluid.
  • the water-soluble polymerizable organic monomer is included in the polymerizable organic monomer composition in an amount in the range of from about 1% to about 20% by weight of the aqueous-base fluid.
  • an oxygen scavenger such as stannous chloride
  • the stannous chloride may be pre-dissolved in a hydrochloric acid solution.
  • the stannous chloride may be dissolved in a 0.1% by weight aqueous hydrochloric acid solution in an amount of about 10% by weight of the resulting solution.
  • the resulting stannous chloride-hydrochloric acid solution may be included in the polymerizable organic monomer composition in an amount in the range of from about 0.1% to about 10% by weight of the polymerizable organic monomer composition.
  • the stannous chloride may be included in the polymerizable organic monomer composition of an exemplary embodiment of the present invention in an amount in the range of from about 0.005% to about 0.1% by weight of the polymerizable organic monomer composition.
  • the primary initiator is used, inter alia, to initiate polymerization of the water- soluble polymerizable organic monomer(s) used in an exemplary embodiment of the present invention.
  • Any compound or compounds that form free radicals in aqueous solution may be used as the primary initiator.
  • the free radicals act, inter alia, to initiate polymerization of the water-soluble polymerizable organic monomer present in the polymerizable organic monomer composition.
  • Compounds suitable for use as the primary initiator include alkali metal persulfates, peroxides, oxidation-reduction systems employing reducing agents, such as sulfites in combination with oxidizers, and azo polymerization initiators.
  • Preferred azo polymerization initiators include 2,2'-azobis(2-imidazole-2-hydroxyethyl) propane, 2,2'- azobis(2-aminopropane), 4,4'-azobis(4-cyanovaleric acid), and 2,2'-azobis(2-methyl-N-(2- hydroxyethyl) propionamide.
  • the primary initiator should be present in the polymerizable organic monomer composition in an amount sufficient to initiate polymerization of the water-soluble polymerizable organic monomer(s).
  • the primary initiator is present in the polymerizable organic monomer composition in an amount in the range of from about 0.1% to about 5% by weight of the water-soluble polymerizable organic monomer(s).
  • the polymerizable organic monomer compositions further may comprise a secondary initiator.
  • a secondary initiator may be used, for example, where the immature aqueous gel is placed into a subterranean formation that is relatively cool as compared to the surface mixing, such as when placed below the mud line in offshore operations.
  • the secondary initiator may be any suitable water-soluble compound or compounds that may react with the primary initiator to provide free radicals at a lower temperature.
  • An example of a suitable secondary initiator is triethanolamine.
  • the secondary initiator is present in the polymerizable organic monomer composition in an amount in the range of from about 0.1% to about 5% by weight of the water-soluble polymerizable organic monomer(s).
  • the polymerizable organic monomer compositions of exemplary embodiments of the present invention further may comprise a crosslinking agent for crosslinking the polymerizable organic monomer compositions in the desired gelled substance
  • the crosslinking agent is a molecule or complex containing a reactive transition metal cation, such as, e.g., trivalent chromium cations complexed or bonded to anions, atomic oxygen, or water.
  • suitable crosslinking agents include compounds or complexes containing chromic acetate and/or chromic chloride.
  • Other suitable transition metal cations include chromium VI within a redox system, aluminum III, iron II, iron III, and zirconium IV.
  • the crosslinking agent may be present in polymerizable organic monomer compositions in an amount in the range of from 0.01% to about 5% by weight of the polymerizable organic monomer composition.
  • fluids that comprise a relative-permeability modifier may be used as the sealing compositions, in accordance with exemplary embodiments of the present invention.
  • the relative-permeability modifier generally may not plug pore spaces within the treated formation to block flow therethrough, the relative-permeability modifier should adsorb onto surfaces within the formation so as to selectively reduce the formation's water permeability.
  • the formation may be treated with the relative- permeability modifier to form an artificial barrier in the treated formation that at least partially reduces the flow of water therethough.
  • the relative-permeability modifier should be included in the fluid in an amount sufficient to provide the desired artificial barrier.
  • the relative-permeability modifier may be included in the fluid in an amount in the range of from 0.01% to about 10% by weight of the fluid.
  • the relative- permeability modifier maybe included in the fluid in an amount in the range of from about 0.1% to about 1 % by weight of the fluid.
  • suitable relative-permeability modifiers may be any compound capable of selectively reducing the effective permeability of a formation to water without a comparable reduction of the formation's effective permeability to hydrocarbons.
  • suitable relative-permeability modifiers may be any compound capable of selectively reducing the effective permeability of a formation to water without a comparable reduction of the formation's effective permeability to hydrocarbons.
  • water-soluble polymers may be suitable for use as the relative-permeability modifiers.
  • suitable water-soluble polymers include homo-, co-, and terpolymers of acrylamide, 2-acrylamido-2-methyl propane sulfonic acid, N,N-dimethylacrylamide, vinyl pyrrolidone, dimethylamfnoethyl methacrylate, acrylic acid, dimethylaminopropyhnethacrylamide, vinyl amine, vinyl acetate, trimethylammoniumethyl methacrylate chloride, methacrylamide, hydroxyethyl acrylate, vinyl sulfonic acid, vinyl phosphomc acid, methacrylic acid, vinyl caprolactam, N- vinylformamide, N,N-diallylacetamide, dimethyldiallyl ammonium halide, itaconic acid, styrene sulfonic acid, methacrylamidoethyltrimethyl ammonium halide, quaternary salt derivatives of acrylamide quaternary salt derivatives of acrylic acid, and combinations thereof.
  • water-soluble polymers suitable for use as relative-permeability modifiers also may include hydrophobically modified polymers.
  • hydrophobically modified polymers refers to the incorporation into the hydrophilic polymer structure of hydrophobic groups, wherein the alkyl chain length is from about 4 to about 22 carbons. While these hydrophobically modified polymers have hydrophobic groups incorporated into the hydrophilic polymer structure, they should remain water-soluble.
  • a mole ratio of a hydrophilic monomer to the hydrophobic compound in the hydrophobically modified polymer is in the range of from about 99.98:0.02 to about 90:10, wherein the hydrophilic monomer is a calculated amount present in the hydrophilic polymer.
  • the hydrophobically modified polymers may comprise a polymer backbone that comprises polar heteroatoms.
  • the polar heteroatoms present within the polymer backbone of the hydrophobically modified polymers include, but are not limited to, oxygen, nitrogen, sulfur, or phosphorous.
  • Exemplary hydrophobically modified polymers may be synthesized utilizing any suitable technique.
  • the hydrophobically modified polymers may be a reaction product of a hydrophilic polymer and a hydrophobic compound.
  • the hydrophobically modified polymers may be prepared from a polymerization reaction comprising a hydrophilic monomer and a hydrophobically modified hydrophilic monomer.
  • the hydrophobically modified polymers may be pre-reacted before they are placed into the well bore 10.
  • the hydrophobically modified polymers may be prepared by an appropriate in situ reaction. Suitable hydrophobically modified polymers and methods for their preparation are described in more detail in U.S. Pat. Nos. 6,476,169 and 7,117,942, the disclosures of which are incorporated herein by reference. Those of ordinary skill in the art, with the benefit of this disclosure, will be able to determine other suitable methods for the synthesis of suitable hydrophobically modified polymers.
  • suitable hydrophobically modified polymers may be synthesized by the hydrophobic modification of a hydrophilic polymer.
  • the hydrophilic polymers suitable for forming the hydrophobically modified polymers used in the present invention should be capable of reacting with hydrophobic compounds.
  • Suitable hydropbilic polymers include, homo-, co-, or terpolymers such as, but not limited to, polyacrylamides, polyvinylamines, poly(vinylamines/vinyl alcohols), alkyl acrylate polymers in general, and combinations thereof.
  • alkyl acrylate polymers include polydimethylaminoethyl methacrylate, polydimethylaminopropyl methacrylamide, poly(acrylamide/dmie1hylarninoethyl methacrylate), poly(methacrylic acid/dimethylaminoethyl methacrylate), poly(2-acrylamido- 2-methyl propane sulfonic acid/dimethylaminoethyl methacrylate), poly(acrylamide/dimethylaminopropyl methacrylamide), P°ly (acrylic acid/dimethylaminopropyl methacrylamide), and poly(methacrylic acid/dimethylaminopropyl methacrylamide).
  • the hydrophilic polymers comprise a polymer backbone and reactive amino groups in the polymer backbone or as pendant groups, the reactive amino groups capable of reacting with hydrophobic compounds.
  • the hydrophilic polymers comprise dialkyl amino pendant groups.
  • the hydrophilic polymers comprise a dimethyl amino pendant group and a monomer comprising dimethylam ⁇ noethyl methacrylate or drmethylaminopropyl methacrylamide.
  • the hydrophilic polymers comprise a polymer backbone that comprises polar heteroatoms, wherein the polar heteroatoms present within the polymer backbone of the hydrophilic polymers include oxygen, nitrogen, sulfur, or phosphorous.
  • Suitable hydrophilic polymers that comprise polar heteroatoms within the polymer backbone include homo-, co-, or terpolymers, such as, but not limited to, celluloses, chitosans, polyamides, polyetheramines, polyethyleneimines, polyhydroxyetherarnines, polylysines, polysulfones, gums, starches, and combinations thereof.
  • the starch is a cationic starch.
  • a suitable cationic starch may be formed by reacting a starch, such as corn, maize, waxy maize, potato, tapioca, or the like, with the reaction product of epichlorohydrin and trialkylamine.
  • the hydrophobic compounds that are capable of reacting with the hydrophilic polymers include alkyl halides, sulfonates, sulfates, organic acids, and organic acid derivatives.
  • suitable organic acids and derivatives thereof include octenyl succinic acid; dodecenyl succinic acid; and anhydrides, esters, imides, and amides of octenyl succinic acid or dodecenyl succinic acid.
  • the hydrophobic compounds may have an alkyl chain length of from about 4 to about 22 carbons. In another exemplary embodiment, the hydrophobic compounds may have an alkyl chain length of from about 7 to about 22 carbons.
  • the hydrophobic compounds may have an alkyl chain length of from about 12 to about 18 carbons.
  • the reaction between the hydrophobic compound and hydrophilic polymer may result in the quaternization of at least some of the hydrophilic polymer amino groups with an alkyl halide, wherein the alkyl chain length is from about 4 to about 22 carbons.
  • suitable hydrophobically modified polymers also may be prepared from a polymerization reaction comprising a hydrophilic monomer and a hydrophobically modified hydrophilic monomer.
  • the hydrophobically modified polymers synthesized from the polymerization reactions may have estimated molecular weights in the range of from about 100,000 to about 10,000,000 and mole ratios of the hydrophilic monomer(s) to the hydrophobically modified hydrophilic monomer(s) in the range of from about 99.98:0.02 to about 90:10.
  • hydrophilic monomers may be used to form the hydrophobically modified polymers useful in the present invention.
  • suitable hydrophilic monomers include acrylamide, 2-acrylamido-2-methyl propane sulfonic acid, N,N- dimethylacrylamide, vinyl pyrrolidone, dimethylaminoethyl methacrylate, acrylic acid, dimemylaminopropylmethacrylamide, vinyl amine, vinyl acetate, Mmethylamrnoniurnethyl methacrylate chloride, methacrylamide, hydroxyethyl acrylate, vinyl sulfonic acid, vinyl phosphonic acid, methacrylic acid, vinyl caprolactam, N-vinylformamide, N,N- diallylacetamide, dimethyldiallyl ammonium halide, itaconic acid, styrene sulfonic acid, methacrylamidoethyltrimethyl ammonium halide, quaternary salt derivatives of acryl
  • hydrophobically modified hydrophilic monomers also may be used to form the hydrophobically modified polymers useful in exemplary embodiments of the present invention.
  • suitable hydrophobically modified hydrophilic monomers include alkyl acrylates, alkyl methacrylates, alkyl acrylamides, alkyl methacrylamides alkyl dimethylammoniumethyl methacrylate halides, and alkyl dimethylammoniumpropyl methacrylamide halides, wherein the alkyl groups have from about 4 to about 22 carbon atoms. In another exemplary embodiment, the alkyl groups have from about 7 to about 22 carbons. In another exemplary embodiment, the alkyl groups have from about 12 to about 18 carbons.
  • the hydrophobically modified hydrophilic monomer comprises octadecyldimethylarnmoniumethyl methacrylate bromide, hexadecyldimethylammoniumethyl methacrylate bromide, hexadecyldimethylammoniumpropyl methacrylamide bromide, 2-ethylhexyl methacrylate, or hexadecyl methacrylamide.
  • Suitable hydrophobically modified polymers that may be formed from the above-described reactions include acrylamide/octadecyldimethylammoriiumethyl methacrylate bromide copolymer, dimethylamino ethyl methacrylate/vinyl pyrrolidone/hexadecyldimethylammoniumethyl methacrylate bromide terpolymer, and acrylamide/2-acrylainido-2-methyl propane sulfonic acid/2-ethylhexyl methacrylate terpolymer.
  • Another suitable hydrophobically modified polymer formed from the above- described reaction comprises an amino methacrylate/alkyl amino methacrylate copolymer.
  • a suitable dimethlyaminoethyl memacrylate/alkyl-dimethylammoniumethyl methacrylate copolymer is a dimethylaminoethyl methacrylate/hexadecyl-dimethylammoniumethyl methacrylate copolymer.
  • these copolymers may be formed by reactions with a variety of alkyl halides.
  • the hydrophobically modified polymer may comprise a dimethylaminoethyl methacrylate/hexadecyl-dimethylammoniumethyl methacrylate bromide copolymer.
  • a consolidating fluid may be introduced into a portion of a subterranean formation to consolidate the treated portion of the formation.
  • the consolidating fluid may be any fluid suitable for enhancing the grain-to-grain (or grain-to-formation) contact between particulates in the treated portion of the subterranean formation so that the particulates are stabilized, locked in place, or at least partially immobilized such that they are resistant to flowing with any produced or injected fluids.
  • the consolidating fluid should inhibit dislodged fines from migrating with any subsequently produced or injected fluids.
  • suitable consolidating fluids include tackifying fluids, resin compositions, and gelable compositions.
  • an exemplary embodiment of the consolidating fluids used in the present invention may comprise a tackifying agent.
  • Suitable tackifying agents are substances that are (or may be activated to become) tacky and, thus, impart a degree of consolidation to unconsolidated particulates in the subterranean formation. In this manner, the particulates may be stabilized, locked in place, or at least partially immobilized such that they are resistant to flowing with fluids that are subsequently produced or injected.
  • Suitable tackifying agents may not be significantly tacky when placed into the formation, but may be capable of being "activated" (that is destabilized, coalesced and/or reacted) to transform into a tacky compound at a desirable time. Such activation may occur before, during, or after the introduction of the tackifying fluid into the subterranean formation. Examples of suitable tackifying agents are described in more detail above with respect to the exemplar ⁇ ' sealing compositions.
  • a consolidating fluid that may be used in an exemplary embodiment of the present invention may comprise a resin.
  • Resins suitable for use may include any resin that is capable of consolidating the treated formation into a hardened, consolidated mass. Examples of suitable resins are described in more detail above with respect to the exemplary sealing compositions.
  • suitable gelable compositions should cure to form a gel.
  • Gelable compositions suitable for use in exemplary embodiments of the present invention include those compositions that cure to form a semi-solid, immovable, gel-like substance. Prior to curing, the gelable compositions should have low viscosities and be capable of flowing in pipe and into the subterranean formation.
  • the gelable composition may be any gelable liquid composition capable of converting into a gelled substance capable of substantially plugging the permeability of the formation while allowing the formation to remain flexible.
  • the term "flexible” refers to a state wherein the treated formation is relatively malleable and elastic and able to withstand substantial pressure cycling without substantial breakdown of the formation.
  • the resultant gelled substance stabilizes the treated portion of the formation while allowing the formation to absorb the stresses created during pressure cycling.
  • the gelled substance may aid in preventing breakdown of the formation both by stabilizing and by adding flexibility to the treated region.
  • Exemplary gelable compositions are described in more detail above with respect to the exemplary sealing compositions.

Abstract

Disclosed embodiments relate to methods of completing wells in subterranean formations. An exemplary embodiment comprises forming an artificial barrier to water flow, wherein the artificial barrier is located at or above a hydrocarbon-water interface between a water-bearing formation zone and a hydrocarbon-bearing formation zone. The exemplary embodiment further comprises consolidating a portion of the hydrocarbon-bearing formation zone, wherein the artificial barrier is located between the consolidated portion of the hydrocarbon-bearing formation zone and the water-bearing formation zone.

Description

METHODS OF COMPLETING WELLS FOR CONTROLLING WATER AND PARTICULATE PRODUCTION
BACKGROUND
[0001] The present disclosure relates to methods of completing wells in subterranean formations, such as in unconsolidated subterranean formations. More particularly, the present disclosure relates to methods of completing wells in unconsolidated subterranean formations for controlling water and particulate production.
[0002] Before desirable fluids (e.g., oil, gas, etc.) may be produced from a well bore that has been drilled into a subterranean formation, the well typically must be completed. Well completions may involve a number of stages, including the installation of additional equipment into the well and the performance of procedures to prepare the well for production. By way of example, well completions may include perforating casing that is cemented into the well bore so that fluids can flow, for example, from the formation and into the well bore. Completing the well may also include the installation of production tubing inside the well bore through which fluids may be produced from the bottom of the well bore to the surface. Well completions also may involve a number of other procedures performed in the well and to the surrounding formation, for example, to address issues related to undesired particulate and water production.
[0003] Additional procedures also may be needed when wells are completed in certain portions of a subterranean formation, such as in unconsolidated subterranean formations, to prevent undesirable particulate production. As used in this disclosure, the phrase "unconsolidated subterranean formation" refers to a subterranean formation that contains loose particulates and/or particulates bonded with insufficient bond strength to withstand forces created by the production (or injection) of fluids through the formation. These particulates present in the unconsolidated subterranean formation may include, for example, sand, crushed gravel, crushed proppant, fines, and the like. When the well is placed into production, these particulates may migrate out of the formation with the fluids produced by the wells. The presence of such particulates in produced fluids may be undesirable in that the particulates may, for example, abrade downhole and surface equipment (e.g., pumps, flow lines, etc.) and/or reduce the production of desired fluids from the well. By way of example, the migrating particulates may clog flow paths, such as formation pores, perforations, and the like, thereby reducing production.
[0004] A number of well completion techniques have been developed to control particulate production in unconsolidated subterranean formations. One technique of controlling particulate production includes placing a filtration bed containing gravel (e.g., a "gravel pack") near the well bore to provide a physical barrier to the migration of particulates with the production (or injection) of fluids. Typically, such "gravel-packing operations" involve the pumping and placement of a quantity of gravel into the unconsolidated formation in an area adjacent to a well bore. One common type of gravel-packing operation involves placing a screen in the well bore and packing the surrounding annulus between the screen and the well bore with gravel of a specific size designed to prevent the passage of formation sand. The screen is generally a filter assembly used to retain the gravel placed during the gravel- pack operation.
[0005] Another technique used to control particulates in unconsolidated formations involves application of a consolidating fluid (e.g., resins, tackiflers, etc.) to consolidate portions of the unconsolidated formation into stable, permeable masses. In general, the consolidating fluid should enhance the grain-to-grain (or grain-to-formation) contact between particulates in the treated portion of the subterranean formation so that the particulates are stabilized, locked in place, or at least partially immobilized such that they are resistant to flowing with produced or injected fluids.
[0006] In addition, the undesired production of water may constitute a major expense in the production of hydrocarbons from subterranean formations, for example, due to the energy expended in producing, separating, and disposing of the water. In addition, when produced through unconsolidated subterranean formations, the water may also have an undesirable effect on the migration of formation sands. While wells are typically completed in hydrocarbon-producing formations, a water-bearing zone may occasionally be adjacent to the hydrocarbon-producing formation. In some instances, the water may be communicated with the hydrocarbon-producing formation by way of fractures and/or high-permeability streaks. In addition, undesired water production may be caused by a variety of other occurrences, including, for example, water coning, water cresting, bottom water, channeling at the well bore (e.g., channels behind casing formed by imperfect bonding between cement and casing), and the like.
[0007] Accordingly, well completions may include procedures to address issues that may be encountered with the undesired production of water. One attempt to address these issues has been to inject sealing compositions into the formation to form an artificial barrier between the water-bearing zone and the hydrocarbon-producing formation. By way of example, a gelable fluid may be introduced into the formation in a flowable state and thereafter form a gel in the formation that plugs off formation flow paths to eliminate, or at least reduce, the flow of water. Crosslinkable gels have also been used in a similar manner. In addition, certain polymers (commonly referred to as "relative-permeability modifiers") may be used to reduce the formation's effective permeability to water without a comparable reduction in the formation's effective permeability to hydrocarbons. The use of relative- permeability modifiers may be desirable, for example, where hydrocarbons will be produced from the treated portion of the formation.
SUMMARY
[0008] The present disclosure relates to methods of completing wells in subterranean formations, such as in unconsolidated subterranean formations. More particularly, the present disclosure relates to methods of completing wells in unconsolidated subterranean formations for controlling water and particulate production.
[0009] An exemplary embodiment of the present invention provides a method of completing a well. The method comprises forming an artificial barrier to water flow, wherein the artificial barrier is located at or above a hydrocarbon-water interface between a waterbearing formation zone and a hydrocarbon-bearing formation zone. The method further comprises consolidating a portion of the hydrocarbon-bearing formation zone, wherein the artificial barrier is located between the consolidated portion of the hydrocarbon-bearing formation zone and the water-bearing formation zone.
[0010] Another exemplary embodiment of the present invention provides a method of completing a well for controlling water and particulate production. The method comprises identifying a hydrocarbon-water interface between a hydrocarbon-bearing formation zone and a water-bearing formation zone. The method further comprises perforating a first interval of a casing, and introducing a sealing composition into one or more subterranean formations surrounding the first interval to form an artificial barrier to water flow. The artificial barrier is located either at or above the hydrocarbon-water interface. The method further comprises perforating a second interval of the casing, wherein the second interval is located above the first interval. The method further comprises introducing a consolidating fluid into one or more subterranean formations surrounding the second interval so as to consolidate at least a portion of the one or more subterranean formations.
[0011] Another exemplary embodiment of the present invention provides a method of completing a well for controlling water and particulate production. The method comprises positioning a jetting tool at a first location in a well bore and perforating a first interval of casing at the first location. The perforating of the first interval comprises using the jetting tool to form one or more perforations that penetrate through the casing. The method further comprises introducing a sealing composition through the jetting tool and into one or more subterranean formations surrounding the first interval to form an artificial barrier to water flow. Either the artificial barrier is adjacent to a hydrocarbon-water interface between a hydrocarbon-bearing formation zone and a water-bearing formation zone, or a bottom of the artificial barrier is located no more than about ten feet above the hydrocarbon-water interface. The method further comprises positioning the jetting tool in the well bore at a second location above the first location, and perforating a second interval of casing at the second location in the well bore. The perforating of the second interval comprises using the jetting tool to form one or more perforations that penetrate through the casing. The method further comprises introducing a consolidating fluid through the jetting tool and into one or more subterranean formations surrounding the second interval so as to consolidate at least a portion of the one or more subterranean formations.
[0012] The features and advantages of the present invention will be apparent to those skilled in the art upon reading the following description of specific embodiments with reference to the accompanying drawings.
DRAWINGS
[0013] These drawings illustrate certain aspects of the present invention disclosure and should not be used to limit or define the invention. [0014] Figure 1 is a cross-sectional, side view of a subterranean formation that is penetrated by a cased well bore, in accordance with exemplary embodiments of the present invention;
[0015] Figure 2 is a cross-sectional, side view of the subterranean formation of Figure 1 after treatment with a sealing composition to form an artificial barrier, in accordance with exemplar}' embodiments of the present invention;
[0016] Figure 3 is a cross-sectional, top view of the treated subterranean formation of Figure 2 taken along line 3-3, in accordance with exemplary embodiments of the present invention;
[0017] Figure 4 is a cross-sectional, side view of the treated subterranean formation of Figure 2 after additional treatment with a consolidating fluid, in accordance with exemplary embodiments of the present invention;
[0018] Figure 5 is a cross-sectional, top view of the treated subterranean formation of Figure 4 taken along line 5-5, in accordance with exemplary embodiments of the present invention; and
[0019] Figure 6 is a cross-sectional, top view of the treated subterranean formation of Figure 4 taken along line 5-5, after an additional fracturing treatment, in accordance with exemplary embodiments of the present invention.
DETAILED DESCRIPTION OF SPECIFIC EMBODIMENTS
[0020] The present disclosure relates to methods of completing wells in subterranean formations, such as in unconsolidated subterranean formations. More particularly, the present disclosure relates to methods of completing wells in unconsolidated subterranean formations for controlling water and particulate production.
I. Exemplary Well Completion
[0021] Turning to the drawings and referring first to Figure 1, a well bore 10 is shown that penetrates a hydrocarbon-bearing zone 12 and a water-bearing zone 14. Even though Figure 1 depicts the well bore 10 as a vertical well bore, the methods of the present invention may be suitable for use in deviated or otherwise formed portions of wells. Moreover, as those of ordinary skill in the art will appreciate, exemplary embodiments of the present invention are applicable for the treatment of both production and injection wells. In the illustrated embodiment, well bore 10 is lined with casing 16 that is cemented to the subterranean formation by cement 18. Those of ordinary skill in the art will appreciate the circumstances when well bore 10 should or should not be cased and whether such casing should or should not be cemented.
[0022] At least a portion of the hydrocarbon-bearing zone 12 may be an unconsolidated formation that contains loose particulates and/or particulates bonded with insufficient bond strength to withstand forces created by the production of fluids through the formation. Accordingly, when the well is completed and the hydrocarbon-bearing zone 12 is placed into production, these particulates may undesirably migrate out of the formation with the fluids produced by the well. Moreover, as illustrated, the hydrocarbon-bearing zone 12 may be adjacent to a water-bearing zone 14. Due to openings into the well bore 10 by perforations, channels behind the casing 16 resulting from incomplete bonding between the casing 16 and the cement 18, fractures, high-permeability streaks, or a variety of other occurrences (e.g., water coning, water cresting, etc.), undesired water production from the water-bearing zone 14 may also occur when the hydrocarbon-bearing zone 12 is placed into production. Exemplary embodiments of the present invention generally address these issues of particulate and water production through successive treatments of different formation intervals with a sealing composition to form an artificial barrier that prevents water flow and with a consolidating fluid to control particulate production.
[0023] Referring now to Figures 2 and 3, in accordance with exemplary embodiments of the present invention, completion of the well may include identifying the location of the hydrocarbon- water interface 20, perforating a first interval 22 of the well bore 10, and introducing a sealing composition into the portion of the subterranean formation surrounding the first interval 22 so that an artificial barrier 24 to water flow is formed. Those of ordinary skill in the art will appreciate that identification of the hydrocarbon-water interface 20 may include identifying the location of the water-bearing zone 14 so that the location of the hydrocarbon-water interface 20 may be identified. In addition, the location of the waterbearing zone 14 and the location of the hydrocarbon- water interface 20 may be identified using any suitable technique, including, for example, logging after a well bore is drilled or logging while drilling.
[0024] While Figure 2 depicts the first interval 22 as being above the hydrocarbon- water interface 20, those of ordinary skill in the art will appreciate that the first interval 22 may be at any suitable location for the formation of the artificial barrier 24 to water flow. In certain exemplary embodiments, the artificial barrier 24 may be formed at the hydrocarbon- water interface. In another embodiment, the bottom of the artificial barrier 24 may be located about five feet, about ten feet or even greater above the hydrocarbon-water interface 20, for example, to effectively control water coning or cresting. Moreover, in certain exemplary embodiments, placing the top of the artificial barrier 24 above the hydrocarbon-water interface 20 should prevent the flow of water from the water-bearing zone 14 to the hydrocarbon-bearing zone 12. In certain exemplary embodiments, the artificial barrier 24 may overlap the hydrocarbon water interface 20. Accordingly, the first interval 22 may be located at a distance above (e.g., within about five feet, ten feet or greater) the hydrocarbon- water interface 20. Moreover, the first interval 22 may have any suitable length (L) for the desired treatment. By way of example, the first interval 22 may have a length (L) in the range of from about 1 foot to about 50 feet.
[0025] As previously mentioned, exemplary embodiments of the present invention may include perforating a first interval 22 of the well bore 10. In the illustrated embodiment, perforations 26 may be formed that penetrate through the casing 16 and the cement sheath 18 and into the formation. As will be discussed in more detail below, the portion of the hydrocarbon-bearing zone 12 surrounding the first interval 22 may then be treated through the perforations 26 with a sealing composition to form an artificial barrier 24 to prevent, or at least substantially reduce, the migration of water from the water-bearing zone 14 to the hydrocarbon-bearing zone 12.
[0026] While the first interval 22 may be perforated using any suitable technique, an exemplary embodiment utilizes a jetting tool 28, as illustrated by FIG. 2. Jetting tool 28 may be any suitable assembly for use in subterranean operations through which a fluid may be jetted at high pressures. By way of example, when used to form the perforations 26, the jetting tool 28 should be configured to jet a fluid against the casing 16 and the cement sheath 18 such that perforations 26 may be formed. As illustrated, jetting tool 28 may contain ports 30 for discharging a fluid from the jetting tool 28. In some exemplary embodiments, the ports 30 form discharge jets as a result of a high pressure fluid forced out of relatively small ports. In other exemplary embodiments, fluid jet forming nozzles ma}' be connected within the ports 30. Examples of suitable jetting tools are described in U.S. Pat. Nos. 5,765,642 and 5,499,678, the disclosures of which are incorporated herein by reference. In operation, the jetting tool 28 may be positioned in the well bore 10 adjacent the portion of the well bore 10 to be perforated, such as the first interval 22. As illustrated, the jetting tool 28 may be coupled to a work string 32 (e.g., piping, coiled tubing, etc.) and lowered into the well bore 10 to the desired position. Once trie jetting tool 28 has been so positioned, a fluid may be pumped down through the work string 32, into the jetting tool 28, out through the ports 30, and against the interior surface of the casing 16 causing perforations 26 to be formed through the casing 16 and the cement sheath 18. Those of ordinary skill in the art will appreciate that abrasives (e.g., sand) may be included in the jetted fluid.
[0027] In accordance with exemplary embodiments, a sealing composition may be introduced into the portion of the subterranean formation surrounding the first interval 22 so that an artificial barrier 24 to water flow is formed. In general, the sealing composition may be any suitable composition suitable for forming an artificial barrier (such as artificial barrier 24) to water flow in the treated portion of the subterranean formation such that the flow of water therethrough is eliminated or at least substantially reduced. In certain exemplary embodiments, the sealing composition should form a substantially impenetrable barrier that eliminates, or at least partially reduces, the migration of any fluids between the water-bearing zone 14 and the hydrocarbon-bearing zone 12, or vice versa. By way of example, the sealing composition should be able to penetrate into the formation and form an artificial barrier therein that plugs off pore spaces to water flow. Examples of suitable sealing compositions are described in more detail below.
[0028] Any suitable technique may be used for the delivery of the sealing composition into the portion of the hydrocarbon-bearing zone 12 surrounding the first interval 22. For example, bull heading, coil tubing or jointed pipe (e.g., with straddle packers, jetting tools, etc.), or any other suitable technique may be used. In certain exemplary embodiments, the sealing composition may be injected into the hydrocarbon- bearing formation 12 by the jetting tool 28 while the jetting tool 28 is still in position in the well bore 10. For example, as illustrated by FIG. 2, the jetting tool 28 may be used for the delivery of the sealing composition into the portion of the hydrocarbon-bearing formation 12 that surrounds the first interval 22. Utilization of jetting tool 28 may reduce the need for equipment, such as packers, to isolate the treated interval (e.g., first interval 22). Alternatively, the sealing composition may be injected through the amulus 42 between the work string 32 and the casing 16. It should be noted that, to reduce the potential for the undesired fracturing of the first interval 22, the sealing composition may be introduced into the hydrocarbon-bearing formation 12 at matrix flow rates. By way of example, the sealing composition may be introduced at a flow rate in the range of from about 0.25 barrels to about 3 barrels per minute, depending, for example, on the length of the first interval 22. However, those of ordinary skill in the art will appreciate that these flow rates are merely exemplary, and the present invention is applicable to flow rates outside these ranges.
[0029] In addition, a sufficient amount of the sealing composition should be introduced such that the sealing composition has the desired penetration into the formation. In accordance with exemplary embodiments, it may be desired for the sealing composition to penetrate deep into the formation so that a sufficient artificial barrier 24 to water flow is fonned. By way of example, a sufficient amount of the sealing composition may be introduced such that it penetrates in the range of from about 5 feet to about 50 feet into the formation. However, as those of ordinary skill in the art will appreciate, the depth of penetration of the sealing composition into the formation will vary, for example, based on the particular application.
[0030] Referring now to Figures 4 and 5, exemplary embodiments of the present invention may comprise perforating a second interval 34 of the well bore 10, and introducing a consolidating fluid into the portion of the subterranean formation surrounding the. second interval 34. In general, the second interval 34 may be located above the first interval 22 so that the artificial barrier 24 prevents, or at least substantially reduces, water flow from the water-bearing formation 14 to the portion of the hydrocarbon bearing zone 12 surrounding the second interval 34. In this manner, the undesired production of water and particulates may be controlled once the well is put on production, in accordance with exemplary embodiments. Moreover, the second interval 34 may have any suitable length (L) for the desired consolidation and production rate. Those of ordinary skill in the art will appreciate that the (L) of the second interval 34 will vary based on a number of factors, including, for example, costs and the desired production rate.
[0031] As previously mentioned, exemplar}' embodiments of the present invention may include perforating the second interval 34 of the well bore 10. In the illustrated embodiment, perforations 36 may be formed in the second interval 34 that penetrate through the casing 16 and the cement sheath 18 and into the formation. As will be discussed in more detail below, the portion of the hydrocarbon-bearing zone 12 surrounding the second interval 34 may then be treated through the perforations 36 with a consolidating fluid for controlling particulate production. While the second interval 34 may be perforated using any suitable technique, an exemplary embodiment utilizes the jetting tool 28. Exemplary embodiments of the jetting tool 28 are described above with respect to perforating the first interval 22. In operation, the jetting tool 28 may be positioned in the well bore 10 adjacent the portion of the well bore 10 to be perforated, such as the second interval 34. By way of example, the jetting tool 28 may be raised from the first interval 22 to the second interval 34. Once the jetting tool 28 has been so positioned, a fluid may be pumped down through the work string 32, into the jetting tool 28, out through the ports 30, and against the interior surface of the casing 16 causing the perforations 36 to be formed through the casing 16 and the cement sheath 18. Those of ordinary skill in the art will appreciate that abrasives (e.g., sand) may be included in the jetted fluid.
[0032] La accordance with exemplar}' embodiments, a consolidating fluid may be introduced into the portion of the subterranean formation surrounding the second interval 34 to consolidate the treated portion of the formation into a consolidated region 38. In general, the consolidating fluid should be any suitable fluid for enhancing the grain-to-grain (or grain- to-formation) contact between particulates in the treated portion of the subterranean formation so that the particulates are stabilized, locked in place, or at least partially immobilized such that they are resistant to flowing with produced or injected fluids. Accordingly, after treatment with the consolidating fluid, the particulates in the consolidated region 38 should be inhibited from migrating with any subsequently produced or injected fluids. Examples of suitable consolidated fluids are described in more detail below. [0033] Any suitable technique may be used for the deliver}' of the consolidating fluid into the second interval 34, for example, bull heading, coil tubing or jointed pipe (e.g., with straddle packers, jetting tools, etc.), or any other suitable technique may be used. By way of example, as illustrated by FIG. 4, the jetting tool 28 may be used for the delivery of the consolidating fluid into the portion of the hydrocarbon-bearing zone 12 that surrounds the second interval 34. Utilization of the jetting tool 28 may reduce the need for additional equipment (e.g., packers) to isolate the second interval 34. In addition, utilization of the jetting tool 28 in the performance of these steps also may reduce the number of trips into the well bore 10, which in turn may reduce the time and expense of the well completion. Moreover, use of jetting tool 28 to introduce consolidating fluid may also reduce equipment needed to place the fluid, while reducing horsepower requirements. It should be noted that, to reduce the potential for the undesired fracturing of the second interval 34, the consolidating fluid may be introduced into the hydrocarbon-bearing formation 12 at matrix flow rates. By way of example, the consolidating fluid may be introduced at a flow rate in the range of from about 0.25 barrels to about 3 barrels per minute, depending on, for example, the length of perforated interval. However, those of ordinary skill in the art will appreciate that these flow rates are merely exemplary, and the present invention is applicable to flow rates outside these ranges.
[0034] Additionally, the consolidating fluid should achieve sufficient penetration into the formation for the particular application. As illustrated, the consolidating fluid may be introduced into the near well bore portion of the formation surrounding the second interval 34. For example, consolidation of the near well bore portion of the formation may alleviate potential problems associated with particulate production and thus help to control such undesired particulate production. Those of ordinary skill in the art will understand that the "near well bore portion" of a formation generally refers to the portion of a subterranean formation surrounding a well bore. For example, the "near well bore portion" may refer to the portion of the formation surrounding a well bore and having a depth of penetration of from about 1 to about 3 well bore diameters. However, as those of ordinary skill in the art will appreciate, the depth of penetration of the consolidating fluid into the formation may vary based on the particular application. [0035] While specific reference is made in the above discussion to treatment of the first interval 22 with the sealing composition followed by treatment of the second interval 34 with the consolidating fluid, it should be appreciated that this invention is not limited to such order of treatment. By way of example, the order of treatment may be reversed in that treatment of the second interval 34 with the consolidating fluid may occur prior to treatment of the first interval 22 with the sealing composition.
[0036] It should be noted that, after placement of the consolidating fluid into the formation, the well bore 10 optionally may be shut in for a period of time. The shutting in of the well bore 10 for a period of time may, inter alia, enhance the coating of the consolidating fluid onto the particulates and minimize the washing away of the consolidating fluid during any later subterranean operations. The necessary shut-in time period is dependent, among other things, on the composition of the consolidating fluid used and the temperature of the formation. Generally, the chosen period of time may be between about 0.5 hours and about 72 hours or longer. Determining the proper period of time to shut in the formation is within the ability of one skilled in the art with the benefit of this disclosure.
[0037] Those of ordinary skill in the art will appreciate that introduction of the consolidating fluid into the portion of the formation surrounding the second interval 34 may result in diminishing the formation's permeability. Reduction in permeability due to the consolidating fluid is based on a variety of factors, including the particular consolidating fluid used, the viscosity of the consolidating fluid, the volume of the consolidating fluid, volume of any after-flush treatment fluid, and the pumpability of the formation. However, in some exemplary embodiments, so that fluids may be produced from, and/or injected through, the consolidated region 38, it may be desired to at least partially restore permeability to the consolidated region 38 after this treatment. In certain exemplary embodiments, a fracturing step may be used to reconnect the well bore 10 with portions of the formation outside the consolidated region 38.
[0038] Referring now to Figure 6, one or more fractures 40 may be created or enhanced through the consolidated region 38 and into the surrounding formation to at least partially restore effective permeability to the consolidated region. As used in this disclosure, the term "enhancing" a fracture refers to the extension or enlargement of a natural or previously created fracture in the formation. The fracturing step may be accomplished by any suitable methodology. By way of example, a hydraulic-fracturing treatment may be used that includes introducing a fracturing fluid into the consolidated region 38 at a pressure sufficient to create or enhance one or more fractures 40. In certain exemplary embodiments, the fracturing step may utilize the j etting tool 28. By way of example, the j etting tool 28 may be used to initiate one or more fractures 40 in the consolidated region 38 by way of jetting a fluid through the perforations 36 and against the consolidated region 38. A fracturing fluid may also be pumped down through the annulus 42 between the work string 32 and the casing 16 and then into the consolidated region 38 at a pressure sufficient to create or enhance the one or more fractures 40. The fracturing fluid may be pumped down through the annulus 42 concurrently with the jetting of the fluid. One example of a suitable fracturing treatment is CobraMax M Fracturing Service, available from Halliburton Energy Services, Inc. hi certain exemplary embodiments, the fracturing fluid may comprise a viscosified fluid (e.g., a gel or a crosslinked gel). In certain embodiments, the fracturing fluid further may comprise proppant 44 that is deposited in the one or more fractures 40 to generate propped fractures. In certain exemplary embodiments, the proppant 44 majr be coated with a consolidating agent (e.g., a curable resin, a tackifying agent, etc.) so that the coated proppant forms a bondable, permeable mass in the one or more fractures 40, for example, to mitigate proppant flow back when the well is placed into production. By way of example, the proppant may be coated with an Expedite™ resin system, available from Halliburton Energy Services, Inc.
[0039] Alternatively, or in addition to the fracturing treatment, one or more after- flush fluids may be used to at least partially restore permeability to the consolidated region 38, if desired. "When used, the after-flush fluid may be introduced into the consolidated region 38 while the consolidating fluid is still in a flowing state. Among other things, the after-flush fluid generally acts to displace at least a portion of the consolidating fluid from flow paths in the consolidated region 38 and to force the displaced portions of the consolidating fluid further into the formation where it may have negligible impact on subsequent production. However, sufficient amounts of the consolidating fluid should remain in the consolidated region 38 to provide effective stabilization of the particulates therein. Generally, the after-flush fluid may be any fluid that does not undesirably react with the other components used or the subterranean formation. For example, the after-flush fluid may be an aqueous-based fluid, a non-aqueous based fluid (e.g., kerosene, toluene, diesel, or crude oil), or a gas (e.g., nitrogen or carbon dioxide).
[0040] Optionally, one or more pre-flush fluids may be introduced into the portion of the hydrocarbon-bearing zone 12 surrounding second interval 34. By way of example, the pre-flush fluid may be introduced into the formation to, for example, cleanout undesirable substances (e.g., oil, residue, or debris) from pore spaces in the matrix of the formation and/or to prepare the formation for subsequent placement of the consolidating fluid. In exemplary embodiments, an acidic pre-flush fluid may be used to, for example, dissolve undesirable substances in the formation. Examples of suitable pre-flush fluids include aqueous-based fluid, a non-aqueous based fluid (e.g., kerosene, xylene, toluene, diesel, or crude oil), or a gas (e.g., nitrogen or carbon dioxide). Aqueous-based fluids may comprise fresh water, salt water, brines, sea water, or combinations thereof. Further, one or more surfactants may be present in the pre-flush fluid, e.g., to aid a consolidating fluid in flowing to contact points between adjacent particulates in the formation.
II. Exemplary Sealing Compositions
[0041] hi accordance with exemplary embodiments, a sealing composition may be introduced into a portion of a subterranean formation to form an artificial barrier to water flow. As described above, the artificial barrier typically may be located between the waterbearing zone and the hydrocarbon-bearing zone so as to minimize the undesired production of water from the hydrocarbon-bearing zone, hi general, the sealing composition may be any composition suitable for forming an artificial barrier in the treated portion of the subterranean formation such that the flow of water therethrough is eliminated or at least substantially reduced. Examples of suitable sealing compositions may include tackifying fluids, resin compositions, and gelable compositions. In addition, examples of suitable sealing compositions may include fluids that comprise relative-permeability modifiers. As used in this disclosure, the phrase "relative-permeability modifier" refers to compounds that should reduce a formation's effective permeability to water without a comparable reduction in the formation's effective permeability to hydrocarbons. Those of ordinary skill in the art will appreciate that these sealing compositions are merely exemplary, and the present invention is applicable to other compositions for forming a suitable artificial barrier to the flow of water. Examples of suitable sealing compositions will be described in more detail as follows. A. Exemplary Tackifying Fluids
[0042] As previously mentioned, an exemplary embodiment of the sealing compositions used in the present invention may comprise a tackifying agent. Suitable tackifying agents are substances that are (or may be activated to become) tacky and thus adhere to unconsolidated particulates in the subterranean formation. In this manner, the tackifying agent may form a barrier in the treated portion of the formation. Suitable tackifying agents may not be significantly tacky when placed into the formation, but may be capable of being "activated" (that is destabilized, coalesced and/or reacted) to transform into a tacky compound at a desirable time. Such activation may occur before, during, or after the introduction of the tackifying fluid into the subterranean formation.
[0043] One type of tackifying agent suitable for use includes a non-aqueous tackifying agent. An example of a suitable non-aqueous tackifying agent comprises polyamides that are liquids or in solution at the temperature of the formation such that they are, by themselves, non-hardening when introduced into the subterranean formation. One exemplary embodiment of a suitable tackifying agent comprises a condensation reaction product that comprises commercially available polyacids and a polyamine. Such commercial products include compounds such as mixtures of C36 dibasic acids containing some trimer and higher oligomers and also small amounts of monomer acids that are reacted with polyamines. Other polyacids include trimer acids, synthetic acids produced from fatty acids, maleic anhydride, acrylic acid, and the like. Such acid compounds are commercially available from companies such as Witco Corporation, Union Camp, Chemtall, and Emery Industries. The reaction products are available from, for example, Champion Technologies, Inc. and Witco Corporation. An example of a suitable non- aqueous tackifying agent is Sand Wedge Enhancement System, available from Halliburton Energy Sendees, Inc.
[0044] Additional exemplary compounds which may be used as non-aqueous tackifying agents include liquids and solutions of, for example, polyesters, polycarbonates and polycarbamates, natural resins such as shellac and the like. Other suitable non-aqueous tackifying agents are described in U.S. Pat. Nos. 5,853,048 and 5,833,000, the disclosures of which are incorporated herein by reference. [0045] Non-aqueous tackifying agents may be either used such that they form a non- hardenitig coating or they may be combined with a multifunctional material capable of reacting with the tackifying compound to form a hardened coating. A "hardened coating" as used in this disclosure means that the reaction of the tackifying compound with the multifunctional material will result in a substantially non-flowable reaction product that exhibits a higher compressive strength in a consolidated agglomerate than the tackifying compound alone with the particulates. In this instance, the tackifying agent may function similarly to a hardenable resin.
[0046] Multifunctional materials suitable for use in the present invention include aldehydes, dialdehydes such as glutaraldehyde, hemiacetals or aldehyde releasing compounds, diacid halides, dihalides such as dichlorides and dibromides, polyacid anhydrides such as citric acid, epoxides, furfuraldehyde, glutaraldehyde, aldehyde condensates, and silyl-modified polyamide compounds and the like, and combinations thereof. Suitable silyl-modified polyamide compounds that may be used in exemplary embodiments of the present invention include those that are substantially self-hardening compositions capable of at least partially adhering to particulates in the unhardened state, and that are further capable of self hardening themselves to a substantially non-tacky state to which individual particulates such as formation fines will not adhere to, for example, in formation or proppant pack pore throats. Such silyl-modified polyamides may be based, for example, on the reaction product of a silating compound with a polyamide or a mixture of polyamides. The polyamide or mixture of polyamides may be one or more polyamide intermediate compounds obtained, for example, from the reaction of a polyacid (e.g., diacid or higher) with a polyamine (e.g., diamine or higher) to form a polyamide polymer with the elimination of water.
[0047] In some exemplary embodiments, the multifunctional material may be mixed with the tackifying agent in an amount of from about 0.01 to about 50 percent by weight of the tackifying agent to effect formation of the reaction product. In some exemplary embodiments, the multifunctional material may be present in an amount of from about 0.5 to about 1 percent by weight of the tackifying compound. Suitable multifunctional materials are described in U.S. Pat. No. 5,839,510, the disclosure of which is incorporated herein by reference. [0048] Solvents suitable for use with the tackifying agents include any solvent that is compatible with the tackifying agent and achieves the desired viscosity effect. The solvents that can be used in exemplary embodiments of the present invention preferably include those having high flash points (e.g., above about 125°F). Examples of solvents suitable for use in exemplary embodiments of the present invention include butylglycidyl ether, dipropylene glycol methyl ether, butyl bottom alcohol, dipropylene glycol dimethyl ether, diethyleneglycol methyl ether, ethyl enegly col butyl ether, methanol, butyl alcohol, isopropyl alcohol, diethyleneglycol butyl ether, propylene carbonate, d'limonene, 2-butoxy ethanol, butyl acetate, furfuryl acetate, butyl lactate, dimethyl sulfoxide, dimethyl formamide, fatty acid methyl esters, and combinations thereof. It is within the ability of one skilled in the art, with the benefit of this disclosure, to determine whether a solvent is needed to achieve a viscosity suitable to the subterranean conditions and, if so, how much.
[0049] Another type of tackifying agent suitable for use in an exemplary embodiment of the present invention includes aqueous tackifying agents. As used in this disclosure, the term "aqueous tackifying agent" refers to a tackifying agent that is soluble in water. Examples of suitable aqueous tackifying agents generally comprise charged polymers, that when in an aqueous solvent or solution, enhance the grain-to-grain contact between the individual particulates within the formation (e.g., proppant, gravel particulates, formation particulates, or other particulates), and may help bring about the consolidation of the particulates into a cohesive, flexible, and permeable mass. Examples of aqueous tackifying agents suitable for use in an exemplary embodiment of the present invention include acrylic acid polymers, acrylic acid ester polymers, acrylic acid derivative polymers, acrylic acid homopolymers, acrylic acid ester homopolymers (such as poly(methyl acrylate), poly (butyl acrylate), and poly(2-ethylhexyl acrylate)), acrylic acid ester copolymers, methacrylic acid derivative polymers, methacrylic acid homopolymers, methacrylic acid ester homopolymers (such as poly(methyl methacrylate), poly(butyl methacrylate), and poly(2-ethylhexyl methacrylate)), acrylamido-methyl-propane sulfonate polymers, acrylamido-methyl-propane sulfonate derivative polymers, acrylamido-methyl-propane sulfonate copolymers, and acrylic acid/acrylamido-methyl-propane sulfonate copolymers, and combinations thereof. Examples of suitable aqueous tackifying agents are FDP-S706-3 and FDP-S800-05, which are available from Halliburton Energy Services, Inc. Examples of suitable aqueous tackifying agents are described in U.S. Pat. No. 7,131,491 and U.S. Pat App. Pub. No. 2005/0277554, the disclosures of which are incorporated herein by reference.
[0050] Another example of a suitable aqueous tackifying agent comprises a benzyl coco di-(hydroxyethyl) quaternary amine, p-T-amyl-phenol condensed with formaldehyde, or a copolymer comprising from about 80% to about 100% Ci-30 alkylmethacrylate monomers and from about 0% to about 20% hydropbilic monomers. In some exemplary embodiments, the aqueous tackifying agent may comprise a copolymer that comprises from about 90% to about 99.5% 2-ethylhexylacrylate and from about 0.5% to about 10% acrylic acid. Suitable hydrophilic monomers may be any monomer that will provide polar oxygen-containing or mixogen-containing groups. Suitable hydrophilic monomers include dialJkyl amino alkyl (meth) acrylates and their quaternary addition and acid salts, acrylamide, N-(dialkyl amino alkyl) acrylamide, methacrylamides and their quaternary addition and acid salts, hydroxy alkyl (meth)acrylates, unsaturated carboxylic acids such as methacrylic acid or acrylic acid, hydroxyethyl acrylate, acrylamide, and the like. These copolymers can be made by any suitable emulsion polymerization technique. Examples of suitable tackifying agents are described in U.S. Pat. No. 5,249,627, the disclosure of which is incorporated herein by reference. Methods of producing these copolymers are disclosed in U.S. Pat. No. 4,670,501, the disclosure of which is incorporated herein by reference.
B. Exemplary Resin Compositions
[0051] Another example of a sealing composition that may be used in an exemplary embodiment of the present invention may comprise a resin. Resins suitable for use may include any suitable resin that is capable of forming a hardened, consolidated mass in the treated formation. The term "resin" as used herein includes any of numerous physically similar polymerized synthetics or chemically modified natural resins, including but not limited to thermoplastic materials and thermosetting materials. Many such resins are commonly used in subterranean consolidation operations, and some suitable resins include two-component epoxy based resins, novolak resins, polyepoxide resins, phenol-aldehyde resins, urea-aldehyde resins, urethane resins, phenolic resins, furan resins, furan/furfuryl alcohol resins, phenolic/latex resins, phenol formaldehyde resins, polyester resins and hybrids and copolymers thereof, polyurethane resins and hybrids and copolymers thereof, acrylate resins, and combinations thereof. Some suitable resins, such as epoxy resins, may be cured with an internal catalyst or activator so that when pumped downhole, they may be cured using only time and temperature. Other suitable resins, such as furan resins generally require a time-delayed catalyst or an external catalyst to help activate the polymerization of the resins if the cure temperature is low (e.g., less than 250° F) but will cure under the effect of time and temperature if the formation temperature is above about 2500F5 preferably above about 3000F. It is within the ability of one skilled in the art, with the benefit of this disclosure, to select a suitable resin for use in exemplary embodiments of the present invention and to determine whether a catalyst is needed to trigger curing. An example of a suitable resin is Sand Trap® Formation Consolidation Service, available from Halliburton Energy Services, Inc.
[0052] Selection of a suitable resin may be affected by the temperature of the subterranean formation to which the fluid will be introduced. By way of example, for subterranean formations having a bottom hole static temperature ("BHST") ranging from about 600F to about 25O0F, two-component epoxy-based resins comprising a hardenable resin component and a hardening agent component containing specific hardening agents may be preferred. For subterranean formations having a BHST ranging from about 3000F to about 6000F, a furan-based resin may be preferred. For subterranean formations having a BHST ranging from about 2000F to about 4000F, either a phenolic-based resin or a one-component HT epoxy-based resin may be suitable. For subterranean formations having a BHST of at least about 175°F, a phenol/phenol formaldehyde/furfuryl alcohol resin may also be suitable.
[0053] Any solvent that is compatible with the chosen resin and achieves the desired viscosity effect may be suitable for use with the resin. Some exemplary solvents are those having high flash points (e.g., about 1250F) because of, among other things, environmental and safety concerns; such solvents include butyl lactate, butylglycidyl ether, dipropylene glycol methyl ether, dipropylene glycol dimethyl ether, dimethyl formamide, diethyleneglycol methyl ether, ethyleneglycol butyl ether, diethyleneglycol butyl ether, propylene carbonate, methanol, butyl alcohol, d-limonene, fatty acid methyl esters, and combinations thereof. Other suitable solvents include aqueous dissolvable solvents such as, methanol, isopropanol, butanol, glycol ether solvents, and combinations thereof. Suitable glycol ether solvents include, but are not limited to, diethylene glycol methyl ether, dipropylene glycol methyl ether, 2-butoxy ethanol, ethers of a C2 to C6 dihydric alkanol containing at least one C1 to C6 alkyl group, mono ethers of dihydric alkanols, methoxypropanol, butoxyethanol, hexoxyethanol, and isomers thereof. Selection of an appropriate solvent is dependent on the resin chosen and is within the ability of one skilled in the art with the benefit of this disclosure.
C. Exemplary Gelable Compositions
[0054] An example of sealing compositions that may be used in an exemplary embodiment of the present invention comprises gelable compositions. In general, suitable gelable compositions should cure to form a gel. Gelable compositions suitable for use in exemplary embodiments of the present invention include those compositions that cure to form a semi-solid, immovable, gel-like substance. Prior to curing, the gelable compositions should have low viscosities and be capable of flowing in pipe and into the subterranean formation. The gelable composition may be any gelable liquid composition capable of converting into a gelled substance that substantially plugs the permeability of the formation. Accordingly, once placed into the formation, the gelable composition should form the desired artificial barrier. Examples of suitable gelable compositions include gelable aqueous silicate compositions, crosslinkable aqueous polymer compositions, gelable resins and polymerizable organic monomer compositions. Examples of suitable gelable compositions will be described in more detail as follows.
1. Exemplary Gelable Aqueous Silicate Compositions
[0055] In certain exemplary embodiments, the gelable compositions may comprise a gelable aqueous silicate composition. Suitable gelable aqueous silicate compositions for barrier formation generally comprise aqueous alkali metal silicate solution and a catalyst (e.g., a temperature-activated catalyst) for gelling the aqueous alkali metal silicate solution. An example of a suitable gelable aqueous silicate composition is Injectrol™, which is available from Halliburton Energy Services, Inc. Examples of suitable gelable aqueous silicate compositions are described in U.S. Pat. No. 4,466,831, the disclosure of which is incorporated herein by reference.
[0056] The aqueous alkali metal silicate solution component of the gelable aqueous silicate compositions generally may comprise an aqueous liquid and an alkali metal silicate. The aqueous liquid component of the aqueous alkali metal silicate solution generally may be fresh water, salt water (e.g., water containing one or more salts dissolved therein), brine (e.g., saturated salt water), seawater, or any other aqueous liquid that does not adversely react with the other components used in accordance with this invention or with the subterranean formation. Examples of suitable alkali metal silicates include one or more of sodium silicate, potassium silicate, lithium silicate, rubidium silicate, or cesium silicate. While sodium silicate exists in many forms, the sodium silicate that may be used in the aqueous alkali metal silicate solution may have a Na2OtO-SiO2 weight ratio in the range of from about 1 :2 to about 1 :4. By way of example, the sodium silicate may have a Na2CMo-SiO2 weight ratio in the range of about 1 :3.2. Generally, the alkali metal silicate ma}' be present in the aqueous alkali metal silicate solution component in an amount in the range of from about 0.1% to about 10% by weight of the aqueous alkali metal silicate solution component.
[0057] The temperature-activated catalyst component of the gelable aqueous silicate compositions is used, inter alia, to convert the gelable aqueous silicate compositions into the desired semi-solid, gel-like substance described above. Selection of a temperature-activated catalyst is related, at least in part, to the temperature of the subterranean formation to which the gelable aqueous silicate composition will be introduced. The temperature-activated catalysts that can be used in the gelable aqueous silicate compositions of exemplary embodiments of the present invention include, but are not limited to, ammonium sulfate (which is most suitable in the range of from about 60°F to about 24O0F); sodium acid pyrophosphate (which is most suitable in the range of from about 6O0F to about 2400F); citric acid (which is most suitable in the range of from about 6O0F to about 1200F); and ethyl acetate (which is most suitable in the range of from about 6O0F to about 1200F). Generally, the temperature-activated catalyst may be present in the gelable aqueous silicate composition in the range of from about 0.1% to about 5% by weight of the gelable aqueous silicate composition.
2. Exemplary Crosslinkable Aqueous Polymer Compositions
[0058] In other exemplary embodiments, the gelable compositions may comprise a crosslinkable aqueous polymer composition. Suitable crosslinkable aqueous polymer compositions for barrier formation generally comprise an aqueous solvent, a crosslinkable polymer, and a crosslinking agent. Such compositions are similar to those used to form gelled treatment fluids, such as fracturing fluids, but, according to the methods of exemplary embodiments of the present invention, they are not exposed to breakers or de-linkers so they retain their viscous nature over time. Moreover, suitable compositions should generally be resistant to breaking, for example, due to formation temperatures. An example of a suitable crosslinkable polymer composition is H2-Zero™, which is commercially available from Halliburton Energy Services, Lac. Examples of suitable crosslinkable aqueous polymer compositions are described in U.S. Pat. Nos. 5,836,392, 6,192,986, and 6,196,317, the disclosures of which are incorporated herein by reference.
[0059] The aqueous solvent may be any aqueous solvent in which the crosslinkable composition and the crosslinking agent may be dissolved, mixed, suspended, or dispersed therein to facilitate gel formation. For example, the aqueous solvent used may be fresh water, salt water, brine, seawater, or any other aqueous liquid that does not adversely react with the other components used in accordance with exemplary embodiments of the present invention or with the subterranean formation.
[0060] Examples of crosslinkable polymers that can be used in the crosslinkable aqueous polymer compositions include carboxylate-containing polymers and acrylamide- containing polymers. Examples of suitable acrylamide-containing polymers include polyacrylamide, partially hydrolyzed polyacrylamide, copolymers of acrylamide and acrylate, copolymers of acrylamide and 2-acrylamido-2-methylpropanesulfonic acid, carboxylate- containing terpolymers and tetrapolymers of acrylate. Additional examples of suitable crosslinkable polymers include hydratable polymers comprising polysaccharides and derivatives thereof and that contain one or more of the monosaccharide unit's galactose, mannose, glucoside, glucose, xylose, arabinose, fructose, glucuronic acid, or pyranosyl sulfate. Suitable natural hydratable polymers include, but are not limited to, guar gum, locust bean gum, tara, konjak, tamarind, starch, cellulose, karaya, xanthan, tragacanth, and carrageenan, and derivatives of all of the above. Suitable hydratable synthetic polymers and copolymers that may be used in the crosslinkable aqueous polymer compositions include polyacrylates, polymethacrylates, polyacrylamides, maleic anhydride, methylvinyl ether polymers, polyvinyl alcohols, and polyvinylpyrrolidone. The crosslinkable polymer used should be included in the crosslinkable aqueous polymer composition in an amount sufficient to form the desired gelled substance in the subterranean formation. In some exemplary embodiments of the present invention, the crosslinkable polymer may be included in the crosslinkable aqueous polymer composition in an amount in the range of from about 1% to about 30% by weight of the aqueous solvent. In another exemplary embodiment of the present invention, the crosslinkable polymer may be included in the crosslinkable aqueous polymer composition in an amount in the range of from about 1% to about 20% by weight of the aqueous solvent.
[0061] The crosslinkable aqueous polymer compositions of exemplary embodiments of the present invention further comprise a crosslinking agent for crosslinking the crosslinkable polymers to form the desired gelled substance. In some exemplary embodiments, the crosslinking agent may be a molecule or complex containing a reactive transition metal cation. An exemplary crosslinking agent comprises trivalent chromium cations complexed or bonded to anions, atomic oxygen, or water. Examples of suitable crosslinking agents include compounds or complexes containing chromic acetate and/or chromic chloride. Other suitable transition metal cations include chromium VI within a redox system, aluminum III, iron II, iron III, and zirconium IV. Organic crosslinkers may also be suitable, in certain exemplary embodiments. Examples of suitable organic crosslinkers include polyalkyleneimines, polyalkylenepolyamines (e.g., polyethyleneimine), chitosan, and mixtures thereof.
[0062] The crosslinking agent should be present in the crosslinkable aqueous polymer compositions of exemplary embodiments of the present invention in an amount sufficient to provide, inter alia, the desired degree of crosslinking. In some exemplary embodiments of the present invention, the crosslinking agent may be present in the crosslinkable aqueous polymer compositions of the present invention in an amount in the range of from about 0.01% to about 5% by weight of the crosslinkable aqueous polymer composition. The exact type and amount of crosslinking agent or agents used depends upon the specific crosslinkable polymer to be crosslinked, formation temperature conditions, and other factors known to those individuals skilled in the art.
[0063] Optionally, the crosslinkable aqueous polymer compositions may further comprise a crosslinking delaying agent, such as a polysaccharide crosslinking delaying agent derived from guar, guar derivatives, or cellulose derivatives. The crosslinking delaying agent may be included in the crosslinkable aqueous polymer compositions, inter alia, to delay crosslinking of the crosslinkable aqueous polymer compositions until desired, such as after placement into the formation. One of ordinary skill in the art, with the benefit of this disclosure, will be able to determine appropriate amount of the crosslinking delaying agent to include in the crosslinkable aqueous polymer compositions for a desired application.
3. Exemplary Gelable Resin Compositions
[0064] Certain exemplary embodiments of the gelable compositions comprise gelable resin compositions that cure to form flexible gels. Unlike the curable resin compositions described below with respect to the consolidating fluids, which cure into hardened masses, the gelable resin compositions cure into flexible, gelled substances that form resilient gelled substances between the particulates of the treated zone of the unconsolidated formation.
[0065] Generally, the gelable resin compositions useful in accordance with exemplary embodiments of the present invention comprise a curable resin, a solvent, and a catalyst. When certain catalysts, such as polyamides, are used in the curable resin compositions, the compositions typically may form the semi-solid, gelled substances described above. Where the catalyst used may cause the organic resin compositions to form hard, brittle material rather than the desired gelled substance, the curable resin compositions may further comprise one or more "flexibilizer additives" (described in more detail below) to provide flexibility to the cured compositions.
[0066] Examples of gelable resins that can be used in exemplary embodiments of the present invention include organic resins such as polyepoxide resins (e.g., Bisphenol a- epichlorohydrin resins), polyester resins, urea-aldehyde resins, furan resins, urethane resins, and mixtures thereof.
[0067] Any solvent that is compatible with the gelable resin and achieves the desired viscosity effect is suitable for use in exemplary embodiments of the present invention. Examples of solvents that may be used in the gelable resin compositions of the present invention include phenols, formaldehydes, furfuryl alcohols, furfurals, alcohols, ethers such as butyl glycidyl ether and cresyl glycidyl etherphenyl glycidyl ether, and combinations thereof. In some embodiments of the present invention, the solvent comprises butyl lactate. The solvent may be used to reduce the viscosity of the gelable resin composition from about 3 to about 3,000 centipoises ("cP") at 8O0F. Among other things, the solvent acts to provide flexibility to the cured composition. The solvent may be included in the gelable resin composition in an amount sufficient to provide the desired viscosity effect. Generally, the solvent used is included in the gelable resin composition in amount in the range of from about 5% to about 75% by weight of the curable resin.
[0068] Generally, any catalyst that may be used to cure an organic resin is suitable for use in exemplary embodiments of the present invention. Suitable catalysts include internal and external catalysts. When the catalyst chosen is an amide or a polyamide, generally no flexibilizer additive should be required because, inter alia, such catalysts should cause the gelable resin composition to convert into the desired semi-solid, gelled substance. Other suitable catalysts (such as an amine, a polyamine, methylene dianiline, and other curing agents known in the art) will tend to cure into a hard, brittle material and will thus benefit from the addition of a flexibilizer additive. Generally, the catalyst used is included in the gelable resin composition, whether a flexibilizer additive is included or not, in an amount in the range of from about 5% to about 75% by weight of the curable resin. In some exemplary embodiments of the present invention, the catalyst used is included in the gelable resin composition in an amount in the range of from about 20% to about 75% by weight of the curable resin.
[0069] As noted above, flexibilizer additives may be used, inter alia, to provide flexibility to the gelled substances formed from the curable resin compositions. Flexibilizer additives may be used where the catalyst chosen would cause the gelable resin composition to cure into a hard and brittle material rather than a desired gelled substance. For example, flexibilizer additives may be used where the catalyst chosen is not an amide or polyamide. Examples of suitable flexibilizer additives include an organic ester, an oxygenated organic solvent, an aromatic solvent, and combinations thereof. Of these, ethers, such as diburyl phthalate, may be used in certain exemplary embodiments. Where used, the flexibilizer additive may be included in the gelable resin composition in an amount in the range of from about 5% to about 80% by weight of the curable resin. In some embodiments of the present invention, the flexibilizer additive may be included in the curable resin composition in an amount in the range of from about 20% to about 45% by weight of the curable resin. 4. Exemplar}7 Polymerizable Organic Monomer Compositions
[0070] Examples of suitable polymerizable organic monomer compositions for use in the sealing compositions generally comprise an aqueous solvent, a water-soluble polymerizable organic monomer, an oxygen scavenger, and a primary initiator. An example of a suitable polymerizable organic monomer composition is Perm-Seal™, which is available from Halliburton Energy Sendees, Inc. Examples of suitable polymerizable organic monomer compositions are described in U.S. Pat. Nos. 5,358,051 and 5,335,726, the disclosures of which are incorporated herein by reference.
[0071] The aqueous solvent component of the polymerizable organic monomer composition generally may be fresh water, salt water, brine, seawater, or any other aqueous liquid that does not adversely react with the other components used in accordance with this invention or with the subterranean formation.
[0072] A variety of monomers are suitable for use as the water-soluble polymerizable organic monomers in exemplary embodiments of the present invention. Examples of suitable monomers include acrylic acid, methacrylic acid, acrylamide, methacrylamide, 2- methacrylamido-2-methylpropane sulfonic acid, 2-dimethylacrylamide, vinyl sulfonic acid, N,N-dimethylaminoethyhnethacrylate, 2-triethylammoniumethylmethacrylate chloride, N,N- dimethyl-aminopropylmethacryl-arnide, memacrylainidepropyltriemylammonium chloride, N-vinyl pyrrolidone, vinyl-phosphonic acid, and methacryloyloxyethyl trimethylammonium sulfate, and mixtures thereof. In exemplary embodiments, the water-soluble polymerizable organic monomer may be self-crosslinking. Examples of suitable monomers which are self- crosslinking include hydroxyethylacrylate, hydroxymethylacrylate, hydroxyethylmethacrylate, N-hydroxymethylacrylamide, N-hydroxymethyl-methacrylamide, polyethylene glycol acrylate, polyethylene glycol methacrylate, polypropylene gylcol acrylate, polypropylene glycol methacrylate, and mixtures thereof. Of these, hydroxyethylacrylate may be used in certain exemplary embodiments. One example particular of a suitable monomer is hydroxyethylcelhαlose- vinyl phosphoric acid.
[0073] The water-soluble polymerizable organic monomer (or monomers where a mixture thereof is used) should be included in the polymerizable organic monomer composition in an amount sufficient to form the desired gelled substance after placement of the polymerizable organic monomer composition into the subterranean formation. In some exemplary embodiments of the present invention, the water-soluble polymerizable organic monomer is included in the polymerizable organic monomer composition in an amount in the range of from about 1% to about 30% by weight of the aqueous-base fluid. In another exemplary embodiment of the present invention, the water-soluble polymerizable organic monomer is included in the polymerizable organic monomer composition in an amount in the range of from about 1% to about 20% by weight of the aqueous-base fluid.
[0074] The presence of oxygen in the polymerizable organic monomer composition may inhibit the polymerization process of the water-soluble polymerizable organic monomer or monomers. Therefore, an oxygen scavenger, such as stannous chloride, may be included in the polymerizable monomer composition. In order to improve the solubility of stannous chloride so that it may be readily combined with the polymerizable organic monomer composition on the fly, the stannous chloride may be pre-dissolved in a hydrochloric acid solution. For example, the stannous chloride may be dissolved in a 0.1% by weight aqueous hydrochloric acid solution in an amount of about 10% by weight of the resulting solution. The resulting stannous chloride-hydrochloric acid solution may be included in the polymerizable organic monomer composition in an amount in the range of from about 0.1% to about 10% by weight of the polymerizable organic monomer composition. Generally, the stannous chloride may be included in the polymerizable organic monomer composition of an exemplary embodiment of the present invention in an amount in the range of from about 0.005% to about 0.1% by weight of the polymerizable organic monomer composition.
[0075] The primary initiator is used, inter alia, to initiate polymerization of the water- soluble polymerizable organic monomer(s) used in an exemplary embodiment of the present invention. Any compound or compounds that form free radicals in aqueous solution may be used as the primary initiator. The free radicals act, inter alia, to initiate polymerization of the water-soluble polymerizable organic monomer present in the polymerizable organic monomer composition. Compounds suitable for use as the primary initiator include alkali metal persulfates, peroxides, oxidation-reduction systems employing reducing agents, such as sulfites in combination with oxidizers, and azo polymerization initiators. Preferred azo polymerization initiators include 2,2'-azobis(2-imidazole-2-hydroxyethyl) propane, 2,2'- azobis(2-aminopropane), 4,4'-azobis(4-cyanovaleric acid), and 2,2'-azobis(2-methyl-N-(2- hydroxyethyl) propionamide. Generally, the primary initiator should be present in the polymerizable organic monomer composition in an amount sufficient to initiate polymerization of the water-soluble polymerizable organic monomer(s). In certain exemplary embodiments of the present invention, the primary initiator is present in the polymerizable organic monomer composition in an amount in the range of from about 0.1% to about 5% by weight of the water-soluble polymerizable organic monomer(s). One skilled in the art will recognize that as the polymerization temperature increases, the required level of activator decreases.
[0076] Optionally, the polymerizable organic monomer compositions further may comprise a secondary initiator. A secondary initiator may be used, for example, where the immature aqueous gel is placed into a subterranean formation that is relatively cool as compared to the surface mixing, such as when placed below the mud line in offshore operations. The secondary initiator may be any suitable water-soluble compound or compounds that may react with the primary initiator to provide free radicals at a lower temperature. An example of a suitable secondary initiator is triethanolamine. In some exemplary embodiments of the present invention, the secondary initiator is present in the polymerizable organic monomer composition in an amount in the range of from about 0.1% to about 5% by weight of the water-soluble polymerizable organic monomer(s).
[0077] Also optionally, the polymerizable organic monomer compositions of exemplary embodiments of the present invention further may comprise a crosslinking agent for crosslinking the polymerizable organic monomer compositions in the desired gelled substance, hi some exemplary embodiments, the crosslinking agent is a molecule or complex containing a reactive transition metal cation, such as, e.g., trivalent chromium cations complexed or bonded to anions, atomic oxygen, or water. Examples of suitable crosslinking agents include compounds or complexes containing chromic acetate and/or chromic chloride. Other suitable transition metal cations include chromium VI within a redox system, aluminum III, iron II, iron III, and zirconium IV. Generally, the crosslinking agent may be present in polymerizable organic monomer compositions in an amount in the range of from 0.01% to about 5% by weight of the polymerizable organic monomer composition. D. Exemplary Relative-Permeability Modifiers
[0078] As described above, fluids that comprise a relative-permeability modifier may be used as the sealing compositions, in accordance with exemplary embodiments of the present invention. "While the relative-permeability modifier generally may not plug pore spaces within the treated formation to block flow therethrough, the relative-permeability modifier should adsorb onto surfaces within the formation so as to selectively reduce the formation's water permeability. As such, the formation may be treated with the relative- permeability modifier to form an artificial barrier in the treated formation that at least partially reduces the flow of water therethough.
[0079] The relative-permeability modifier should be included in the fluid in an amount sufficient to provide the desired artificial barrier. In one exemplary embodiment, the relative-permeability modifier may be included in the fluid in an amount in the range of from 0.01% to about 10% by weight of the fluid. In another exemplary embodiment, the relative- permeability modifier maybe included in the fluid in an amount in the range of from about 0.1% to about 1 % by weight of the fluid.
[0080] In general, suitable relative-permeability modifiers may be any compound capable of selectively reducing the effective permeability of a formation to water without a comparable reduction of the formation's effective permeability to hydrocarbons. Those of ordinary skill in the art will appreciate that a variety of different water-soluble polymers may be suitable for use as the relative-permeability modifiers. Examples of suitable water-soluble polymers include homo-, co-, and terpolymers of acrylamide, 2-acrylamido-2-methyl propane sulfonic acid, N,N-dimethylacrylamide, vinyl pyrrolidone, dimethylamfnoethyl methacrylate, acrylic acid, dimethylaminopropyhnethacrylamide, vinyl amine, vinyl acetate, trimethylammoniumethyl methacrylate chloride, methacrylamide, hydroxyethyl acrylate, vinyl sulfonic acid, vinyl phosphomc acid, methacrylic acid, vinyl caprolactam, N- vinylformamide, N,N-diallylacetamide, dimethyldiallyl ammonium halide, itaconic acid, styrene sulfonic acid, methacrylamidoethyltrimethyl ammonium halide, quaternary salt derivatives of acrylamide quaternary salt derivatives of acrylic acid, and combinations thereof. [0081] In addition, water-soluble polymers suitable for use as relative-permeability modifiers also may include hydrophobically modified polymers. As used in this disclosure, the phrase "hydrophobicalfy modified," or "hydrophobic modification," or any variation thereof, refers to the incorporation into the hydrophilic polymer structure of hydrophobic groups, wherein the alkyl chain length is from about 4 to about 22 carbons. While these hydrophobically modified polymers have hydrophobic groups incorporated into the hydrophilic polymer structure, they should remain water-soluble. In some embodiments, a mole ratio of a hydrophilic monomer to the hydrophobic compound in the hydrophobically modified polymer is in the range of from about 99.98:0.02 to about 90:10, wherein the hydrophilic monomer is a calculated amount present in the hydrophilic polymer. In certain embodiments, the hydrophobically modified polymers may comprise a polymer backbone that comprises polar heteroatoms. Generally, the polar heteroatoms present within the polymer backbone of the hydrophobically modified polymers include, but are not limited to, oxygen, nitrogen, sulfur, or phosphorous.
[0082] Exemplary hydrophobically modified polymers may be synthesized utilizing any suitable technique. In one example, the hydrophobically modified polymers may be a reaction product of a hydrophilic polymer and a hydrophobic compound. In another example, the hydrophobically modified polymers may be prepared from a polymerization reaction comprising a hydrophilic monomer and a hydrophobically modified hydrophilic monomer. In general, the hydrophobically modified polymers may be pre-reacted before they are placed into the well bore 10. Alternatively, in certain embodiments, the hydrophobically modified polymers may be prepared by an appropriate in situ reaction. Suitable hydrophobically modified polymers and methods for their preparation are described in more detail in U.S. Pat. Nos. 6,476,169 and 7,117,942, the disclosures of which are incorporated herein by reference. Those of ordinary skill in the art, with the benefit of this disclosure, will be able to determine other suitable methods for the synthesis of suitable hydrophobically modified polymers.
[0083] In certain exemplary embodiments of the present invention, suitable hydrophobically modified polymers may be synthesized by the hydrophobic modification of a hydrophilic polymer. The hydrophilic polymers suitable for forming the hydrophobically modified polymers used in the present invention should be capable of reacting with hydrophobic compounds. Suitable hydropbilic polymers include, homo-, co-, or terpolymers such as, but not limited to, polyacrylamides, polyvinylamines, poly(vinylamines/vinyl alcohols), alkyl acrylate polymers in general, and combinations thereof. Additional examples of alkyl acrylate polymers include polydimethylaminoethyl methacrylate, polydimethylaminopropyl methacrylamide, poly(acrylamide/dmie1hylarninoethyl methacrylate), poly(methacrylic acid/dimethylaminoethyl methacrylate), poly(2-acrylamido- 2-methyl propane sulfonic acid/dimethylaminoethyl methacrylate), poly(acrylamide/dimethylaminopropyl methacrylamide), P°ly (acrylic acid/dimethylaminopropyl methacrylamide), and poly(methacrylic acid/dimethylaminopropyl methacrylamide). In certain exemplary embodiments, the hydrophilic polymers comprise a polymer backbone and reactive amino groups in the polymer backbone or as pendant groups, the reactive amino groups capable of reacting with hydrophobic compounds. In some exemplary embodiments, the hydrophilic polymers comprise dialkyl amino pendant groups. In some exemplary embodiments, the hydrophilic polymers comprise a dimethyl amino pendant group and a monomer comprising dimethylamϊnoethyl methacrylate or drmethylaminopropyl methacrylamide. In certain exemplary embodiments, the hydrophilic polymers comprise a polymer backbone that comprises polar heteroatoms, wherein the polar heteroatoms present within the polymer backbone of the hydrophilic polymers include oxygen, nitrogen, sulfur, or phosphorous. Suitable hydrophilic polymers that comprise polar heteroatoms within the polymer backbone include homo-, co-, or terpolymers, such as, but not limited to, celluloses, chitosans, polyamides, polyetheramines, polyethyleneimines, polyhydroxyetherarnines, polylysines, polysulfones, gums, starches, and combinations thereof. In one exemplary embodiment, the starch is a cationic starch. A suitable cationic starch may be formed by reacting a starch, such as corn, maize, waxy maize, potato, tapioca, or the like, with the reaction product of epichlorohydrin and trialkylamine.
[0084] The hydrophobic compounds that are capable of reacting with the hydrophilic polymers include alkyl halides, sulfonates, sulfates, organic acids, and organic acid derivatives. Examples of suitable organic acids and derivatives thereof include octenyl succinic acid; dodecenyl succinic acid; and anhydrides, esters, imides, and amides of octenyl succinic acid or dodecenyl succinic acid. In certain exemplary embodiments, the hydrophobic compounds may have an alkyl chain length of from about 4 to about 22 carbons. In another exemplary embodiment, the hydrophobic compounds may have an alkyl chain length of from about 7 to about 22 carbons. In another exemplary embodiment, the hydrophobic compounds may have an alkyl chain length of from about 12 to about 18 carbons. For example, where the hydrophobic compound is an alkyl halide, the reaction between the hydrophobic compound and hydrophilic polymer may result in the quaternization of at least some of the hydrophilic polymer amino groups with an alkyl halide, wherein the alkyl chain length is from about 4 to about 22 carbons.
[0085] As previously mentioned, in certain exemplary embodiments, suitable hydrophobically modified polymers also may be prepared from a polymerization reaction comprising a hydrophilic monomer and a hydrophobically modified hydrophilic monomer. The hydrophobically modified polymers synthesized from the polymerization reactions may have estimated molecular weights in the range of from about 100,000 to about 10,000,000 and mole ratios of the hydrophilic monomer(s) to the hydrophobically modified hydrophilic monomer(s) in the range of from about 99.98:0.02 to about 90:10.
[0086] A variety of hydrophilic monomers may be used to form the hydrophobically modified polymers useful in the present invention. Examples of suitable hydrophilic monomers include acrylamide, 2-acrylamido-2-methyl propane sulfonic acid, N,N- dimethylacrylamide, vinyl pyrrolidone, dimethylaminoethyl methacrylate, acrylic acid, dimemylaminopropylmethacrylamide, vinyl amine, vinyl acetate, Mmethylamrnoniurnethyl methacrylate chloride, methacrylamide, hydroxyethyl acrylate, vinyl sulfonic acid, vinyl phosphonic acid, methacrylic acid, vinyl caprolactam, N-vinylformamide, N,N- diallylacetamide, dimethyldiallyl ammonium halide, itaconic acid, styrene sulfonic acid, methacrylamidoethyltrimethyl ammonium halide, quaternary salt derivatives of acrylamide, and quaternary salt derivatives of acrylic acid.
[0087] A variety of hydrophobically modified hydrophilic monomers also may be used to form the hydrophobically modified polymers useful in exemplary embodiments of the present invention. Examples of suitable hydrophobically modified hydrophilic monomers include alkyl acrylates, alkyl methacrylates, alkyl acrylamides, alkyl methacrylamides alkyl dimethylammoniumethyl methacrylate halides, and alkyl dimethylammoniumpropyl methacrylamide halides, wherein the alkyl groups have from about 4 to about 22 carbon atoms. In another exemplary embodiment, the alkyl groups have from about 7 to about 22 carbons. In another exemplary embodiment, the alkyl groups have from about 12 to about 18 carbons. In certain exemplary embodiments, the hydrophobically modified hydrophilic monomer comprises octadecyldimethylarnmoniumethyl methacrylate bromide, hexadecyldimethylammoniumethyl methacrylate bromide, hexadecyldimethylammoniumpropyl methacrylamide bromide, 2-ethylhexyl methacrylate, or hexadecyl methacrylamide.
[0088] Suitable hydrophobically modified polymers that may be formed from the above-described reactions include acrylamide/octadecyldimethylammoriiumethyl methacrylate bromide copolymer, dimethylamino ethyl methacrylate/vinyl pyrrolidone/hexadecyldimethylammoniumethyl methacrylate bromide terpolymer, and acrylamide/2-acrylainido-2-methyl propane sulfonic acid/2-ethylhexyl methacrylate terpolymer. Another suitable hydrophobically modified polymer formed from the above- described reaction comprises an amino methacrylate/alkyl amino methacrylate copolymer. A suitable dimethlyaminoethyl memacrylate/alkyl-dimethylammoniumethyl methacrylate copolymer is a dimethylaminoethyl methacrylate/hexadecyl-dimethylammoniumethyl methacrylate copolymer. As previously discussed, these copolymers may be formed by reactions with a variety of alkyl halides. For example, in some exemplary embodiments, the hydrophobically modified polymer may comprise a dimethylaminoethyl methacrylate/hexadecyl-dimethylammoniumethyl methacrylate bromide copolymer.
III. Exemplary Consolidating Fluids
[0089] In accordance with exemplar}' embodiments, a consolidating fluid may be introduced into a portion of a subterranean formation to consolidate the treated portion of the formation. In general, the consolidating fluid may be any fluid suitable for enhancing the grain-to-grain (or grain-to-formation) contact between particulates in the treated portion of the subterranean formation so that the particulates are stabilized, locked in place, or at least partially immobilized such that they are resistant to flowing with any produced or injected fluids. When placed into the formation, the consolidating fluid should inhibit dislodged fines from migrating with any subsequently produced or injected fluids. Examples of suitable consolidating fluids include tackifying fluids, resin compositions, and gelable compositions. Those of ordinary skill in the art will appreciate that these consolidating fluids are merely exemplary, and the present invention is applicable to other fluids for introduction into the formation to control particulate production.
[0090] As previously mentioned, an exemplary embodiment of the consolidating fluids used in the present invention may comprise a tackifying agent. Suitable tackifying agents are substances that are (or may be activated to become) tacky and, thus, impart a degree of consolidation to unconsolidated particulates in the subterranean formation. In this manner, the particulates may be stabilized, locked in place, or at least partially immobilized such that they are resistant to flowing with fluids that are subsequently produced or injected. Suitable tackifying agents may not be significantly tacky when placed into the formation, but may be capable of being "activated" (that is destabilized, coalesced and/or reacted) to transform into a tacky compound at a desirable time. Such activation may occur before, during, or after the introduction of the tackifying fluid into the subterranean formation. Examples of suitable tackifying agents are described in more detail above with respect to the exemplar}' sealing compositions.
[0091] Another example of a consolidating fluid that may be used in an exemplary embodiment of the present invention may comprise a resin. Resins suitable for use may include any resin that is capable of consolidating the treated formation into a hardened, consolidated mass. Examples of suitable resins are described in more detail above with respect to the exemplary sealing compositions.
[0092] Another example of a consolidating fluid that may be used in an exemplary embodiment of the present invention comprises gelable compositions. In general, suitable gelable compositions should cure to form a gel. Gelable compositions suitable for use in exemplary embodiments of the present invention include those compositions that cure to form a semi-solid, immovable, gel-like substance. Prior to curing, the gelable compositions should have low viscosities and be capable of flowing in pipe and into the subterranean formation. The gelable composition may be any gelable liquid composition capable of converting into a gelled substance capable of substantially plugging the permeability of the formation while allowing the formation to remain flexible. As referred to in this disclosure, the term "flexible" refers to a state wherein the treated formation is relatively malleable and elastic and able to withstand substantial pressure cycling without substantial breakdown of the formation. Thus, the resultant gelled substance stabilizes the treated portion of the formation while allowing the formation to absorb the stresses created during pressure cycling. As a result, the gelled substance may aid in preventing breakdown of the formation both by stabilizing and by adding flexibility to the treated region. Exemplary gelable compositions are described in more detail above with respect to the exemplary sealing compositions.
[0093] While the invention may be susceptible to various modifications and alternative forms, specific embodiments have been shown by way of example in the drawings and have been described in detail herein. However, it should be understood that the invention is not intended to be limited to the particular forms disclosed. Rather, the invention is to cover all modifications, equivalents, and alternatives falling within the spirit and scope of the invention as defined by the following appended claims.

Claims

What is claimed is:
1. A method of completing a well, comprising: forming an artificial barrier to water flow, wherein the artificial barrier is located at or above a hydrocarbon-water interface between a water-bearing formation zone and a hydrocarbon-bearing formation zone; and consolidating a portion of the hydrocarbon-bearing formation zone, wherein the artificial barrier is located between the consolidated portion of the hydrocarbon-bearing zone and the water-bearing formation zone.
2. The method of claim 1, wherein a bottom of the artificial barrier is located about ten feet above the hydro carbon- water interface.
3. The method of claim 1, wherein the artificial barrier is a substantially impenetrable barrier for reducing fluid migration between the hydrocarbon-bearing formation zone and the water-bearing formation zone.
4. The method of claim 1, wherein forming the artificial barrier comprises introducing a sealing composition into a subterranean formation so as to form the artificial barrier.
5. The method of claim 4, wherein the sealing composition comprises a fluid selected from the group consisting of a tackifying fluid, a resin composition, a gelable composition, a fluid comprising a relative-permeability modifier, and combinations thereof.
6. The method of claim 4, wherein the sealing composition comprises a nonaqueous tackifying agent selected from the group consisting of a polyamide, a condensation reaction product of one or more polyacids and one or more polyamines, a polyester, a polycarbonate, a poly carbamate, a natural resin, a shellac, and combinations thereof.
7. The method of claim 4, wherein the sealing composition comprises an aqueous tackifying agent selected from the group consisting of an acrylic acid polymer, an acrylic acid ester polymer, an acrylic acid derivative polymer, an acrylic acid homopolymer, an acrylic acid ester homopolymers, a poly(methyl acrylate), a poly (butyl acrylate), a poly(2-ethylhexyl acrylate, an acrylic acid ester copolymer, a methacrylic acid derivative polymer, a methacrylic acid homopolymer, a methacrylic acid ester homopolymer, a poly(methyl methacrylate), a poly(butyl methacrylate), a poly(2-ethylhexyl methacrylate), an acrylamido- methyl-propane sulfonate polymer, an acrylamido-methyl-propane sulfonate derivative polymer, an acrylamido-methyl-propane sulfonate copolymer, an acrylic acid/acrylamido- methyl-propane sulfonate copolymer, a benzyl coco di-(hydroxyethyl) quaternary amine, a p- T-amyl-phenol condensed with formaldehyde, a copolymer comprising from about 80% to about 100% C1-3O alkylmethacrylate monomers and from up to about 20% hydrophilic monomers, and combinations thereof.
8. The method of claim 4, wherein the sealing composition comprises a resin selected from the group consisting of a two-component epoxy based resin, a novolak resin, a polyepoxide resin, a phenol-aldehyde resin, a urea-aldehyde resin, a urethane resins, a phenolic resin, a furan resin, a furan/furfuryl alcohol resin, a phenolic/latex resin, a phenol formaldehyde resin, a polyester resin, a hybrid of a polyester resin, a copolymer of a polyester resin, a polyurethane resin, a hybrid of a polyurethane resin, a copolymer of a polyurethane resin, an acrylate resin, and combinations thereof.
9. The method of claim 4, wherein the sealing composition comprises a gelable composition selected from the group consisting of a gelable aqueous silicate composition, a crosslinkable aqueous polymer composition, a gelable resin composition, a polymerizable organic monomer composition, and combinations thereof.
10. The method of claim 4, wherein the sealing composition comprises an aqueous alkali metal silicate solution and a catalyst.
11. The method of claim 4, wherein the sealing composition comprises an aqueous solvent, a crosslinkable polymer, and a crosslinking agent.
12. The method of claim 4, wherein the sealing composition comprises a gelable resin composition comprising a resin selected from the group consisting of an organic resin, a polyepoxide resin, a polyester resin, a urea-aldehyde resin, a furan resin, a urethane resin, and combinations thereof.
13. The method of claim 12, wherein the gelable resin composition comprises a flexibilizer additive selected from the group consisting of an organic ester, an oxygenated organic solvent, an aromatic solvent, and combinations thereof.
14. The method of claim 4, wherein the sealing composition comprises an aqueous solvent, a water-soluble polymerizable organic monomer, an oxygen scavenger, and a primary initiator.
15. The method of claim 4, wherein the sealing composition comprises a fluid comprising a relative permeability modifier selected from the group consisting of homo-, co-, and terpolymers of acrylamide, 2-acrylamido-2-methyl propane sulfonic acid, N9N- dimethylacrylamide, vinyl pyrrolidone, dimethylaminoethyl methacrylate, acrylic acid, dimethylaminopropylmethacrylamide, vinyl amine, vinyl acetate, trimethylammoniumethyl methacrylate chloride, methacrylamide, hydrόxyethyl acrylate, vinyl sulfonic acid, vinyl phosphonic acid, methacrylic acid, vinyl caprolactam, N-vinylformamide, N3N- diallylacetamide, dimethyldiallyl ammonium halide, itaconic acid, styrene sulfonic acid, methacrylamidoemyltrimethyl ammonium halide, a quaternary salt derivative of acrylamide and a quaternary salt derivative of acrylic acid, and combinations thereof.
16. The method of claim 4, wherein the sealing composition comprises a fluid comprising a hydrophobically modified polymer selected from the group consisting of a a hydrophobically modified polyacrylamide, a hydrophobically modified polyvinylamine, a hydrophobically modified poly(vinylamine/vinyl alcohol), a hydrophobically modified alkyl acrylate polymer, a hydrophobically modified cellulose, a hydrophobically modified chitosan, a hydrophobically modified polyamide, a hydrophobically modified polyetheramine, a hydrophobically modified polyethyleneimine, a hydrophobically modified polyhydroxyetheramine, a hydrophobically modified polylysme, a hydrophobically modified polysulfone, a hydrophobically modified gum, a hydrophobically modified starch, and combinations thereof.
17. The method of claim 1, wherein consolidating the portion of the subterranean formation comprises introducing a consolidating fluid into the portion of the hydrocarbon- bearing formation zone so as to consolidate the portion of the hydrocarbon-bearing formation zone.
18. The method of claim 17, wherein the consolidating fluid comprises a fluid selected from the group consisting of a tackifying fluid, a resin composition, a gelable composition, and combinations thereof.
19. The method of claim 17, wherein the consolidating fluid comprises a nonaqueous tackifying agent selected from the group consisting of a polyamide, a condensation reaction product of one or more polyacids and one or more polyamines, a polyester, a polycarbonate, a polycarbamate, a natural resin, a shellac, and combinations thereof.
20. The method of claim 17, wherein the consolidating fluid comprises an aqueous tackifying agent selected from the group consisting of an acrylic acid polymer, an acrylic acid ester polymer, an acrylic acid derivative polymer, an acrylic acid homopolymer, an acrylic acid ester homopolymers, a poly(methyl acrylate), a poly (butyl acrylate), a poly(2-ethylhexyl acrylate, an acrylic acid ester copolymer, a tnethacrylic acid derivative polymer, a methacrylic acid homopolymer, a methacrylic acid ester homopolymer, a poly(methyl methacrylate), a poly(butyl methacrylate), a poly(2-ethylhexyl methacrylate), an acrylamido- methyl-propane sulfonate polymer, an acrylamido-methyl-propane sulfonate derivative polymer, an acrylamido-methyl-propane sulfonate copolymer, an acrylic acid/acrylamido- methyl-propane sulfonate copolymer, a benzyl coco di-(hydroxyethyl) quaternary amine, a p- T-amyl-phenol condensed with formaldehyde, a copolymer comprising from about 80% to about 100% C1-30 alkylmethacrylate monomers and from up to about 20% hydrophilic monomers, and combinations thereof.
21. The method of claim 17, wherein the consolidating fluid comprises a resin selected from the group consisting of a two-component epoxy based resin, a novolak resin, a polyepoxide resin, a phenol-aldehyde resin, a urea-aldehyde resin, a urethane resin, a phenolic resin, a furan resin, a furan/furfuryl alcohol resin, a phenolic/latex resin, a phenol formaldehyde resin, a polyester resin, a hybrid of a polyester resin, a copolymer of a polyester resin, a polyurethane resin, a hybrid of a polyurethane resin, a copolymer of a polyurethane resin, an acrylate resin, and combinations thereof.
22. The method of claim 17, wherein the consolidating fluid comprises a gelable composition selected from the group consisting of a gelable aqueous silicate composition, a crosslinkable aqueous polymer composition, a gelable resin composition, a polymerizable organic monomer composition, and combinations thereof.
23. The method of claim 17, wherein the consolidating fluid comprises a gelable resin composition comprising a resin selected from the group consisting of an organic resin, a polyepoxide resin, a polyester resin, a urea-aldehyde resin, a furan resin, a urethane resin, and combinations thereof.
.
24. The method of claim 11, wherein the consolidating fluid comprises a flexibilizer additive selected from the group consisting of an organic ester, an oxygenated organic solvent, an aromatic solvent, and combinations thereof.
25. The method of claim 1, wherein consolidating the portion of the subterranean formation comprises consolidating particulates within the hydrocarbon-bearing formation zone so that the particulates are inhibited from migrating with any subsequently produced fluids.
26. A method of completing a well for controlling water and particulate production, the method comprising: identifying a hydrocarbon-water interface between a hydrocarbon-bearing formation zone and a water-bearing formation zone; perforating a first interval of a casing; introducing a sealing composition into one or more subterranean formations surrounding the first interval to form an artificial barrier to water flow, wherein the artificial barrier is located either at or above the hydrocarbon-water interface; perforating a second interval of the casing, wherein the second interval is located above the first interval; and introducing a consolidating fluid into one or more subterranean formations surrounding the second interval so as to consolidate at least a portion of the one or more subterranean formations.
27. The method of claim 26, wherein a bottom of the artificial barrier is located about ten feet above the hydrocarbon- water interface.
28. The method of claim 26, wherein the artificial barrier is a substantially impenetrable barrier for reducing fluid migration between the hydrocarbon-bearing formation zone and the water-bearing formation zone.
29. The method of claim 26, wherein the sealing composition penetrates in the range of from about 5 feet to about 50 feet into the one or more subterranean formations.
30. The method of claim 26, wherein the sealing composition comprises a fluid selected from the group consisting of a tackifying fluid, a resin composition, a gelable composition, a fluid comprising a relative-permeability modifier, and combinations thereof.
31. The method of claim 26, wherein the consolidating fluid comprises a fluid selected from the group consisting of a tackifying fluid, a resin composition, a gelable composition, and combinations thereof.
32. The method of claim 26, wherein the particulates within the consolidated portion of the one or more subterranean formations are inhibited from migrating with any subsequently produced fluids.
33. The method of claim 26, wherein the consolidating fluid is introduced into the one or more subterranean formations prior to the introduction of the sealing composition into the one or more subterranean formations.
34. The method of claim 26, wherein the one or more subterranean formations into which the consolidating fluid is introduced and the one or more subterranean formations into which the sealing composition is introduced are the same or different formations.
35. The method of claim 34, wherein the hydrocarbon-bearing formation zone comprises the one or more subterranean formations into which the consolidating fluid is introduced.
36. The method of claim 26, comprising at least one step selected from the group of creating or enhancing one or more propped fractures through the consolidated portion of the one or more subterranean formations, introducing an after-flush fluid into the consolidated portion of the subterranean formation to at least partially restore effective permeability to the consolidated portion, introducing a pre-flush fluid into the one or more subterranean formations surrounding the second interval prior to the introduction of the consolidating fluid, shutting in the well bore after the step of introducing the consolidating fluid, and combinations thereof.
37. A method of completing a well for controlling water and particulate production, the method comprising: positioning a jetting tool at a first location in a well bore; perforating a first interval of casing at the first location, the perforating comprising using the jetting tool to form one or more perforations that penetrate through the casing; introducing a sealing composition through the jetting tool and into one or more subterranean formations surrounding the first interval to form an artificial barrier to water flow, wherein either the artificial barrier is adjacent to a hydrocarbon-water interface between a hydrocarbon-bearing formation zone and a water-bearing formation zone, or a bottom of the artificial barrier is located no more than about ten feet above the hydrocarbon-water interface; positioning the jetting tool in the well bore at a second location above the first location; perforating a second interval of casing at the second location in the well bore, the perforating comprising using the jetting tool to form one or more perforations that penetrate through the casing; and introducing a consolidating fluid through the jetting tool and into one or more formations surrounding the second interval so as to consolidate at least a portion of the one or more subterranean formations.
38. The method of claim 37, comprising jetting a fluid through the jetting tool and into the consolidated portion of the one or more subterranean formations and pumping a fluid down through an annulus between the casing and a work string coupled to the jetting tool and into the consolidated portion such that one or more propped fractures through the consolidated portion are created or enhanced.
PCT/GB2008/000476 2007-02-15 2008-02-08 Methods of completing wells for controlling water and particulate production WO2008099154A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US11/706,737 US7934557B2 (en) 2007-02-15 2007-02-15 Methods of completing wells for controlling water and particulate production
US11/706,737 2007-02-15

Publications (1)

Publication Number Publication Date
WO2008099154A1 true WO2008099154A1 (en) 2008-08-21

Family

ID=39345362

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/GB2008/000476 WO2008099154A1 (en) 2007-02-15 2008-02-08 Methods of completing wells for controlling water and particulate production

Country Status (2)

Country Link
US (1) US7934557B2 (en)
WO (1) WO2008099154A1 (en)

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2009087349A1 (en) * 2008-01-08 2009-07-16 Halliburton Energy Services, Inc. Methods for controlling water and particulate production in subterranean wells
US7934557B2 (en) 2007-02-15 2011-05-03 Halliburton Energy Services, Inc. Methods of completing wells for controlling water and particulate production
CN102250595A (en) * 2011-05-19 2011-11-23 中国石油天然气集团公司 Drilling fluid used for active mud shale drilling
WO2015016934A1 (en) * 2013-08-01 2015-02-05 Halliburton Energy Services, Inc. Resin composition for treatment of a subterranean formation
CN104449618A (en) * 2015-01-06 2015-03-25 西南石油大学 Temperature-resisting salt-tolerant high-temperature self-cross-linking onsite polymerization water plugging gel
CN110387222A (en) * 2019-08-01 2019-10-29 西南石油大学 A kind of porous gel sealing agent, preparation method and application
CN111139042A (en) * 2018-11-02 2020-05-12 中国石油化工股份有限公司 Resin modified polymer fluid loss agent based on degradation and preparation method thereof
CN111139039A (en) * 2018-11-02 2020-05-12 中国石油化工股份有限公司 Sulfonated phenolic resin graft modified polymer filtrate reducer and preparation method thereof
WO2020146885A1 (en) * 2019-01-11 2020-07-16 Saudi Arabian Oil Company Methods and compositions for controlling excess water production
EP3420047B1 (en) * 2016-02-23 2023-01-11 Ecolab USA Inc. Hydrazide crosslinked polymer emulsions for use in crude oil recovery

Families Citing this family (85)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7741251B2 (en) * 2002-09-06 2010-06-22 Halliburton Energy Services, Inc. Compositions and methods of stabilizing subterranean formations containing reactive shales
US8631869B2 (en) 2003-05-16 2014-01-21 Leopoldo Sierra Methods useful for controlling fluid loss in subterranean treatments
US8181703B2 (en) 2003-05-16 2012-05-22 Halliburton Energy Services, Inc. Method useful for controlling fluid loss in subterranean formations
US8091638B2 (en) 2003-05-16 2012-01-10 Halliburton Energy Services, Inc. Methods useful for controlling fluid loss in subterranean formations
US7759292B2 (en) 2003-05-16 2010-07-20 Halliburton Energy Services, Inc. Methods and compositions for reducing the production of water and stimulating hydrocarbon production from a subterranean formation
US8962535B2 (en) 2003-05-16 2015-02-24 Halliburton Energy Services, Inc. Methods of diverting chelating agents in subterranean treatments
US8251141B2 (en) 2003-05-16 2012-08-28 Halliburton Energy Services, Inc. Methods useful for controlling fluid loss during sand control operations
US8278250B2 (en) 2003-05-16 2012-10-02 Halliburton Energy Services, Inc. Methods useful for diverting aqueous fluids in subterranean operations
US7678742B2 (en) 2006-09-20 2010-03-16 Halliburton Energy Services, Inc. Drill-in fluids and associated methods
US7678743B2 (en) 2006-09-20 2010-03-16 Halliburton Energy Services, Inc. Drill-in fluids and associated methods
US7687438B2 (en) 2006-09-20 2010-03-30 Halliburton Energy Services, Inc. Drill-in fluids and associated methods
US20080139411A1 (en) * 2006-12-07 2008-06-12 Harris Phillip C Methods of treating subterranean formations using hydrophobically modified polymers and compositions of the same
US7730950B2 (en) * 2007-01-19 2010-06-08 Halliburton Energy Services, Inc. Methods for treating intervals of a subterranean formation having variable permeability
EA017428B1 (en) * 2007-08-01 2012-12-28 Эм-Ай ЭлЭлСи Methods of increasing fracture resistance in low permeability formations
US20090253594A1 (en) * 2008-04-04 2009-10-08 Halliburton Energy Services, Inc. Methods for placement of sealant in subterranean intervals
US7998910B2 (en) 2009-02-24 2011-08-16 Halliburton Energy Services, Inc. Treatment fluids comprising relative permeability modifiers and methods of use
US8420576B2 (en) 2009-08-10 2013-04-16 Halliburton Energy Services, Inc. Hydrophobically and cationically modified relative permeability modifiers and associated methods
US20110186295A1 (en) * 2010-01-29 2011-08-04 Kaminsky Robert D Recovery of Hydrocarbons Using Artificial Topseals
EP2694616A4 (en) 2011-04-05 2014-09-03 Montgomery Chemicals Llc Method and compositions for enhanced oil recovery
WO2012174370A2 (en) * 2011-06-17 2012-12-20 M-I L.L.C. Composition of polybutadiene-based formula for downhole applications
US9291046B2 (en) * 2011-07-27 2016-03-22 Schlumberger Technology Corporation Dual or twin-well completion with wettability alteration for segregated oil and water production
US9045965B2 (en) 2012-05-01 2015-06-02 Halliburton Energy Services, Inc. Biodegradable activators to gel silica sol for blocking permeability
US10093770B2 (en) 2012-09-21 2018-10-09 Schlumberger Technology Corporation Supramolecular initiator for latent cationic epoxy polymerization
US9938452B2 (en) 2012-10-24 2018-04-10 Halliburton Energy Services, Inc. Immobile proppants
US9133386B2 (en) * 2012-12-12 2015-09-15 Hallburton Energy Services, Inc. Viscous settable fluid for lost circulation in subterranean formations
US9863220B2 (en) 2013-01-08 2018-01-09 Halliburton Energy Services, Inc. Hydrophobically modified amine-containing polymers for mitigating scale buildup
US9404031B2 (en) 2013-01-08 2016-08-02 Halliburton Energy Services, Inc. Compositions and methods for controlling particulate migration in a subterranean formation
MX2015014096A (en) * 2013-04-05 2016-02-18 Mi Llc Polymeric compositions for downhole applications.
US9441151B2 (en) 2013-05-14 2016-09-13 Halliburton Energy Serives, Inc. Wellbore servicing materials and methods of making and using same
AU2013400700B2 (en) 2013-09-23 2016-11-03 Halliburton Energy Services, Inc. A solidified, thermally insulating composition
WO2015057215A1 (en) * 2013-10-16 2015-04-23 Halliburton Energy Services, Inc. Compositions providing consolidation and water-control
US9321954B2 (en) * 2013-11-06 2016-04-26 Halliburton Energy Services, Inc. Consolidation compositions for use in subterranean formation operations
US20150233205A1 (en) * 2014-02-17 2015-08-20 Sharp-Rock Technologies, Inc. Pumping Fluid To Seal A Subterranean Fracture
GB2523750A (en) * 2014-03-03 2015-09-09 Maersl Olie Og Gas As Method of sealing a fracture in a wellbore and sealing system
US9663703B2 (en) 2014-04-25 2017-05-30 James George Clements Method and compositions for enhanced oil recovery
US9862872B2 (en) * 2014-05-09 2018-01-09 Halliburton Energy Services, Inc. Stabilizing formation laminae in coal seam wellbores
MX2016014263A (en) * 2014-06-27 2017-02-06 Halliburton Energy Services Inc Reaction products of acrylamide polymers and methods for use thereof as relative permeability modifiers.
WO2016018239A1 (en) * 2014-07-28 2016-02-04 Halliburton Energy Services, Inc. Foamed curable resin fluids
US9810051B2 (en) 2014-11-20 2017-11-07 Thru Tubing Solutions, Inc. Well completion
WO2016137608A1 (en) 2015-02-26 2016-09-01 Halliburton Energy Services, Inc. Sealant composition for use in subterranean formations
US9869170B2 (en) * 2015-03-17 2018-01-16 Halliburton Energy Services, Inc. Methods of controlling water production in horizontal wells with multistage fractures
CN107429154B (en) * 2015-09-18 2020-11-20 亨斯迈石油化学有限责任公司 Improved poly (vinyl caprolactam) kinetic gas hydrate inhibitors and methods of making the same
CN106566495B (en) * 2015-10-12 2021-11-09 中国石油化工股份有限公司 Tackifying and cutting-improving agent for oil-based drilling fluid and preparation method and application thereof
WO2017075112A1 (en) * 2015-10-26 2017-05-04 Savage James M Improving hydrocarbon production from a well
US10472555B2 (en) 2016-04-08 2019-11-12 Schlumberger Technology Corporation Polymer gel for water control applications
CN106800919B (en) * 2017-01-22 2018-10-30 中国石油大学(华东) A kind of water-base drilling fluid and its preparation method and application of protection Thief zone reservoir
US10619083B2 (en) 2017-02-03 2020-04-14 Saudi Arabian Oil Company Nanosilica dispersion lost circulation material (LCM)
US10407609B2 (en) 2017-05-02 2019-09-10 Saudi Arabian Oil Company Chemical plugs for preventing wellbore treatment fluid losses
US10053613B1 (en) 2017-05-02 2018-08-21 Saudi Arabian Oil Company Plugging and sealing subterranean formations
US10759986B2 (en) 2017-08-17 2020-09-01 Saudi Arabian Oil Company Loss circulation material composition having alkaline nanoparticle based dispersion and water soluble hydrolysable ester
US11015102B2 (en) 2017-08-17 2021-05-25 Saudi Arabian Oil Company Loss circulation material composition having alkaline nanoparticle based dispersion, water insoluble hydrolysable polyester, and formaldehyde resin
US10351755B2 (en) 2017-08-17 2019-07-16 Saudi Arabian Oil Company Loss circulation material composition having alkaline nanoparticle based dispersion and water insoluble hydrolysable polyester
US10683452B2 (en) 2017-09-11 2020-06-16 Saudi Arabian Oil Company Nanosilica dispersion for thermally insulating packer fluid
US10233380B1 (en) 2017-09-11 2019-03-19 Saudi Arabian Oil Company Well treatment fluid having an acidic nanoparticle based dispersion and a polyamine
US10577526B2 (en) 2017-09-11 2020-03-03 Saudi Arabian Oil Company Loss circulation material composition having an acidic nanoparticle based dispersion and polyamine
US11279865B2 (en) 2017-09-11 2022-03-22 Saudi Arabian Oil Company Well treatment fluid having an acidic nanoparticle based dispersion, an epoxy resin, and a polyamine
US10316238B2 (en) 2017-09-11 2019-06-11 Saudi Arabian Oil Company Nanosilica dispersion for thermally insulating packer fluid
US10570699B2 (en) 2017-11-14 2020-02-25 Saudi Arabian Oil Company Insulating fluid for thermal insulation
US20190161668A1 (en) 2017-11-27 2019-05-30 Saudi Arabian Oil Company Method and materials to convert a drilling mud into a solid gel based lost circulation material
US11149181B2 (en) 2017-11-27 2021-10-19 Saudi Arabian Oil Company Method and materials to convert a drilling mud into a solid gel based lost circulation material
EP3752577A1 (en) 2018-02-15 2020-12-23 Saudi Arabian Oil Company A method and material for isolating a severe loss zone
US10745610B2 (en) 2018-05-17 2020-08-18 Saudi Arabian Oil Company Method and composition for sealing a subsurface formation
US10954427B2 (en) 2018-05-17 2021-03-23 Saudi Arabian Oil Company Method and composition for sealing a subsurface formation
US10655049B1 (en) 2019-02-21 2020-05-19 Saudi Arabian Oil Company Method and materials to convert a drilling mud into a solid gel based lost circulation material
US10655050B1 (en) 2019-02-21 2020-05-19 Saudi Arabian Oil Company Method and materials to convert a drilling mud into a solid gel based lost circulation material
US11203710B2 (en) 2019-02-21 2021-12-21 Saudi Arabian Oil Company Method and materials to convert a drilling mud into a solid gel based lost circulation material
US11124691B2 (en) 2019-02-21 2021-09-21 Saudi Arabian Oil Company Method and materials to convert a drilling mud into a solid gel based lost circulation material
WO2021046294A1 (en) 2019-09-05 2021-03-11 Saudi Arabian Oil Company Propping open hydraulic fractures
US11781413B2 (en) 2020-02-04 2023-10-10 Halliburton Energy Services, Inc. Downhole acid injection to stimulate formation production
US11408240B2 (en) 2020-02-04 2022-08-09 Halliburton Energy Services, Inc. Downhole acid injection to stimulate formation production
CN113356788A (en) * 2020-03-06 2021-09-07 中国石油化工股份有限公司 Visual simulation device and method for artificial partition plate of radial well structure
US11098235B1 (en) 2020-03-18 2021-08-24 Saudi Arabian Oil Company Methods of converting drilling fluids into geopolymer cements and use thereof
US11820708B2 (en) 2020-03-18 2023-11-21 Saudi Arabian Oil Company Geopolymer cement slurries, cured geopolymer cement and methods of making and use thereof
US11066899B1 (en) 2020-03-18 2021-07-20 Saudi Arabian Oil Company Methods of sealing a subsurface formation with saudi arabian volcanic ash
US11820707B2 (en) 2020-03-18 2023-11-21 Saudi Arabian Oil Company Geopolymer cement slurries, cured geopolymer cement and methods of making and use thereof
US11015108B1 (en) 2020-03-18 2021-05-25 Saudi Arabian Oil Company Methods of reducing lost circulation in a wellbore using Saudi Arabian volcanic ash
US10920121B1 (en) 2020-03-18 2021-02-16 Saudi Arabian Oil Company Methods of reducing lost circulation in a wellbore using Saudi Arabian volcanic ash
US11299662B2 (en) 2020-07-07 2022-04-12 Saudi Arabian Oil Company Method to use lost circulation material composition comprising alkaline nanoparticle based dispersion and sodium bicarbonate in downhole conditions
US11802232B2 (en) 2021-03-10 2023-10-31 Saudi Arabian Oil Company Polymer-nanofiller hydrogels
CN115163027A (en) * 2021-04-02 2022-10-11 中国石油化工股份有限公司 Method for treating water coning or ridge entering at bottom of oil well
US11753574B2 (en) 2021-07-30 2023-09-12 Saudi Arabian Oil Company Packer fluid with nanosilica dispersion and sodium bicarbonate for thermal insulation
US11572761B1 (en) 2021-12-14 2023-02-07 Saudi Arabian Oil Company Rigless method for selective zonal isolation in subterranean formations using colloidal silica
US11708521B2 (en) 2021-12-14 2023-07-25 Saudi Arabian Oil Company Rigless method for selective zonal isolation in subterranean formations using polymer gels
US11718776B2 (en) 2021-12-16 2023-08-08 Saudi Arabian Oil Company Method to use loss circulation material composition comprising acidic nanoparticle based dispersion and sodium bicarbonate in downhole conditions
CN116253986A (en) * 2023-03-31 2023-06-13 浙江理工大学 Preparation method of water-based efficient biomass antibacterial flame-retardant polyurethane

Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3865600A (en) * 1972-03-08 1975-02-11 Fosroc Ag Soil consolidation
US4091868A (en) * 1977-03-07 1978-05-30 Diversified Chemical Corporation Method of treating oil wells
US4718491A (en) * 1985-08-29 1988-01-12 Institut Francais Du Petrole Process for preventing water inflow in an oil- and/or gas-producing well
US5150754A (en) * 1991-05-28 1992-09-29 Mobil Oil Corporation Aqueous and petroleum gel method for preventing water-influx
US5379841A (en) * 1992-04-10 1995-01-10 Hoechst Aktiengesellschaft Method for reducing or completely stopping the influx of water in boreholes for the extraction of oil and/or hydrocarbon gas
US6187839B1 (en) * 1999-03-03 2001-02-13 Halliburton Energy Services, Inc. Methods of sealing compositions and methods
US6228812B1 (en) * 1998-12-10 2001-05-08 Bj Services Company Compositions and methods for selective modification of subterranean formation permeability
US6283210B1 (en) * 1999-09-01 2001-09-04 Halliburton Energy Services, Inc. Proactive conformance for oil or gas wells
US20030092578A1 (en) * 2001-11-15 2003-05-15 Hirasaki George J. Subterranean formation water permeability reducing methods
US20040144542A1 (en) * 2001-05-25 2004-07-29 Luisa Chiappa Process for reducing the production of water in oil wells
US6920928B1 (en) * 1998-03-27 2005-07-26 Schlumberger Technology Corporation Method for water control

Family Cites Families (721)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3123138A (en) 1964-03-03 robichaux
US2238671A (en) 1940-02-09 1941-04-15 Du Pont Method of treating wells
US2278838A (en) 1940-03-11 1942-04-07 Petrolite Corp Composition of matter and process for preventing water-in-oil type emulsions resulting from acidization of calcareous oil-bearing strata
US2689244A (en) 1950-06-23 1954-09-14 Phillips Petroleum Co Process for production of chitin sulfate
US2670329A (en) 1950-08-03 1954-02-23 Phillips Petroleum Co Drilling muds and methods of using same
US2703316A (en) 1951-06-05 1955-03-01 Du Pont Polymers of high melting lactide
US3765804A (en) 1951-08-13 1973-10-16 Brandon O Apparatus for producing variable high frequency vibrations in a liquid medium
US2910436A (en) 1953-10-02 1959-10-27 California Research Corp Method of treating wells with acid
US2863832A (en) 1954-05-14 1958-12-09 California Research Corp Method of acidizing petroliferous formations
US2869642A (en) 1954-09-14 1959-01-20 Texas Co Method of treating subsurface formations
US2843573A (en) 1955-03-21 1958-07-15 Rohm & Haas New quaternary ammonium compounds in which the nitrogen atom carries an alkoxymethyl group
US3065247A (en) 1955-11-23 1962-11-20 Petrolte Corp Reaction product of epoxidized fatty acid esters of lower alkanols and polyamino compounds
US2877179A (en) 1956-03-26 1959-03-10 Cities Service Res & Dev Co Composition for and method of inhibiting corrosion of metals
US2819278A (en) 1956-05-09 1958-01-07 Petrolite Corp Reaction product of epoxidized glycerides and hydroxylated tertiary monoamines
US3173484A (en) 1958-09-02 1965-03-16 Gulf Research Development Co Fracturing process employing a heterogeneous propping agent
US3047067A (en) 1958-09-08 1962-07-31 Jersey Prod Res Co Sand consolidation method
US3008898A (en) 1959-06-26 1961-11-14 Cities Service Res & Dev Co Method of inhibiting corrosion
US3070165A (en) 1959-12-14 1962-12-25 Phillips Petroleum Co Fracturing formations in wells
US3052298A (en) 1960-03-22 1962-09-04 Shell Oil Co Method and apparatus for cementing wells
US3258428A (en) 1960-08-04 1966-06-28 Petrolite Corp Scale prevention
US3259578A (en) 1960-08-04 1966-07-05 Petrolite Corp Lubricating compositions
US3251778A (en) 1960-08-04 1966-05-17 Petrolite Corp Process of preventing scale
US3271307A (en) 1960-08-04 1966-09-06 Petrolite Corp Oil well treatment
US3187567A (en) * 1961-11-16 1965-06-08 Pure Oil Co Fluid flow indicating method and apparatus for well bores
US3297086A (en) 1962-03-30 1967-01-10 Exxon Production Research Co Sand consolidation method
US3237690A (en) * 1962-10-01 1966-03-01 Gulf Research Development Co Process for forming an impermeable barrier in subsurface formations
US3215199A (en) 1963-02-21 1965-11-02 Shell Oil Co Acidizing oil formations
US3272650A (en) 1963-02-21 1966-09-13 Union Carbide Corp Process for cleaning conduits
US3199590A (en) 1963-02-25 1965-08-10 Halliburton Co Method of consolidating incompetent sands and composition therefor
US3195635A (en) 1963-05-23 1965-07-20 Pan American Petroleum Corp Spacers for fracture props
US3316965A (en) 1963-08-05 1967-05-02 Union Oil Co Material and process for treating subterranean formations
US3308886A (en) 1963-12-26 1967-03-14 Halliburton Co Retrievable bridge plug
DE1468014A1 (en) 1964-01-29 1969-01-09 Henkel & Cie Gmbh Process for the preparation of hydroxyalkyl ethers of galactomannans
US3297090A (en) 1964-04-24 1967-01-10 Shell Oil Co Acidizing oil formations
US3307630A (en) 1964-06-12 1967-03-07 Shell Oil Co Acidizing oil formations
US3176768A (en) 1964-07-27 1965-04-06 California Research Corp Sand consolidation
US3492147A (en) 1964-10-22 1970-01-27 Halliburton Co Method of coating particulate solids with an infusible resin
US3302719A (en) 1965-01-25 1967-02-07 Union Oil Co Method for treating subterranean formations
US3251415A (en) 1965-04-01 1966-05-17 Exxon Production Research Co Acid treating process
GB1107584A (en) 1965-04-06 1968-03-27 Pan American Petroleum Corp Method of treating unconsolidated well formations
US3329204A (en) 1965-04-29 1967-07-04 Schlumberger Well Surv Corp Methods for well completion
US3404114A (en) 1965-06-18 1968-10-01 Dow Chemical Co Method for preparing latexes having improved adhesive properties
US3434971A (en) 1965-08-25 1969-03-25 Dow Chemical Co Composition and method for acidizing wells
US3366178A (en) 1965-09-10 1968-01-30 Halliburton Co Method of fracturing and propping a subterranean formation
US3375872A (en) 1965-12-02 1968-04-02 Halliburton Co Method of plugging or sealing formations with acidic silicic acid solution
US3455390A (en) 1965-12-03 1969-07-15 Union Oil Co Low fluid loss well treating composition and method
US3308885A (en) 1965-12-28 1967-03-14 Union Oil Co Treatment of subsurface hydrocarbon fluid-bearing formations to reduce water production therefrom
US3364995A (en) 1966-02-14 1968-01-23 Dow Chemical Co Hydraulic fracturing fluid-bearing earth formations
US3347789A (en) 1966-03-04 1967-10-17 Petrolite Corp Treatment of oil wells
US3451818A (en) 1966-04-19 1969-06-24 Polaroid Corp Composite rollfilm assembly for use in the diffusion transfer process
US3394758A (en) * 1966-07-28 1968-07-30 Exxon Production Research Co Method for drilling wells with a gas
US3382924A (en) 1966-09-06 1968-05-14 Dow Chemical Co Treatment of earthen formations comprising argillaceous material
US3404735A (en) 1966-11-01 1968-10-08 Halliburton Co Sand control method
US3415320A (en) 1967-02-09 1968-12-10 Halliburton Co Method of treating clay-containing earth formations
US3336980A (en) 1967-02-09 1967-08-22 Exxon Production Research Co Sand control in wells
US3378074A (en) 1967-05-25 1968-04-16 Exxon Production Research Co Method for fracturing subterranean formations
US3441085A (en) 1967-09-07 1969-04-29 Exxon Production Research Co Method for acid treating carbonate formations
US3478824A (en) 1968-04-12 1969-11-18 Chevron Res Sand consolidation process
US3481403A (en) 1968-07-26 1969-12-02 Exxon Production Research Co Method for consolidating formations surrounding boreholes with resin
US3525398A (en) 1968-11-19 1970-08-25 Phillips Petroleum Co Sealing a permeable stratum with resin
US3489222A (en) 1968-12-26 1970-01-13 Chevron Res Method of consolidating earth formations without removing tubing from well
DE1905834C3 (en) 1969-02-06 1972-11-09 Basf Ag Procedure for avoiding dust and caking of salts or fertilizers
US3592266A (en) 1969-03-25 1971-07-13 Halliburton Co Method of fracturing formations in wells
US3601194A (en) 1969-07-14 1971-08-24 Union Oil Co Low fluid loss well-treating composition and method
US3565176A (en) 1969-09-08 1971-02-23 Clifford V Wittenwyler Consolidation of earth formation using epoxy-modified resins
US3647567A (en) 1969-11-28 1972-03-07 Celanese Coatings Co Post-dipping of acidic deposition coatings
US3647507A (en) 1970-01-07 1972-03-07 Johnson & Johnson Resin composition containing a polyacrylic acid-polyacrylamide copolymer and method of using the same to control resin composition
DE2250552A1 (en) 1970-01-30 1974-04-18 Gaf Corp Filmogenic quat ammonium copolymers - use as hair fixatives ,in textile treatments etc
US3910862A (en) 1970-01-30 1975-10-07 Gaf Corp Copolymers of vinyl pyrrolidone containing quarternary ammonium groups
US3709641A (en) 1970-08-03 1973-01-09 Union Oil Co Apparatus for preparing and extruding a gelatinous material
US3659651A (en) 1970-08-17 1972-05-02 Exxon Production Research Co Hydraulic fracturing using reinforced resin pellets
US4305463A (en) 1979-10-31 1981-12-15 Oil Trieval Corporation Oil recovery method and apparatus
US3689468A (en) 1970-12-14 1972-09-05 Rohm & Haas Unsaturated quaternary monomers and polymers
US3689418A (en) 1971-01-18 1972-09-05 Monsanto Co Detergent formulations
US3769070A (en) 1971-02-18 1973-10-30 S Schilt A method of glazing greenware with an ambient epoxy resin curing composition
US3681287A (en) 1971-03-03 1972-08-01 Quaker Oats Co Siliceous materials bound with resin containing organosilane coupling agent
US3768564A (en) 1971-04-26 1973-10-30 Halliburton Co Method of fracture acidizing a well formation
US3842911A (en) 1971-04-26 1974-10-22 Halliburton Co Method of fracture acidizing a well formation
US3708013A (en) 1971-05-03 1973-01-02 Mobil Oil Corp Method and apparatus for obtaining an improved gravel pack
US3709298A (en) 1971-05-20 1973-01-09 Shell Oil Co Sand pack-aided formation sand consolidation
US3784585A (en) 1971-10-21 1974-01-08 American Cyanamid Co Water-degradable resins containing recurring,contiguous,polymerized glycolide units and process for preparing same
US3741308A (en) 1971-11-05 1973-06-26 Permeator Corp Method of consolidating sand formations
US3754598A (en) 1971-11-08 1973-08-28 Phillips Petroleum Co Method for producing a hydrocarbon-containing formation
US3744566A (en) 1972-03-16 1973-07-10 Calgon Corp Secondary oil recovery process
US3819525A (en) 1972-08-21 1974-06-25 Avon Prod Inc Cosmetic cleansing preparation
US3857444A (en) 1972-10-06 1974-12-31 Dow Chemical Co Method for forming a consolidated gravel pack in a subterranean formation
US3854533A (en) 1972-12-07 1974-12-17 Dow Chemical Co Method for forming a consolidated gravel pack in a subterranean formation
US3912692A (en) 1973-05-03 1975-10-14 American Cyanamid Co Process for polymerizing a substantially pure glycolide composition
US4042032A (en) 1973-06-07 1977-08-16 Halliburton Company Methods of consolidating incompetent subterranean formations using aqueous treating solutions
US3850247A (en) 1973-08-27 1974-11-26 Halliburton Co Placing zones of solids in a subterranean fracture
US3888311A (en) 1973-10-01 1975-06-10 Exxon Production Research Co Hydraulic fracturing method
US3933205A (en) 1973-10-09 1976-01-20 Othar Meade Kiel Hydraulic fracturing process using reverse flow
US4015995A (en) 1973-11-23 1977-04-05 Chevron Research Company Method for delaying the setting of an acid-settable liquid in a terrestrial zone
US4052345A (en) 1973-12-17 1977-10-04 Basf Wyandotte Corporation Process for the preparation of polyurethane foams
US3863709A (en) 1973-12-20 1975-02-04 Mobil Oil Corp Method of recovering geothermal energy
US3861467A (en) 1973-12-28 1975-01-21 Texaco Inc Permeable cementing method
US3955993A (en) 1973-12-28 1976-05-11 Texaco Inc. Method and composition for stabilizing incompetent oil-containing formations
US3948672A (en) 1973-12-28 1976-04-06 Texaco Inc. Permeable cement composition and method
US3902557A (en) 1974-03-25 1975-09-02 Exxon Production Research Co Treatment of wells
US3943060A (en) 1974-07-26 1976-03-09 Calgon Corporation Friction reducing
US4060988A (en) 1975-04-21 1977-12-06 Texaco Inc. Process for heating a fluid in a geothermal formation
US4000781A (en) 1975-04-24 1977-01-04 Shell Oil Company Well treating process for consolidating particles with aqueous emulsions of epoxy resin components
US4299710A (en) 1975-05-30 1981-11-10 Rohm And Haas Company Drilling fluid and method
US4031958A (en) 1975-06-13 1977-06-28 Union Oil Company Of California Plugging of water-producing zones in a subterranean formation
CA1045027A (en) 1975-09-26 1978-12-26 Walter A. Hedden Hydraulic fracturing method using sintered bauxite propping agent
US4052343A (en) 1975-11-10 1977-10-04 Rohm And Haas Company Crosslinked, macroreticular poly(dimethylaminoethyl methacrylate) ion-exchange resins and method of preparation by aqueous suspension polymerization using trialkylamine phase extender
US3983941A (en) 1975-11-10 1976-10-05 Mobil Oil Corporation Well completion technique for sand control
US4070865A (en) 1976-03-10 1978-01-31 Halliburton Company Method of consolidating porous formations using vinyl polymer sealer with divinylbenzene crosslinker
US4018285A (en) 1976-03-19 1977-04-19 Exxon Production Research Company Method for controlling fines migrations
US4008763A (en) 1976-05-20 1977-02-22 Atlantic Richfield Company Well treatment method
US4089437A (en) 1976-06-18 1978-05-16 The Procter & Gamble Company Collapsible co-dispensing tubular container
CA1103008A (en) 1976-08-13 1981-06-16 Homer C. Mclaughlin Treatment of clay formations with organic polycationic polymers
US4366073A (en) 1976-08-13 1982-12-28 Halliburton Company Oil well treating method and composition
US4366072A (en) 1976-08-13 1982-12-28 Halliburton Company Oil well treating method and composition
US4366071A (en) 1976-08-13 1982-12-28 Halliburton Company Oil well treating method and composition
US4374739A (en) 1976-08-13 1983-02-22 Halliburton Company Oil well treating method and composition
US4366074A (en) 1976-08-13 1982-12-28 Halliburton Company Oil well treating method and composition
US4029148A (en) 1976-09-13 1977-06-14 Atlantic Richfield Company Well fracturing method
US4074760A (en) 1976-11-01 1978-02-21 The Dow Chemical Company Method for forming a consolidated gravel pack
US4085801A (en) 1976-11-05 1978-04-25 Continental Oil Company Control of incompetent formations with thickened acid-settable resin compositions
JPS6024122B2 (en) 1977-01-05 1985-06-11 三菱化学株式会社 Method for producing bead-like polymer
US4085802A (en) 1977-01-17 1978-04-25 Continental Oil Company Use of thickened oil for sand control processes
US4142595A (en) 1977-03-09 1979-03-06 Standard Oil Company (Indiana) Shale stabilizing drilling fluid
US4129183A (en) 1977-06-30 1978-12-12 Texaco Inc. Use of organic acid chrome complexes to treat clay containing formations
US4127173A (en) 1977-07-28 1978-11-28 Exxon Production Research Company Method of gravel packing a well
US4259205A (en) 1977-10-06 1981-03-31 Halliburton Company Process involving breaking of aqueous gel of neutral polysaccharide polymer
US4152274A (en) 1978-02-09 1979-05-01 Nalco Chemical Company Method for reducing friction loss in a well fracturing process
GB1569063A (en) 1978-05-22 1980-06-11 Shell Int Research Formation parts around a borehole method for forming channels of high fluid conductivity in
US4337828A (en) 1978-06-19 1982-07-06 Magna Corporation Method of recovering petroleum from a subterranean reservoir incorporating polyepoxide condensates of resinous polyalkylene oxide adducts and polyether polyols
US4158521A (en) 1978-06-26 1979-06-19 The Western Company Of North America Method of stabilizing clay formations
US4532052A (en) 1978-09-28 1985-07-30 Halliburton Company Polymeric well treating method
US4460627A (en) 1978-09-28 1984-07-17 Halliburton Company Polymeric well treating method
US4228277A (en) 1979-02-12 1980-10-14 Hercules Incorporated Modified nonionic cellulose ethers
US4291766A (en) 1979-04-09 1981-09-29 Shell Oil Company Process for consolidating water-wet sands with an epoxy resin-forming solution
US4247430A (en) 1979-04-11 1981-01-27 The Dow Chemical Company Aqueous based slurry and method of forming a consolidated gravel pack
US4273187A (en) 1979-07-30 1981-06-16 Texaco Inc. Petroleum recovery chemical retention prediction technique
US4443380A (en) 1979-08-31 1984-04-17 Asahi-Dow Limited Organic europlum salt phosphor
US4306981A (en) 1979-10-05 1981-12-22 Magna Corporation Method for breaking petroleum emulsions and the like comprising resinous polyalkylene oxide adducts
US4552670A (en) 1979-10-15 1985-11-12 Diamond Shamrock Chemicals Company Amphoteric water-in-oil self-inverting polymer emulsion
FR2473180A1 (en) 1980-01-08 1981-07-10 Petroles Cie Francaise METHOD OF TRACING THE DRILLING MUD BY DETERMINING THE CONCENTRATION OF A SOLUBLE ION
US4353806A (en) 1980-04-03 1982-10-12 Exxon Research And Engineering Company Polymer-microemulsion complexes for the enhanced recovery of oil
US4336842A (en) 1981-01-05 1982-06-29 Graham John W Method of treating wells using resin-coated particles
US4814096A (en) 1981-02-06 1989-03-21 The Dow Chemical Company Enhanced oil recovery process using a hydrophobic associative composition containing a hydrophilic/hydrophobic polymer
US4399866A (en) 1981-04-10 1983-08-23 Atlantic Richfield Company Method for controlling the flow of subterranean water into a selected zone in a permeable subterranean carbonaceous deposit
US4393939A (en) 1981-04-20 1983-07-19 Halliburton Services Clay stabilization during oil and gas well cementing operations
US4392988A (en) 1981-05-11 1983-07-12 Ga Technologies Inc. Method of producing stable alumina
US4466831A (en) 1981-05-21 1984-08-21 Halliburton Company Rapidly dissolvable silicates and methods of using the same
US4415805A (en) 1981-06-18 1983-11-15 Dresser Industries, Inc. Method and apparatus for evaluating multiple stage fracturing or earth formations surrounding a borehole
US4395340A (en) 1981-07-14 1983-07-26 Halliburton Company Enhanced oil recovery methods and systems
US4401789A (en) 1981-07-14 1983-08-30 Halliburton Company Enhanced oil recovery methods and systems
US4439334A (en) 1981-07-14 1984-03-27 Halliburton Company Enhanced oil recovery methods and systems
US4460052A (en) 1981-08-10 1984-07-17 Judith Gockel Prevention of lost circulation of drilling muds
US4498995A (en) 1981-08-10 1985-02-12 Judith Gockel Lost circulation drilling fluid
US4441556A (en) 1981-08-17 1984-04-10 Standard Oil Company Diverter tool and its use
US4443347A (en) 1981-12-03 1984-04-17 Baker Oil Tools, Inc. Proppant charge and method
US4428427A (en) 1981-12-03 1984-01-31 Getty Oil Company Consolidatable gravel pack method
US4564459A (en) 1981-12-03 1986-01-14 Baker Oil Tools, Inc. Proppant charge and method
US4664819A (en) 1981-12-03 1987-05-12 Baker Oil Tools, Inc. Proppant charge and method
US4494605A (en) 1981-12-11 1985-01-22 Texaco Inc. Sand control employing halogenated, oil soluble hydrocarbons
US4536297A (en) 1982-01-28 1985-08-20 Halliburton Company Well drilling and completion fluid composition
US4440649A (en) 1982-01-28 1984-04-03 Halliburton Company Well drilling and completion fluid composition
US4439489A (en) 1982-02-16 1984-03-27 Acme Resin Corporation Particles covered with a cured infusible thermoset film and process for their production
US4447342A (en) 1982-04-19 1984-05-08 Halliburton Co. Method of clay stabilization in enhanced oil recovery
US4604216A (en) 1982-10-19 1986-08-05 Phillips Petroleum Company Drilling fluids
US4553596A (en) 1982-10-27 1985-11-19 Santrol Products, Inc. Well completion technique
DE3400164A1 (en) 1983-01-14 1984-07-19 Sandoz-Patent-GmbH, 7850 Lörrach LIQUID LOSS REDUCING ADDITIVES FOR PUNCHING LIQUIDS
US5186257A (en) 1983-01-28 1993-02-16 Phillips Petroleum Company Polymers useful in the recovery and processing of natural resources
US4501328A (en) 1983-03-14 1985-02-26 Mobil Oil Corporation Method of consolidation of oil bearing sands
US4499214A (en) 1983-05-03 1985-02-12 Diachem Industries, Inc. Method of rapidly dissolving polymers in water
US4527627A (en) 1983-07-28 1985-07-09 Santrol Products, Inc. Method of acidizing propped fractures
US4493875A (en) 1983-12-09 1985-01-15 Minnesota Mining And Manufacturing Company Proppant for well fractures and method of making same
US4681165A (en) 1984-03-01 1987-07-21 Dowell Schlumberger Incorporated Aqueous chemical wash compositions
US4541489A (en) 1984-03-19 1985-09-17 Phillips Petroleum Company Method of removing flow-restricting materials from wells
US4546012A (en) 1984-04-26 1985-10-08 Carbomedics, Inc. Level control for a fluidized bed
GB8412423D0 (en) 1984-05-16 1984-06-20 Allied Colloids Ltd Polymeric compositions
KR920006865B1 (en) 1984-05-18 1992-08-21 워싱톤 유니버시티 테크놀러지 어소우시에이츠 인코오퍼레이티드 Method and apparatus for coating particles or liquid droplets
US4554081A (en) 1984-05-21 1985-11-19 Halliburton Company High density well drilling, completion and workover brines, fluid loss reducing additives therefor and methods of use
GB8413716D0 (en) 1984-05-30 1984-07-04 Allied Colloids Ltd Aqueous well fluids
US4888240A (en) 1984-07-02 1989-12-19 Graham John W High strength particulates
US4585064A (en) 1984-07-02 1986-04-29 Graham John W High strength particulates
US4563292A (en) 1984-08-02 1986-01-07 Halliburton Company Methods for stabilizing fines contained in subterranean formations
US4536303A (en) 1984-08-02 1985-08-20 Halliburton Company Methods of minimizing fines migration in subterranean formations
US4627926A (en) 1984-09-19 1986-12-09 Exxon Research And Engineering Company Thermally stable borehole fluids
US4536305A (en) 1984-09-21 1985-08-20 Halliburton Company Methods for stabilizing swelling clays or migrating fines in subterranean formations
US4608139A (en) 1985-06-21 1986-08-26 Scm Corporation Electrocoating process using shear stable cationic latex
US4619776A (en) 1985-07-02 1986-10-28 Texas United Chemical Corp. Crosslinked fracturing fluids
US4992182A (en) 1985-11-21 1991-02-12 Union Oil Company Of California Scale removal treatment
US4730028A (en) 1986-03-28 1988-03-08 Exxon Research And Engineering Company Process for preparing hydrophobically associating terpolymers containing sulfonate functionality
US4665988A (en) 1986-04-04 1987-05-19 Halliburton Company Method of preparation of variable permeability fill material for use in subterranean formations
EP0421980B1 (en) 1986-04-18 1993-08-25 Hosokawa Micron Corporation Particulate material treating apparatus
US4662448A (en) 1986-04-25 1987-05-05 Atlantic Richfield Company Well treatment method using sodium silicate to seal formation
US4959432A (en) 1986-05-19 1990-09-25 Union Carbide Chemicals And Plastics Company Inc. Acid viscosifier compositions
US4669543A (en) 1986-05-23 1987-06-02 Halliburton Company Methods and compositions for consolidating solids in subterranean zones
US4694905A (en) 1986-05-23 1987-09-22 Acme Resin Corporation Precured coated particulate material
US4785884A (en) 1986-05-23 1988-11-22 Acme Resin Corporation Consolidation of partially cured resin coated particulate material
US4693808A (en) 1986-06-16 1987-09-15 Shell Oil Company Downflow fluidized catalytic cranking reactor process and apparatus with quick catalyst separation means in the bottom thereof
US4693639A (en) 1986-06-25 1987-09-15 Halliburton Company Clay stabilizing agent preparation and use
US4649998A (en) 1986-07-02 1987-03-17 Texaco Inc. Sand consolidation method employing latex
US4737295A (en) 1986-07-21 1988-04-12 Venture Chemicals, Inc. Organophilic polyphenolic acid adducts
US4683954A (en) 1986-09-05 1987-08-04 Halliburton Company Composition and method of stimulating subterranean formations
US4733729A (en) 1986-09-08 1988-03-29 Dowell Schlumberger Incorporated Matched particle/liquid density well packing technique
US4828725A (en) 1986-10-01 1989-05-09 Air Products And Chemicals, Inc. Completion fluids containing high molecular weight poly(vinylamines)
US4787453A (en) 1986-10-30 1988-11-29 Union Oil Company Of California Permeability stabilization in subterranean formations containing particulate matter
US4772646A (en) 1986-11-17 1988-09-20 Halliburton Company Concentrated hydrophilic polymer suspensions
FR2618846A2 (en) 1986-11-25 1989-02-03 Schlumberger Cie Dowell PROCESS FOR SEALING UNDERGROUND FORMATIONS, PARTICULARLY IN THE OIL DRILLING SECTOR AND CORRESPONDING COMPOSITIONS AND APPLICATIONS
US4856590A (en) 1986-11-28 1989-08-15 Mike Caillier Process for washing through filter media in a production zone with a pre-packed screen and coil tubing
US4739832A (en) 1986-12-24 1988-04-26 Mobil Oil Corporation Method for improving high impulse fracturing
US4702319A (en) 1986-12-29 1987-10-27 Exxon Research And Engineering Company Enhanced oil recovery with hydrophobically associating polymers containing sulfonate functionality
US4850430A (en) 1987-02-04 1989-07-25 Dowell Schlumberger Incorporated Matched particle/liquid density well packing technique
US4870167A (en) 1987-03-02 1989-09-26 Hi-Tek Polymers, Inc. Hydrophobically modified non-ionic polygalactomannan ethers
US4796701A (en) 1987-07-30 1989-01-10 Dowell Schlumberger Incorporated Pyrolytic carbon coating of media improves gravel packing and fracturing capabilities
US4828726A (en) 1987-09-11 1989-05-09 Halliburton Company Stabilizing clayey formations
US4942186A (en) 1987-10-23 1990-07-17 Halliburton Company Continuously forming and transporting consolidatable resin coated particulate materials in aqueous gels
US4829100A (en) 1987-10-23 1989-05-09 Halliburton Company Continuously forming and transporting consolidatable resin coated particulate materials in aqueous gels
US4800960A (en) 1987-12-18 1989-01-31 Texaco Inc. Consolidatable gravel pack method
US5071934A (en) 1987-12-21 1991-12-10 Exxon Research And Engineering Company Cationic hydrophobic monomers and polymers
US4892147A (en) 1987-12-28 1990-01-09 Mobil Oil Corporation Hydraulic fracturing utilizing a refractory proppant
IT1224421B (en) 1987-12-29 1990-10-04 Lamberti Flli Spa MODIFIED GALATTOMANNANS AND REALIVE PREPARATION PROCEDURE
DE3805116A1 (en) 1988-02-18 1989-08-31 Hilterhaus Karl Heinz METHOD FOR PRODUCING ORGANOMINERAL PRODUCTS
US4941537A (en) 1988-02-25 1990-07-17 Hi-Tek Polymers, Inc. Method for reducing the viscosity of aqueous fluid
US5248665A (en) 1988-03-14 1993-09-28 Shell Oil Company Drilling fluids comprising polycyclic polyether polyol
US4886354A (en) 1988-05-06 1989-12-12 Conoco Inc. Method and apparatus for measuring crystal formation
US4846118A (en) 1988-06-14 1989-07-11 Brunswick Corporation Duel fuel pump and oil-fuel mixing valve system
US4842072A (en) 1988-07-25 1989-06-27 Texaco Inc. Sand consolidation methods
US5030603A (en) 1988-08-02 1991-07-09 Norton-Alcoa Lightweight oil and gas well proppants
NO893150L (en) 1988-08-15 1990-02-16 Baroid Technology Inc PROCEDURE FOR DRILLING A DRILL IN EARTH AND DRILL FOR USE IN THE PROCEDURE.
US4903770A (en) 1988-09-01 1990-02-27 Texaco Inc. Sand consolidation methods
US4842070A (en) 1988-09-15 1989-06-27 Amoco Corporation Procedure for improving reservoir sweep efficiency using paraffinic or asphaltic hydrocarbons
US4848470A (en) 1988-11-21 1989-07-18 Acme Resin Corporation Process for removing flow-restricting materials from wells
US4898750A (en) 1988-12-05 1990-02-06 Texaco Inc. Processes for forming and using particles coated with a resin which is resistant to high temperature and high pH aqueous environments
US4895207A (en) 1988-12-19 1990-01-23 Texaco, Inc. Method and fluid for placing resin coated gravel or sand in a producing oil well
US4969522A (en) 1988-12-21 1990-11-13 Mobil Oil Corporation Polymer-coated support and its use as sand pack in enhanced oil recovery
US4917186A (en) 1989-02-16 1990-04-17 Phillips Petroleum Company Altering subterranean formation permeability
US4875525A (en) 1989-03-03 1989-10-24 Atlantic Richfield Company Consolidated proppant pack for producing formations
DE3907392A1 (en) 1989-03-08 1990-09-13 Henkel Kgaa ESTER OF CARBONIC ACIDS, MEDIUM CHAIN LENGTH, AS THE BEST NEEDLE PART OF THE OIL PHASE IN INVERT DRILL RINSE
US4934456A (en) 1989-03-29 1990-06-19 Phillips Petroleum Company Method for altering high temperature subterranean formation permeability
US4928763A (en) * 1989-03-31 1990-05-29 Marathon Oil Company Method of treating a permeable formation
US4921576A (en) 1989-04-20 1990-05-01 Mobil Oil Corporation Method for improving sweep efficiency in CO2 oil recovery
US4969523A (en) 1989-06-12 1990-11-13 Dowell Schlumberger Incorporated Method for gravel packing a well
US5351754A (en) 1989-06-21 1994-10-04 N. A. Hardin 1977 Trust Apparatus and method to cause fatigue failure of subterranean formations
US5056597A (en) 1989-07-27 1991-10-15 Chevron Research And Technology Company Method for improving the steam splits in a multiple steam injection process using multiple steam headers
US4936385A (en) 1989-10-30 1990-06-26 Halliburton Company Method of particulate consolidation
US4984635A (en) 1989-11-16 1991-01-15 Mobil Oil Corporation Thermal barriers for enhanced oil recovery
US5464060A (en) 1989-12-27 1995-11-07 Shell Oil Company Universal fluids for drilling and cementing wells
US5049743A (en) 1990-01-17 1991-09-17 Protechnics International, Inc. Surface located isotope tracer injection apparatus
US5182051A (en) 1990-01-17 1993-01-26 Protechnics International, Inc. Raioactive tracing with particles
US5002127A (en) * 1990-02-27 1991-03-26 Halliburton Company Placement aid for dual injection placement techniques
US6184311B1 (en) 1990-03-26 2001-02-06 Courtaulds Coatings (Holdings) Limited Powder coating composition of semi-crystalline polyester and curing agent
US5160642A (en) 1990-05-25 1992-11-03 Petrolite Corporation Polyimide quaternary salts as clay stabilization agents
US5067564A (en) * 1990-10-12 1991-11-26 Marathon Oil Company Selective placement of a permeability-reducing material to inhibit fluid communication between a near well bore interval and an underlying aquifer
US5082056A (en) 1990-10-16 1992-01-21 Marathon Oil Company In situ reversible crosslinked polymer gel used in hydrocarbon recovery applications
US5105886A (en) 1990-10-24 1992-04-21 Mobil Oil Corporation Method for the control of solids accompanying hydrocarbon production from subterranean formations
DE69106869T2 (en) 1990-10-29 1995-05-18 Inst Francais Du Petrole USE OF GEL-BASED COMPOSITIONS TO REDUCE WATER PRODUCTION IN OIL OR GAS PRODUCTION HOLES.
US5256651A (en) 1991-01-22 1993-10-26 Rhone-Poulenc, Inc. Hydrophilic-hydrophobic derivatives of polygalactomannans containing tertiary amine functionality
US5128390A (en) 1991-01-22 1992-07-07 Halliburton Company Methods of forming consolidatable resin coated particulate materials in aqueous gels
US5095987A (en) 1991-01-31 1992-03-17 Halliburton Company Method of forming and using high density particulate slurries for well completion
US5099923A (en) 1991-02-25 1992-03-31 Nalco Chemical Company Clay stabilizing method for oil and gas well treatment
US5197544A (en) 1991-02-28 1993-03-30 Halliburton Company Method for clay stabilization with quaternary amines
US5097904A (en) 1991-02-28 1992-03-24 Halliburton Company Method for clay stabilization with quaternary amines
US5146986A (en) 1991-03-15 1992-09-15 Halliburton Company Methods of reducing the water permeability of water and oil producing subterranean formations
US5278203A (en) 1991-03-21 1994-01-11 Halliburton Company Method of preparing and improved liquid gelling agent concentrate and suspendable gelling agent
IT1245383B (en) 1991-03-28 1994-09-20 Eniricerche Spa GELIFIABLE WATER COMPOSITION WITH DELAYED GELIFICATION TIME
US5244042A (en) 1991-05-07 1993-09-14 Union Oil Company Of California Lanthanide-crosslinked polymers for subterranean injection
US5173527A (en) 1991-05-15 1992-12-22 Forintek Canada Corp. Fast cure and pre-cure resistant cross-linked phenol-formaldehyde adhesives and methods of making same
US5208216A (en) 1991-06-13 1993-05-04 Nalco Chemical Company Acrylamide terpolymer shale stabilizing additive for low viscosity oil and gas drilling operations
US5135051A (en) 1991-06-17 1992-08-04 Facteau David M Perforation cleaning tool
US5178218A (en) 1991-06-19 1993-01-12 Oryx Energy Company Method of sand consolidation with resin
CA2062395A1 (en) 1991-06-21 1992-12-22 Robert H. Friedman Sand consolidation methods
US5232961A (en) 1991-08-19 1993-08-03 Murphey Joseph R Hardenable resin compositions and methods
US5256729A (en) 1991-09-04 1993-10-26 Atlantic Richfield Company Nitrile derivative for sand control
US5199491A (en) 1991-09-04 1993-04-06 Atlantic Richfield Company Method of using nitrile derivative for sand control
US5199492A (en) 1991-09-19 1993-04-06 Texaco Inc. Sand consolidation methods
US5424284A (en) 1991-10-28 1995-06-13 M-I Drilling Fluids Company Drilling fluid additive and method for inhibiting hydration
US5908814A (en) 1991-10-28 1999-06-01 M-I L.L.C. Drilling fluid additive and method for inhibiting hydration
US5218038A (en) 1991-11-14 1993-06-08 Borden, Inc. Phenolic resin coated proppants with reduced hydraulic fluid interaction
CA2057750A1 (en) 1991-12-16 1993-06-17 Tibor Csabai Process for producing a high strength artificial (cast) stone with high permeability and filter effect
US5677187A (en) 1992-01-29 1997-10-14 Anderson, Ii; David K. Tagging chemical compositions
US5211234A (en) 1992-01-30 1993-05-18 Halliburton Company Horizontal well completion methods
US5728653A (en) 1992-01-31 1998-03-17 Institut Francais Du Petrole Method for inhibiting reactive argillaceous formations and use thereof in a drilling fluid
FR2686892B1 (en) 1992-01-31 1995-01-13 Inst Francais Du Petrole PROCESS FOR INHIBITING REACTIVE CLAY FORMATIONS AND APPLICATION TO A DRILLING FLUID.
US5249627A (en) 1992-03-13 1993-10-05 Halliburton Company Method for stimulating methane production from coal seams
US5165438A (en) 1992-05-26 1992-11-24 Facteau David M Fluidic oscillator
US5265678A (en) 1992-06-10 1993-11-30 Halliburton Company Method for creating multiple radial fractures surrounding a wellbore
US5238068A (en) 1992-07-01 1993-08-24 Halliburton Company Methods of fracture acidizing subterranean formations
US5273115A (en) 1992-07-13 1993-12-28 Gas Research Institute Method for refracturing zones in hydrocarbon-producing wells
US5663123A (en) 1992-07-15 1997-09-02 Kb Technologies Ltd. Polymeric earth support fluid compositions and method for their use
US5293939A (en) 1992-07-31 1994-03-15 Texaco Chemical Company Formation treating methods
US5425994A (en) 1992-08-04 1995-06-20 Technisand, Inc. Resin coated particulates comprissing a formaldehyde source-metal compound (FS-MC) complex
US5244362A (en) 1992-08-17 1993-09-14 Txam Chemical Pumps, Inc. Chemical injector system for hydrocarbon wells
US5249628A (en) 1992-09-29 1993-10-05 Halliburton Company Horizontal well completions
US5361856A (en) 1992-09-29 1994-11-08 Halliburton Company Well jetting apparatus and met of modifying a well therewith
US5325923A (en) 1992-09-29 1994-07-05 Halliburton Company Well completions with expandable casing portions
US5396957A (en) 1992-09-29 1995-03-14 Halliburton Company Well completions with expandable casing portions
US5295542A (en) 1992-10-05 1994-03-22 Halliburton Company Well gravel packing methods
US5320171A (en) 1992-10-09 1994-06-14 Halliburton Company Method of preventing gas coning and fingering in a high temperature hydrocarbon bearing formation
US5321062A (en) 1992-10-20 1994-06-14 Halliburton Company Substituted alkoxy benzene and use thereof as wetting aid for polyepoxide resins
US5271466A (en) 1992-10-30 1993-12-21 Halliburton Company Subterranean formation treating with dual delayed crosslinking gelled fluids
US5420174A (en) 1992-11-02 1995-05-30 Halliburton Company Method of producing coated proppants compatible with oxidizing gel breakers
US5332037A (en) 1992-11-16 1994-07-26 Atlantic Richfield Company Squeeze cementing method for wells
US5316587A (en) 1993-01-21 1994-05-31 Church & Dwight Co., Inc. Water soluble blast media containing surfactant
US5387675A (en) 1993-03-10 1995-02-07 Rhone-Poulenc Specialty Chemicals Co. Modified hydrophobic cationic thickening compositions
CA2119316C (en) 1993-04-05 2006-01-03 Roger J. Card Control of particulate flowback in subterranean wells
US5330005A (en) 1993-04-05 1994-07-19 Dowell Schlumberger Incorporated Control of particulate flowback in subterranean wells
US5360068A (en) 1993-04-19 1994-11-01 Mobil Oil Corporation Formation fracturing
US5377759A (en) 1993-05-20 1995-01-03 Texaco Inc. Formation treating methods
US5422183A (en) 1993-06-01 1995-06-06 Santrol, Inc. Composite and reinforced coatings on proppants and particles
GB9313081D0 (en) * 1993-06-25 1993-08-11 Pumptech Nv Selective zonal isolation of oil wells
US5368102A (en) 1993-09-09 1994-11-29 Halliburton Company Consolidatable particulate material and well treatment method
US5545824A (en) 1993-09-14 1996-08-13 Ppg Industries, Inc. Curing composition for acrylic polyol coatings and coating produced therefrom
US5388648A (en) 1993-10-08 1995-02-14 Baker Hughes Incorporated Method and apparatus for sealing the juncture between a vertical well and one or more horizontal wells using deformable sealing means
US5335726A (en) 1993-10-22 1994-08-09 Halliburton Company Water control
US5358051A (en) 1993-10-22 1994-10-25 Halliburton Company Method of water control with hydroxy unsaturated carbonyls
US5377756A (en) 1993-10-28 1995-01-03 Mobil Oil Corporation Method for producing low permeability reservoirs using a single well
US5423381A (en) 1993-10-29 1995-06-13 Texaco Inc. Quick-set formation treating methods
US5381864A (en) 1993-11-12 1995-01-17 Halliburton Company Well treating methods using particulate blends
US5402846A (en) 1993-11-15 1995-04-04 Mobil Oil Corporation Unique method of hydraulic fracturing
DK0654582T3 (en) 1993-11-18 1999-08-30 Halliburton Energy Serv Inc Reduction of precipitation of aluminum compounds by acid treatment of an underground formation
DE69417015T2 (en) 1993-11-19 1999-07-01 Clearwater Inc METHOD FOR TREATING SLATE AND CLAY IN OIL HOLES
EP0656459B1 (en) 1993-11-27 2001-03-28 AEA Technology plc Method for treating oil wells
US5390741A (en) 1993-12-21 1995-02-21 Halliburton Company Remedial treatment methods for coal bed methane wells
US5393810A (en) 1993-12-30 1995-02-28 Halliburton Company Method and composition for breaking crosslinked gels
US5643460A (en) 1994-01-14 1997-07-01 Nalco/Exxon Energy Chemicals, L. P. Method for separating oil from water in petroleum production
FR2716928B1 (en) 1994-03-03 1996-05-03 Inst Francais Du Petrole Water-based process and fluid using hydrophobically modified cellulosic derivatives as a filtrate reducer.
US5445223A (en) 1994-03-15 1995-08-29 Dowell, A Division Of Schlumberger Technology Corporation Delayed borate crosslinked fracturing fluid having increased temperature range
FR2719600B1 (en) 1994-05-04 1996-06-14 Inst Francais Du Petrole Process and fluid used in a well - Application to drilling.
FR2719601B1 (en) 1994-05-04 1996-06-28 Inst Francais Du Petrole Water-based process and fluid for controlling the dispersion of solids. Application to drilling.
US5837656A (en) 1994-07-21 1998-11-17 Santrol, Inc. Well treatment fluid compatible self-consolidating particles
US5494178A (en) 1994-07-25 1996-02-27 Alu Inc. Display and decorative fixture apparatus
US5531274A (en) 1994-07-29 1996-07-02 Bienvenu, Jr.; Raymond L. Lightweight proppants and their use in hydraulic fracturing
US5681796A (en) 1994-07-29 1997-10-28 Schlumberger Technology Corporation Borate crosslinked fracturing fluid and method
US5499678A (en) 1994-08-02 1996-03-19 Halliburton Company Coplanar angular jetting head for well perforating
US5566760A (en) 1994-09-02 1996-10-22 Halliburton Company Method of using a foamed fracturing fluid
US5646093A (en) 1994-09-13 1997-07-08 Rhone-Poulenc Inc. Modified polygalactomannans as oil field shale inhibitors
US5431225A (en) 1994-09-21 1995-07-11 Halliburton Company Sand control well completion methods for poorly consolidated formations
US5498280A (en) 1994-11-14 1996-03-12 Binney & Smith Inc. Phosphorescent and fluorescent marking composition
US5492177A (en) 1994-12-01 1996-02-20 Mobil Oil Corporation Method for consolidating a subterranean formation
GB9426025D0 (en) 1994-12-22 1995-02-22 Smith Philip L U Oil and gas field chemicals
US5551514A (en) 1995-01-06 1996-09-03 Dowell, A Division Of Schlumberger Technology Corp. Sand control without requiring a gravel pack screen
USRE36466E (en) 1995-01-06 1999-12-28 Dowel Sand control without requiring a gravel pack screen
FR2729181A1 (en) 1995-01-10 1996-07-12 Inst Francais Du Petrole WATER-BASED PROCESS AND FLUID USING HYDROPHOBICALLY MODIFIED GUARS AS A FILTRATE REDUCER
US5649323A (en) 1995-01-17 1997-07-15 Kalb; Paul D. Composition and process for the encapsulation and stabilization of radioactive hazardous and mixed wastes
US5522460A (en) 1995-01-30 1996-06-04 Mobil Oil Corporation Water compatible chemical in situ and sand consolidation with furan resin
GB9503949D0 (en) 1995-02-28 1995-04-19 Atomic Energy Authority Uk Oil well treatment
DE69611756T2 (en) 1995-03-01 2001-09-13 Morii Toshihiro PAINT COMPOSITE WITH LONG-LUMINOUS PROPERTIES AND COLOR OBJECTS WITH LONG-LUMINOUS PROPERTIES
US5639806A (en) 1995-03-28 1997-06-17 Borden Chemical, Inc. Bisphenol-containing resin coating articles and methods of using same
US6047772A (en) 1995-03-29 2000-04-11 Halliburton Energy Services, Inc. Control of particulate flowback in subterranean wells
US5501274A (en) 1995-03-29 1996-03-26 Halliburton Company Control of particulate flowback in subterranean wells
US5960878A (en) 1995-03-29 1999-10-05 Halliburton Energy Services, Inc. Methods of protecting well tubular goods from corrosion
US5839510A (en) 1995-03-29 1998-11-24 Halliburton Energy Services, Inc. Control of particulate flowback in subterranean wells
US5582249A (en) 1995-08-02 1996-12-10 Halliburton Company Control of particulate flowback in subterranean wells
US5833000A (en) 1995-03-29 1998-11-10 Halliburton Energy Services, Inc. Control of particulate flowback in subterranean wells
US6209643B1 (en) 1995-03-29 2001-04-03 Halliburton Energy Services, Inc. Method of controlling particulate flowback in subterranean wells and introducing treatment chemicals
US5787986A (en) 1995-03-29 1998-08-04 Halliburton Energy Services, Inc. Control of particulate flowback in subterranean wells
US5775425A (en) 1995-03-29 1998-07-07 Halliburton Energy Services, Inc. Control of fine particulate flowback in subterranean wells
US5604184A (en) 1995-04-10 1997-02-18 Texaco, Inc. Chemically inert resin coated proppant system for control of proppant flowback in hydraulically fractured wells
US5529123A (en) 1995-04-10 1996-06-25 Atlantic Richfield Company Method for controlling fluid loss from wells into high conductivity earth formations
US5551513A (en) 1995-05-12 1996-09-03 Texaco Inc. Prepacked screen
GB9510396D0 (en) 1995-05-23 1995-07-19 Allied Colloids Ltd Polymers for drilling and reservoir fluids and their use
IL114001A (en) 1995-06-02 1998-09-24 Super Disc Filters Ltd Pulsator device and method
US5661561A (en) 1995-06-02 1997-08-26 Accu-Sort Systems, Inc. Dimensioning system
DE19627469A1 (en) 1995-07-12 1997-01-16 Sanyo Chemical Ind Ltd Epoxy resin crosslinking agent and one-component epoxy resin composition
US5836391A (en) 1995-07-25 1998-11-17 Alberta Oil Sands Technology & Research Authority Wellbore sand control method
US5595245A (en) 1995-08-04 1997-01-21 Scott, Iii; George L. Systems of injecting phenolic resin activator during subsurface fracture stimulation for enhanced oil recovery
US5929437A (en) 1995-08-18 1999-07-27 Protechnics International, Inc. Encapsulated radioactive tracer
US5588488A (en) 1995-08-22 1996-12-31 Halliburton Company Cementing multi-lateral wells
US5833361A (en) 1995-09-07 1998-11-10 Funk; James E. Apparatus for the production of small spherical granules
US6028113A (en) 1995-09-27 2000-02-22 Sunburst Chemicals, Inc. Solid sanitizers and cleaner disinfectants
US6528157B1 (en) 1995-11-01 2003-03-04 Borden Chemical, Inc. Proppants with fiber reinforced resin coatings
UA67719C2 (en) 1995-11-08 2004-07-15 Shell Int Research Deformable well filter and method for its installation
US5582250A (en) 1995-11-09 1996-12-10 Dowell, A Division Of Schlumberger Technology Corporation Overbalanced perforating and fracturing process using low-density, neutrally buoyant proppant
US5697448A (en) 1995-11-29 1997-12-16 Johnson; Gordon Oil well pumping mechanism providing water removal without lifting
US5620049A (en) 1995-12-14 1997-04-15 Atlantic Richfield Company Method for increasing the production of petroleum from a subterranean formation penetrated by a wellbore
NO965327L (en) 1995-12-14 1997-06-16 Halliburton Co Traceable well cement compositions and methods
US5697440A (en) 1996-01-04 1997-12-16 Halliburton Energy Services, Inc. Control of particulate flowback in subterranean wells
US5692566A (en) 1996-01-22 1997-12-02 Texaco Inc. Formation treating method
US5704426A (en) 1996-03-20 1998-01-06 Schlumberger Technology Corporation Zonal isolation method and apparatus
US5701956A (en) 1996-04-17 1997-12-30 Halliburton Energy Services, Inc. Methods and compositions for reducing water production from subterranean formations
US6162496A (en) 1996-05-20 2000-12-19 Blue; David Method of mixing
US6620857B2 (en) 1996-07-02 2003-09-16 Ciba Specialty Chemicals Corporation Process for curing a polymerizable composition
US5799734A (en) 1996-07-18 1998-09-01 Halliburton Energy Services, Inc. Method of forming and using particulate slurries for well completion
US5806593A (en) 1996-07-22 1998-09-15 Texaco Inc Method to increase sand grain coating coverage
US5864003A (en) 1996-07-23 1999-01-26 Georgia-Pacific Resins, Inc. Thermosetting phenolic resin composition
US5712314A (en) 1996-08-09 1998-01-27 Texaco Inc. Formulation for creating a pliable resin plug
US5977283A (en) 1996-08-12 1999-11-02 Lear Corporation Thermosetting adhesive and method of making same
US5735349A (en) 1996-08-16 1998-04-07 Bj Services Company Compositions and methods for modifying the permeability of subterranean formations
US5960880A (en) 1996-08-27 1999-10-05 Halliburton Energy Services, Inc. Unconsolidated formation stimulation with sand filtration
GB9619418D0 (en) 1996-09-18 1996-10-30 Urlwin Smith Phillip L Oil and gas field chemicals
US6435277B1 (en) 1996-10-09 2002-08-20 Schlumberger Technology Corporation Compositions containing aqueous viscosifying surfactants and methods for applying such compositions in subterranean formations
US5964295A (en) 1996-10-09 1999-10-12 Schlumberger Technology Corporation, Dowell Division Methods and compositions for testing subterranean formations
US5782300A (en) 1996-11-13 1998-07-21 Schlumberger Technology Corporation Suspension and porous pack for reduction of particles in subterranean well fluids, and method for treating an underground formation
US6059034A (en) 1996-11-27 2000-05-09 Bj Services Company Formation treatment method using deformable particles
US7426961B2 (en) 2002-09-03 2008-09-23 Bj Services Company Method of treating subterranean formations with porous particulate materials
US6330916B1 (en) 1996-11-27 2001-12-18 Bj Services Company Formation treatment method using deformable particles
US6749025B1 (en) 1996-11-27 2004-06-15 Bj Services Company Lightweight methods and compositions for sand control
US20050028979A1 (en) 1996-11-27 2005-02-10 Brannon Harold Dean Methods and compositions of a storable relatively lightweight proppant slurry for hydraulic fracturing and gravel packing applications
US6364018B1 (en) 1996-11-27 2002-04-02 Bj Services Company Lightweight methods and compositions for well treating
US5765642A (en) 1996-12-23 1998-06-16 Halliburton Energy Services, Inc. Subterranean formation fracturing methods
AU6639198A (en) 1997-03-07 1998-09-22 Dsm N.V. Radiation-curable composition having high cure speed
US5830987A (en) 1997-03-11 1998-11-03 Hehr International Inc. Amino-acrylate polymers and method
US5791415A (en) 1997-03-13 1998-08-11 Halliburton Energy Services, Inc. Stimulating wells in unconsolidated formations
US5836393A (en) 1997-03-19 1998-11-17 Johnson; Howard E. Pulse generator for oil well and method of stimulating the flow of liquid
GB9706044D0 (en) 1997-03-24 1997-05-14 Davidson Brett C Dynamic enhancement of fluid flow rate using pressure and strain pulsing
US5865936A (en) 1997-03-28 1999-02-02 National Starch And Chemical Investment Holding Corporation Rapid curing structural acrylic adhesive
GB9708484D0 (en) 1997-04-25 1997-06-18 Merck Sharp & Dohme Therapeutic agents
US5960877A (en) 1997-05-07 1999-10-05 Halliburton Energy Services, Inc. Polymeric compositions and methods for use in well applications
US5840784A (en) 1997-05-07 1998-11-24 Halliburton Energy Services, Inc. Polymeric compositions and methods for use in low temperature well applications
US5968879A (en) 1997-05-12 1999-10-19 Halliburton Energy Services, Inc. Polymeric well completion and remedial compositions and methods
US5981447A (en) 1997-05-28 1999-11-09 Schlumberger Technology Corporation Method and composition for controlling fluid loss in high permeability hydrocarbon bearing formations
US6028534A (en) 1997-06-02 2000-02-22 Schlumberger Technology Corporation Formation data sensing with deployed remote sensors during well drilling
US6169058B1 (en) 1997-06-05 2001-01-02 Bj Services Company Compositions and methods for hydraulic fracturing
US5924488A (en) 1997-06-11 1999-07-20 Halliburton Energy Services, Inc. Methods of preventing well fracture proppant flow-back
US6004400A (en) 1997-07-09 1999-12-21 Phillip W. Bishop Carbon dioxide cleaning process
AU736803B2 (en) 1997-08-06 2001-08-02 Halliburton Energy Services, Inc. Well treating fluids and methods
US6070664A (en) 1998-02-12 2000-06-06 Halliburton Energy Services Well treating fluids and methods
US5944106A (en) 1997-08-06 1999-08-31 Halliburton Energy Services, Inc. Well treating fluids and methods
US5921317A (en) 1997-08-14 1999-07-13 Halliburton Energy Services, Inc. Coating well proppant with hardenable resin-fiber composites
US5887653A (en) 1997-08-15 1999-03-30 Plainsman Technology, Inc. Method for clay stabilization
AU738096B2 (en) 1997-08-15 2001-09-06 Halliburton Energy Services, Inc. Light weight high temperature well cement compositions and methods
US5873413A (en) 1997-08-18 1999-02-23 Halliburton Energy Services, Inc. Methods of modifying subterranean strata properties
US6006836A (en) 1997-08-18 1999-12-28 Halliburton Energy Services, Inc. Methods of sealing plugs in well bores
EP0909875A3 (en) 1997-10-16 1999-10-27 Halliburton Energy Services, Inc. Method of completing well in unconsolidated subterranean zone
US6003600A (en) 1997-10-16 1999-12-21 Halliburton Energy Services, Inc. Methods of completing wells in unconsolidated subterranean zones
US6177484B1 (en) 1997-11-03 2001-01-23 Texaco Inc. Combination catalyst/coupling agent for furan resin
US5944105A (en) 1997-11-11 1999-08-31 Halliburton Energy Services, Inc. Well stabilization methods
US6124246A (en) 1997-11-17 2000-09-26 Halliburton Energy Services, Inc. High temperature epoxy resin compositions, additives and methods
US6140446A (en) 1997-11-18 2000-10-31 Shin-Etsu Chemical Co., Ltd. Hydrosilylation catalysts and silicone compositions using the same
US5893383A (en) 1997-11-25 1999-04-13 Perfclean International Fluidic Oscillator
DE19752093C2 (en) 1997-11-25 2000-10-26 Clariant Gmbh Water-soluble copolymers based on acrylamide and their use as cementation aids
US6059036A (en) 1997-11-26 2000-05-09 Halliburton Energy Services, Inc. Methods and compositions for sealing subterranean zones
GB2332224B (en) 1997-12-13 2000-01-19 Sofitech Nv Gelling composition for wellbore service fluids
EP0926310A1 (en) 1997-12-24 1999-06-30 Shell Internationale Researchmaatschappij B.V. Apparatus and method for injecting treatment fluids into an underground formation
US5960784A (en) 1998-01-26 1999-10-05 Ryan; John Patrick Barbecue grill with smoke incinerator
US6109350A (en) 1998-01-30 2000-08-29 Halliburton Energy Services, Inc. Method of reducing water produced with hydrocarbons from wells
EP0933498B1 (en) 1998-02-03 2003-05-28 Halliburton Energy Services, Inc. Method of rapidly consolidating particulate materials in wells
US6070667A (en) 1998-02-05 2000-06-06 Halliburton Energy Services, Inc. Lateral wellbore connection
US6006835A (en) 1998-02-17 1999-12-28 Halliburton Energy Services, Inc. Methods for sealing subterranean zones using foamed resin
US6516885B1 (en) 1998-02-18 2003-02-11 Lattice Intellectual Property Ltd Reducing water flow
GB2335428B (en) 1998-03-20 2001-03-14 Sofitech Nv Hydrophobically modified polymers for water control
US6012524A (en) 1998-04-14 2000-01-11 Halliburton Energy Services, Inc. Remedial well bore sealing methods and compositions
US6315040B1 (en) 1998-05-01 2001-11-13 Shell Oil Company Expandable well screen
EP0955675B1 (en) 1998-05-07 2004-12-15 Shin-Etsu Chemical Co., Ltd. Epoxy resin compositions and semiconductor devices encapsulated therewith
US6162766A (en) 1998-05-29 2000-12-19 3M Innovative Properties Company Encapsulated breakers, compositions and methods of use
US6458885B1 (en) 1998-05-29 2002-10-01 Ppg Industries Ohio, Inc. Fast drying clear coat composition
US6024170A (en) 1998-06-03 2000-02-15 Halliburton Energy Services, Inc. Methods of treating subterranean formation using borate cross-linking compositions
US6152234A (en) 1998-06-10 2000-11-28 Atlantic Richfield Company Method for strengthening a subterranean formation
US6016870A (en) 1998-06-11 2000-01-25 Halliburton Energy Services, Inc. Compositions and methods for consolidating unconsolidated subterranean zones
US6068055A (en) 1998-06-30 2000-05-30 Halliburton Energy Services, Inc. Well sealing compositions and methods
US6114410A (en) 1998-07-17 2000-09-05 Technisand, Inc. Proppant containing bondable particles and removable particles
US6059035A (en) 1998-07-20 2000-05-09 Halliburton Energy Services, Inc. Subterranean zone sealing methods and compositions
US6582819B2 (en) 1998-07-22 2003-06-24 Borden Chemical, Inc. Low density composite proppant, filtration media, gravel packing media, and sports field media, and methods for making and using same
US6406789B1 (en) 1998-07-22 2002-06-18 Borden Chemical, Inc. Composite proppant, composite filtration media and methods for making and using same
US6242390B1 (en) 1998-07-31 2001-06-05 Schlumberger Technology Corporation Cleanup additive
US6131661A (en) 1998-08-03 2000-10-17 Tetra Technologies Inc. Method for removing filtercake
US6098711A (en) 1998-08-18 2000-08-08 Halliburton Energy Services, Inc. Compositions and methods for sealing pipe in well bores
US6279652B1 (en) 1998-09-23 2001-08-28 Halliburton Energy Services, Inc. Heat insulation compositions and methods
US6124245A (en) 1998-10-07 2000-09-26 Phillips Petroleum Company Drilling fluid additive and process therewith
US6116342A (en) 1998-10-20 2000-09-12 Halliburton Energy Services, Inc. Methods of preventing well fracture proppant flow-back
JP4169171B2 (en) 1998-11-13 2008-10-22 ヤマハマリン株式会社 Oil supply control device for 2-cycle engine
DE19854207A1 (en) 1998-11-24 2000-05-25 Wacker Chemie Gmbh Process for the production of fast-curing molded articles bound with phenolic resin
US6186228B1 (en) 1998-12-01 2001-02-13 Phillips Petroleum Company Methods and apparatus for enhancing well production using sonic energy
US6213209B1 (en) 1998-12-02 2001-04-10 Halliburton Energy Services, Inc. Methods of preventing the production of sand with well fluids
US6607035B1 (en) 1998-12-04 2003-08-19 Halliburton Energy Services, Inc. Preventing flow through subterranean zones
US6176315B1 (en) 1998-12-04 2001-01-23 Halliburton Energy Services, Inc. Preventing flow through subterranean zones
KR100635550B1 (en) 1998-12-09 2006-10-18 니폰 가야꾸 가부시끼가이샤 Hard coating material and film obtained with the same
US6196317B1 (en) 1998-12-15 2001-03-06 Halliburton Energy Services, Inc. Method and compositions for reducing the permeabilities of subterranean zones
US6189615B1 (en) 1998-12-15 2001-02-20 Marathon Oil Company Application of a stabilized polymer gel to an alkaline treatment region for improved hydrocarbon recovery
US6130286A (en) 1998-12-18 2000-10-10 Ppg Industries Ohio, Inc. Fast drying clear coat composition with low volatile organic content
US6192985B1 (en) 1998-12-19 2001-02-27 Schlumberger Technology Corporation Fluids and techniques for maximizing fracture fluid clean-up
US6291404B2 (en) 1998-12-28 2001-09-18 Venture Innovations, Inc. Viscosified aqueous chitosan-containing well drilling and servicing fluids
US6562762B2 (en) 1998-12-28 2003-05-13 Venture Chemicals, Inc. Method of and composition for reducing the loss of fluid during well drilling, completion or workover operations
US6358889B2 (en) 1998-12-28 2002-03-19 Venture Innovations, Inc. Viscosified aqueous chitosan-containing well drilling and servicing fluids
US6780822B2 (en) 1998-12-28 2004-08-24 Venture Chemicals, Inc. Anhydride-modified chitosan, method of preparation thereof, and fluids containing same
US6656885B2 (en) 1998-12-28 2003-12-02 Venture Innovations, Inc. Anhydride-modified chitosan, method of preparation thereof, and fluids containing same
US20030130133A1 (en) 1999-01-07 2003-07-10 Vollmer Daniel Patrick Well treatment fluid
US6123871A (en) 1999-01-11 2000-09-26 Carroll; Michael Lee Photoluminescence polymers, their preparation and uses thereof
DE19904147C2 (en) 1999-02-03 2001-05-10 Herbert Huettlin Device for treating particulate material
US6328106B1 (en) 1999-02-04 2001-12-11 Halliburton Energy Services, Inc. Sealing subterranean zones
US6271181B1 (en) 1999-02-04 2001-08-07 Halliburton Energy Services, Inc. Sealing subterranean zones
US6136078A (en) 1999-02-05 2000-10-24 Binney & Smith Inc. Marking composition and method for marking dark substrates
US6244344B1 (en) 1999-02-09 2001-06-12 Halliburton Energy Services, Inc. Methods and compositions for cementing pipe strings in well bores
US6599863B1 (en) 1999-02-18 2003-07-29 Schlumberger Technology Corporation Fracturing process and composition
US6234251B1 (en) 1999-02-22 2001-05-22 Halliburton Energy Services, Inc. Resilient well cement compositions and methods
EP1031611B1 (en) 1999-02-26 2004-07-21 Shin-Etsu Chemical Co., Ltd. Room temperature fast curable silicone composition
DE19909231C2 (en) 1999-03-03 2001-04-19 Clariant Gmbh Water-soluble copolymers based on AMPS and their use as drilling aids
KR100305750B1 (en) 1999-03-10 2001-09-24 윤덕용 Manufacturing Method for Anisotropic Conductive Adhesive for Flip Chip Interconnection on an Organic Substrate
US6209644B1 (en) 1999-03-29 2001-04-03 Weatherford Lamb, Inc. Assembly and method for forming a seal in a junction of a multilateral well bore
US6148911A (en) 1999-03-30 2000-11-21 Atlantic Richfield Company Method of treating subterranean gas hydrate formations
US6281172B1 (en) 1999-04-07 2001-08-28 Akzo Nobel Nv Quaternary nitrogen containing amphoteric water soluble polymers and their use in drilling fluids
US6063738A (en) 1999-04-19 2000-05-16 Halliburton Energy Services, Inc. Foamed well cement slurries, additives and methods
US6209646B1 (en) 1999-04-21 2001-04-03 Halliburton Energy Services, Inc. Controlling the release of chemical additives in well treating fluids
US6538576B1 (en) 1999-04-23 2003-03-25 Halliburton Energy Services, Inc. Self-contained downhole sensor and method of placing and interrogating same
SG93832A1 (en) 1999-05-07 2003-01-21 Inst Of Microelectronics Epoxy resin compositions for liquid encapsulation
US6534449B1 (en) 1999-05-27 2003-03-18 Schlumberger Technology Corp. Removal of wellbore residues
US6283214B1 (en) 1999-05-27 2001-09-04 Schlumberger Technology Corp. Optimum perforation design and technique to minimize sand intrusion
US6237687B1 (en) 1999-06-09 2001-05-29 Eclipse Packer Company Method and apparatus for placing a gravel pack in an oil and gas well
GB2351098B (en) 1999-06-18 2004-02-04 Sofitech Nv Water based wellbore fluids
US6394181B2 (en) 1999-06-18 2002-05-28 Halliburton Energy Services, Inc. Self-regulating lift fluid injection tool and method for use of same
WO2001004164A2 (en) 1999-07-09 2001-01-18 The Dow Chemical Company Hydrogenation of unsaturated polymers using divalent diene-containing bis-cyclopentadienyl group iv metal catalysts
US6187834B1 (en) 1999-09-08 2001-02-13 Dow Corning Corporation Radiation curable silicone compositions
US6253851B1 (en) 1999-09-20 2001-07-03 Marathon Oil Company Method of completing a well
US6214773B1 (en) 1999-09-29 2001-04-10 Halliburton Energy Services, Inc. High temperature, low residue well treating fluids and methods
US6310008B1 (en) 1999-10-12 2001-10-30 Halliburton Energy Services, Inc. Cross-linked well treating fluids
US6279656B1 (en) 1999-11-03 2001-08-28 Santrol, Inc. Downhole chemical delivery system for oil and gas wells
JP4857421B2 (en) 1999-12-08 2012-01-18 独立行政法人産業技術総合研究所 Biodegradable resin composition
US6311773B1 (en) 2000-01-28 2001-11-06 Halliburton Energy Services, Inc. Resin composition and methods of consolidating particulate solids in wells with or without closure pressure
FR2804953B1 (en) 2000-02-10 2002-07-26 Inst Francais Du Petrole CEMENT DAIRY HAVING HYDROPHOBIC POLYMERS
US6609578B2 (en) 2000-02-11 2003-08-26 Mo M-I Llc Shale hydration inhibition agent and method of use
US6302207B1 (en) 2000-02-15 2001-10-16 Halliburton Energy Services, Inc. Methods of completing unconsolidated subterranean producing zones
US6394184B2 (en) 2000-02-15 2002-05-28 Exxonmobil Upstream Research Company Method and apparatus for stimulation of multiple formation intervals
US6767869B2 (en) 2000-02-29 2004-07-27 Bj Services Company Well service fluid and method of making and using the same
US6257335B1 (en) 2000-03-02 2001-07-10 Halliburton Energy Services, Inc. Stimulating fluid production from unconsolidated formations
AU2001260178B2 (en) 2000-04-05 2005-12-15 Schlumberger Technology B.V. Viscosity reduction of viscoelastic surfactant based fluids
US6745159B1 (en) 2000-04-28 2004-06-01 Halliburton Energy Services, Inc. Process of designing screenless completions for oil or gas wells
GB2382143B (en) 2000-05-01 2004-05-26 Schlumberger Holdings A method for telemetering data between wellbores
US6632778B1 (en) 2000-05-02 2003-10-14 Schlumberger Technology Corporation Self-diverting resin systems for sand consolidation
US6457518B1 (en) 2000-05-05 2002-10-01 Halliburton Energy Services, Inc. Expandable well screen
US6357527B1 (en) 2000-05-05 2002-03-19 Halliburton Energy Services, Inc. Encapsulated breakers and method for use in treating subterranean formations
US6415509B1 (en) 2000-05-18 2002-07-09 Halliburton Energy Services, Inc. Methods of fabricating a thin-wall expandable well screen assembly
WO2001094744A1 (en) 2000-06-06 2001-12-13 T R Oil Services Limited Microcapsule well treatment
CN1200971C (en) 2000-06-12 2005-05-11 三井化学株式会社 Phenolic resin composition
US6450260B1 (en) 2000-07-07 2002-09-17 Schlumberger Technology Corporation Sand consolidation with flexible gel system
US6408943B1 (en) 2000-07-17 2002-06-25 Halliburton Energy Services, Inc. Method and apparatus for placing and interrogating downhole sensors
US6202751B1 (en) 2000-07-28 2001-03-20 Halliburton Energy Sevices, Inc. Methods and compositions for forming permeable cement sand screens in well bores
US6422314B1 (en) 2000-08-01 2002-07-23 Halliburton Energy Services, Inc. Well drilling and servicing fluids and methods of removing filter cake deposited thereby
US6494263B2 (en) 2000-08-01 2002-12-17 Halliburton Energy Services, Inc. Well drilling and servicing fluids and methods of removing filter cake deposited thereby
US6552333B1 (en) 2000-08-16 2003-04-22 Halliburton Energy Services, Inc. Apparatus and methods for determining gravel pack quality
US6478092B2 (en) 2000-09-11 2002-11-12 Baker Hughes Incorporated Well completion method and apparatus
MXPA03001910A (en) 2000-09-12 2003-06-19 Sofitech Nv Evaluation of multilayer reservoirs.
US6439310B1 (en) 2000-09-15 2002-08-27 Scott, Iii George L. Real-time reservoir fracturing process
US6372678B1 (en) 2000-09-28 2002-04-16 Fairmount Minerals, Ltd Proppant composition for gas and oil well fracturing
US6476169B1 (en) 2000-09-28 2002-11-05 Halliburton Energy Services, Inc. Methods of reducing subterranean formation water permeability
US6364016B1 (en) 2000-10-26 2002-04-02 Halliburton Energy Services, Inc. Methods of reducing the water permeability of subterranean formations
US6543545B1 (en) 2000-10-27 2003-04-08 Halliburton Energy Services, Inc. Expandable sand control device and specialized completion system and method
US20040011534A1 (en) 2002-07-16 2004-01-22 Simonds Floyd Randolph Apparatus and method for completing an interval of a wellbore while drilling
US6405796B1 (en) 2000-10-30 2002-06-18 Xerox Corporation Method for improving oil recovery using an ultrasound technique
GB0028264D0 (en) 2000-11-20 2001-01-03 Norske Stats Oljeselskap Well treatment
US20020070020A1 (en) 2000-12-08 2002-06-13 Nguyen Philip D. Completing wells in unconsolidated formations
US6439309B1 (en) 2000-12-13 2002-08-27 Bj Services Company Compositions and methods for controlling particulate movement in wellbores and subterranean formations
US6481501B2 (en) * 2000-12-19 2002-11-19 Intevep, S.A. Method and apparatus for drilling and completing a well
US6648501B2 (en) 2000-12-19 2003-11-18 Wenger Manufacturing, Inc. System for homogeneously mixing plural incoming product streams of different composition
US6627719B2 (en) 2001-01-31 2003-09-30 Ondeo Nalco Company Cationic latex terpolymers for sludge dewatering
US6933381B2 (en) 2001-02-02 2005-08-23 Charles B. Mallon Method of preparing modified cellulose ether
US6729405B2 (en) 2001-02-15 2004-05-04 Bj Services Company High temperature flexible cementing compositions and methods for using same
US6321841B1 (en) 2001-02-21 2001-11-27 Halliburton Energy Services, Inc. Methods of sealing pipe strings in disposal wells
US6767868B2 (en) 2001-02-22 2004-07-27 Bj Services Company Breaker system for fracturing fluids used in fracturing oil bearing formations
US6605570B2 (en) 2001-03-01 2003-08-12 Schlumberger Technology Corporation Compositions and methods to control fluid loss in surfactant-based wellbore service fluids
US6557634B2 (en) 2001-03-06 2003-05-06 Halliburton Energy Services, Inc. Apparatus and method for gravel packing an interval of a wellbore
US6359047B1 (en) 2001-03-20 2002-03-19 Isp Investments Inc. Gas hydrate inhibitor
CA2443390C (en) 2001-04-16 2009-12-15 Halliburton Energy Services, Inc. Methods of treating subterranean zones penetrated by well bores
US6510896B2 (en) 2001-05-04 2003-01-28 Weatherford/Lamb, Inc. Apparatus and methods for utilizing expandable sand screen in wellbores
US6659179B2 (en) 2001-05-18 2003-12-09 Halliburton Energy Serv Inc Method of controlling proppant flowback in a well
MXPA03010715A (en) 2001-05-23 2005-03-07 Core Lab L P Method of determining the extent of recovery of materials injected into oil wells.
US7080688B2 (en) 2003-08-14 2006-07-25 Halliburton Energy Services, Inc. Compositions and methods for degrading filter cake
US6488091B1 (en) 2001-06-11 2002-12-03 Halliburton Energy Services, Inc. Subterranean formation treating fluid concentrates, treating fluids and methods
US20020189808A1 (en) 2001-06-13 2002-12-19 Nguyen Philip D. Methods and apparatus for gravel packing or frac packing wells
US7056868B2 (en) 2001-07-30 2006-06-06 Cabot Corporation Hydrophobe associative polymers and compositions and methods employing them
US6642309B2 (en) 2001-08-14 2003-11-04 Kaneka Corporation Curable resin composition
US6830104B2 (en) 2001-08-14 2004-12-14 Halliburton Energy Services, Inc. Well shroud and sand control screen apparatus and completion method
US6632892B2 (en) 2001-08-21 2003-10-14 General Electric Company Composition comprising silicone epoxy resin, hydroxyl compound, anhydride and curing catalyst
JP2003064152A (en) 2001-08-23 2003-03-05 Japan Epoxy Resin Kk Modified epoxy resin composition and method for producing the same and solventless type coating using the same composition
US6938693B2 (en) 2001-10-31 2005-09-06 Schlumberger Technology Corporation Methods for controlling screenouts
US6837309B2 (en) 2001-09-11 2005-01-04 Schlumberger Technology Corporation Methods and fluid compositions designed to cause tip screenouts
US6367549B1 (en) 2001-09-21 2002-04-09 Halliburton Energy Services, Inc. Methods and ultra-low density sealing compositions for sealing pipe in well bores
AU2002327694A1 (en) 2001-09-26 2003-04-07 Claude E. Cooke Jr. Method and materials for hydraulic fracturing of wells
US6662874B2 (en) 2001-09-28 2003-12-16 Halliburton Energy Services, Inc. System and method for fracturing a subterranean well formation for improving hydrocarbon production
US6601648B2 (en) 2001-10-22 2003-08-05 Charles D. Ebinger Well completion method
US6855672B2 (en) 2001-11-07 2005-02-15 Baker Hughes Incorporated Copolymers useful for gelling acids
US6753299B2 (en) 2001-11-09 2004-06-22 Badger Mining Corporation Composite silica proppant material
US6497283B1 (en) 2001-11-19 2002-12-24 Halliburton Energy Services, Inc. Well cement additives, compositions and methods
US6790812B2 (en) 2001-11-30 2004-09-14 Baker Hughes Incorporated Acid soluble, high fluid loss pill for lost circulation
US6626241B2 (en) 2001-12-06 2003-09-30 Halliburton Energy Services, Inc. Method of frac packing through existing gravel packed screens
US6861394B2 (en) 2001-12-19 2005-03-01 M-I L.L.C. Internal breaker
US6569983B1 (en) 2001-12-20 2003-05-27 Ondeo Nalco Energy Services, L.P. Method and composition for recovering hydrocarbon fluids from a subterranean reservoir
US6962200B2 (en) 2002-01-08 2005-11-08 Halliburton Energy Services, Inc. Methods and compositions for consolidating proppant in subterranean fractures
US6668926B2 (en) 2002-01-08 2003-12-30 Halliburton Energy Services, Inc. Methods of consolidating proppant in subterranean fractures
US7343973B2 (en) 2002-01-08 2008-03-18 Halliburton Energy Services, Inc. Methods of stabilizing surfaces of subterranean formations
US6725931B2 (en) 2002-06-26 2004-04-27 Halliburton Energy Services, Inc. Methods of consolidating proppant and controlling fines in wells
US7267171B2 (en) 2002-01-08 2007-09-11 Halliburton Energy Services, Inc. Methods and compositions for stabilizing the surface of a subterranean formation
US7216711B2 (en) 2002-01-08 2007-05-15 Halliburton Eenrgy Services, Inc. Methods of coating resin and blending resin-coated proppant
US6608162B1 (en) 2002-03-15 2003-08-19 Borden Chemical, Inc. Spray-dried phenol formaldehyde resins
US6830105B2 (en) 2002-03-26 2004-12-14 Halliburton Energy Services, Inc. Proppant flowback control using elastomeric component
US6787506B2 (en) 2002-04-03 2004-09-07 Nalco Energy Services, L.P. Use of dispersion polymers as friction reducers in aqueous fracturing fluids
US6852173B2 (en) 2002-04-05 2005-02-08 Boc, Inc. Liquid-assisted cryogenic cleaning
US6691780B2 (en) 2002-04-18 2004-02-17 Halliburton Energy Services, Inc. Tracking of particulate flowback in subterranean wells
US6725930B2 (en) 2002-04-19 2004-04-27 Schlumberger Technology Corporation Conductive proppant and method of hydraulic fracturing using the same
US20030205376A1 (en) 2002-04-19 2003-11-06 Schlumberger Technology Corporation Means and Method for Assessing the Geometry of a Subterranean Fracture During or After a Hydraulic Fracturing Treatment
EP1362978A1 (en) 2002-05-17 2003-11-19 Resolution Research Nederland B.V. System for treating an underground formation
US7153575B2 (en) 2002-06-03 2006-12-26 Borden Chemical, Inc. Particulate material having multiple curable coatings and methods for making and using same
US6838417B2 (en) 2002-06-05 2005-01-04 Halliburton Energy Services, Inc. Compositions and methods including formate brines for conformance control
US6732800B2 (en) 2002-06-12 2004-05-11 Schlumberger Technology Corporation Method of completing a well in an unconsolidated formation
US6702044B2 (en) 2002-06-13 2004-03-09 Halliburton Energy Services, Inc. Methods of consolidating formations or forming chemical casing or both while drilling
US6840318B2 (en) 2002-06-20 2005-01-11 Schlumberger Technology Corporation Method for treating subterranean formation
US7049272B2 (en) 2002-07-16 2006-05-23 Santrol, Inc. Downhole chemical delivery system for oil and gas wells
US6877560B2 (en) 2002-07-19 2005-04-12 Halliburton Energy Services Methods of preventing the flow-back of particulates deposited in subterranean formations
US6776235B1 (en) 2002-07-23 2004-08-17 Schlumberger Technology Corporation Hydraulic fracturing method
US7428037B2 (en) 2002-07-24 2008-09-23 Carl Zeiss Smt Ag Optical component that includes a material having a thermal longitudinal expansion with a zero crossing
US6886635B2 (en) 2002-08-28 2005-05-03 Tetra Technologies, Inc. Filter cake removal fluid and method
US6705400B1 (en) 2002-08-28 2004-03-16 Halliburton Energy Services, Inc. Methods and compositions for forming subterranean fractures containing resilient proppant packs
US6832651B2 (en) 2002-08-29 2004-12-21 Halliburton Energy Services, Inc. Cement composition exhibiting improved resilience/toughness and method for using same
US6887834B2 (en) 2002-09-05 2005-05-03 Halliburton Energy Services, Inc. Methods and compositions for consolidating proppant in subterranean fractures
US6742590B1 (en) 2002-09-05 2004-06-01 Halliburton Energy Services, Inc. Methods of treating subterranean formations using solid particles and other larger solid materials
US7741251B2 (en) 2002-09-06 2010-06-22 Halliburton Energy Services, Inc. Compositions and methods of stabilizing subterranean formations containing reactive shales
US7091159B2 (en) 2002-09-06 2006-08-15 Halliburton Energy Services, Inc. Compositions for and methods of stabilizing subterranean formations containing clays
US6832650B2 (en) 2002-09-11 2004-12-21 Halliburton Energy Services, Inc. Methods of reducing or preventing particulate flow-back in wells
US6817414B2 (en) 2002-09-20 2004-11-16 M-I Llc Acid coated sand for gravel pack and filter cake clean-up
US6935432B2 (en) 2002-09-20 2005-08-30 Halliburton Energy Services, Inc. Method and apparatus for forming an annular barrier in a wellbore
US6832655B2 (en) 2002-09-27 2004-12-21 Bj Services Company Method for cleaning gravel packs
US6776236B1 (en) 2002-10-16 2004-08-17 Halliburton Energy Services, Inc. Methods of completing wells in unconsolidated formations
MXPA05003835A (en) 2002-10-28 2005-06-22 Schlumberger Technology Bv Self-destructing filter cake.
US7008908B2 (en) 2002-11-22 2006-03-07 Schlumberger Technology Corporation Selective stimulation with selective water reduction
US6766858B2 (en) 2002-12-04 2004-07-27 Halliburton Energy Services, Inc. Method for managing the production of a well
US6846420B2 (en) 2002-12-19 2005-01-25 Halliburton Energy Services, Inc. Process for removing oil from solid materials recovered from a well bore
WO2004057152A1 (en) 2002-12-19 2004-07-08 Schlumberger Canada Limited Method for providing treatment chemicals in a subterranean well
GB2399362B (en) 2003-01-17 2005-02-02 Bj Services Co Crosslinking delaying agents for acid fluids
US6892813B2 (en) 2003-01-30 2005-05-17 Halliburton Energy Services, Inc. Methods for preventing fracture proppant flowback
US6851474B2 (en) 2003-02-06 2005-02-08 Halliburton Energy Services, Inc. Methods of preventing gravel loss in through-tubing vent-screen well completions
US6913081B2 (en) 2003-02-06 2005-07-05 Baker Hughes Incorporated Combined scale inhibitor and water control treatments
US6866099B2 (en) 2003-02-12 2005-03-15 Halliburton Energy Services, Inc. Methods of completing wells in unconsolidated subterranean zones
US7220708B2 (en) 2003-02-27 2007-05-22 Halliburton Energy Services, Inc. Drilling fluid component
US20040211561A1 (en) 2003-03-06 2004-10-28 Nguyen Philip D. Methods and compositions for consolidating proppant in fractures
CA2644213C (en) 2003-03-18 2013-10-15 Bj Services Company Method of treating subterranean formations using mixed density proppants or sequential proppant stages
US6764981B1 (en) 2003-03-21 2004-07-20 Halliburton Energy Services, Inc. Well treatment fluid and methods with oxidized chitosan-based compound
US6981552B2 (en) 2003-03-21 2006-01-03 Halliburton Energy Services, Inc. Well treatment fluid and methods with oxidized polysaccharide-based polymers
US7007752B2 (en) 2003-03-21 2006-03-07 Halliburton Energy Services, Inc. Well treatment fluid and methods with oxidized polysaccharide-based polymers
US6962203B2 (en) 2003-03-24 2005-11-08 Owen Oil Tools Lp One trip completion process
US7114570B2 (en) 2003-04-07 2006-10-03 Halliburton Energy Services, Inc. Methods and compositions for stabilizing unconsolidated subterranean formations
US20040211559A1 (en) 2003-04-25 2004-10-28 Nguyen Philip D. Methods and apparatus for completing unconsolidated lateral well bores
US6951250B2 (en) 2003-05-13 2005-10-04 Halliburton Energy Services, Inc. Sealant compositions and methods of using the same to isolate a subterranean zone from a disposal well
US20040231845A1 (en) 2003-05-15 2004-11-25 Cooke Claude E. Applications of degradable polymers in wells
US8181703B2 (en) 2003-05-16 2012-05-22 Halliburton Energy Services, Inc. Method useful for controlling fluid loss in subterranean formations
US8631869B2 (en) 2003-05-16 2014-01-21 Leopoldo Sierra Methods useful for controlling fluid loss in subterranean treatments
US20040229756A1 (en) 2003-05-16 2004-11-18 Eoff Larry S. Method for stimulating hydrocarbon production and reducing the production of water from a subterranean formation
US7182136B2 (en) 2003-07-02 2007-02-27 Halliburton Energy Services, Inc. Methods of reducing water permeability for acidizing a subterranean formation
US8251141B2 (en) 2003-05-16 2012-08-28 Halliburton Energy Services, Inc. Methods useful for controlling fluid loss during sand control operations
US7117942B2 (en) 2004-06-29 2006-10-10 Halliburton Energy Services, Inc. Methods useful for controlling fluid loss during sand control operations
US8278250B2 (en) 2003-05-16 2012-10-02 Halliburton Energy Services, Inc. Methods useful for diverting aqueous fluids in subterranean operations
US7759292B2 (en) 2003-05-16 2010-07-20 Halliburton Energy Services, Inc. Methods and compositions for reducing the production of water and stimulating hydrocarbon production from a subterranean formation
US8091638B2 (en) 2003-05-16 2012-01-10 Halliburton Energy Services, Inc. Methods useful for controlling fluid loss in subterranean formations
US6978836B2 (en) 2003-05-23 2005-12-27 Halliburton Energy Services, Inc. Methods for controlling water and particulate production
US7114560B2 (en) 2003-06-23 2006-10-03 Halliburton Energy Services, Inc. Methods for enhancing treatment fluid placement in a subterranean formation
US7025134B2 (en) 2003-06-23 2006-04-11 Halliburton Energy Services, Inc. Surface pulse system for injection wells
US7013976B2 (en) 2003-06-25 2006-03-21 Halliburton Energy Services, Inc. Compositions and methods for consolidating unconsolidated subterranean formations
US7178596B2 (en) 2003-06-27 2007-02-20 Halliburton Energy Services, Inc. Methods for improving proppant pack permeability and fracture conductivity in a subterranean well
US7032663B2 (en) 2003-06-27 2006-04-25 Halliburton Energy Services, Inc. Permeable cement and sand control methods utilizing permeable cement in subterranean well bores
US7044224B2 (en) 2003-06-27 2006-05-16 Halliburton Energy Services, Inc. Permeable cement and methods of fracturing utilizing permeable cement in subterranean well bores
US7228904B2 (en) 2003-06-27 2007-06-12 Halliburton Energy Services, Inc. Compositions and methods for improving fracture conductivity in a subterranean well
US7044220B2 (en) 2003-06-27 2006-05-16 Halliburton Energy Services, Inc. Compositions and methods for improving proppant pack permeability and fracture conductivity in a subterranean well
US7036587B2 (en) 2003-06-27 2006-05-02 Halliburton Energy Services, Inc. Methods of diverting treating fluids in subterranean zones and degradable diverting materials
US6981560B2 (en) 2003-07-03 2006-01-03 Halliburton Energy Services, Inc. Method and apparatus for treating a productive zone while drilling
US7021379B2 (en) 2003-07-07 2006-04-04 Halliburton Energy Services, Inc. Methods and compositions for enhancing consolidation strength of proppant in subterranean fractures
US7066258B2 (en) 2003-07-08 2006-06-27 Halliburton Energy Services, Inc. Reduced-density proppants and methods of using reduced-density proppants to enhance their transport in well bores and fractures
US7104325B2 (en) 2003-07-09 2006-09-12 Halliburton Energy Services, Inc. Methods of consolidating subterranean zones and compositions therefor
US20050028976A1 (en) 2003-08-05 2005-02-10 Nguyen Philip D. Compositions and methods for controlling the release of chemicals placed on particulates
US7036589B2 (en) 2003-08-14 2006-05-02 Halliburton Energy Services, Inc. Methods for fracturing stimulation
US7059406B2 (en) 2003-08-26 2006-06-13 Halliburton Energy Services, Inc. Production-enhancing completion methods
US7156194B2 (en) 2003-08-26 2007-01-02 Halliburton Energy Services, Inc. Methods of drilling and consolidating subterranean formation particulate
US7237609B2 (en) 2003-08-26 2007-07-03 Halliburton Energy Services, Inc. Methods for producing fluids from acidized and consolidated portions of subterranean formations
US7017665B2 (en) 2003-08-26 2006-03-28 Halliburton Energy Services, Inc. Strengthening near well bore subterranean formations
US7131491B2 (en) 2004-06-09 2006-11-07 Halliburton Energy Services, Inc. Aqueous-based tackifier fluids and methods of use
US7040403B2 (en) 2003-08-27 2006-05-09 Halliburton Energy Services, Inc. Methods for controlling migration of particulates in a subterranean formation
US7204311B2 (en) 2003-08-27 2007-04-17 Halliburton Energy Services, Inc. Methods for controlling migration of particulates in a subterranean formation
US8076271B2 (en) 2004-06-09 2011-12-13 Halliburton Energy Services, Inc. Aqueous tackifier and methods of controlling particulates
US6997259B2 (en) 2003-09-05 2006-02-14 Halliburton Energy Services, Inc. Methods for forming a permeable and stable mass in a subterranean formation
US7032667B2 (en) 2003-09-10 2006-04-25 Halliburtonn Energy Services, Inc. Methods for enhancing the consolidation strength of resin coated particulates
US7081439B2 (en) 2003-11-13 2006-07-25 Schlumberger Technology Corporation Methods for controlling the fluid loss properties of viscoelastic surfactant based fluids
US7063150B2 (en) 2003-11-25 2006-06-20 Halliburton Energy Services, Inc. Methods for preparing slurries of coated particulates
US20050139359A1 (en) 2003-12-29 2005-06-30 Noble Drilling Services Inc. Multiple expansion sand screen system and method
US20050145385A1 (en) 2004-01-05 2005-07-07 Nguyen Philip D. Methods of well stimulation and completion
US7563750B2 (en) 2004-01-24 2009-07-21 Halliburton Energy Services, Inc. Methods and compositions for the diversion of aqueous injection fluids in injection operations
US20050173116A1 (en) 2004-02-10 2005-08-11 Nguyen Philip D. Resin compositions and methods of using resin compositions to control proppant flow-back
US7159656B2 (en) 2004-02-18 2007-01-09 Halliburton Energy Services, Inc. Methods of reducing the permeabilities of horizontal well bore sections
US7211547B2 (en) 2004-03-03 2007-05-01 Halliburton Energy Services, Inc. Resin compositions and methods of using such resin compositions in subterranean applications
US7063151B2 (en) 2004-03-05 2006-06-20 Halliburton Energy Services, Inc. Methods of preparing and using coated particulates
US20050194142A1 (en) * 2004-03-05 2005-09-08 Nguyen Philip D. Compositions and methods for controlling unconsolidated particulates
US7503404B2 (en) 2004-04-14 2009-03-17 Halliburton Energy Services, Inc, Methods of well stimulation during drilling operations
US7114568B2 (en) 2004-04-15 2006-10-03 Halliburton Energy Services, Inc. Hydrophobically modified polymers for a well completion spacer fluid
US7207387B2 (en) 2004-04-15 2007-04-24 Halliburton Energy Services, Inc. Methods and compositions for use with spacer fluids used in subterranean well bores
US7128148B2 (en) 2004-04-16 2006-10-31 Halliburton Energy Services, Inc. Well treatment fluid and methods for blocking permeability of a subterranean zone
US20050263283A1 (en) * 2004-05-25 2005-12-01 Nguyen Philip D Methods for stabilizing and stimulating wells in unconsolidated subterranean formations
US7541318B2 (en) 2004-05-26 2009-06-02 Halliburton Energy Services, Inc. On-the-fly preparation of proppant and its use in subterranean operations
US20050269101A1 (en) 2004-06-04 2005-12-08 Halliburton Energy Services Methods of treating subterranean formations using low-molecular-weight fluids
US20050269099A1 (en) * 2004-06-04 2005-12-08 Halliburton Energy Services Methods of treating subterranean formations using low-molecular-weight fluids
US20050284637A1 (en) 2004-06-04 2005-12-29 Halliburton Energy Services Methods of treating subterranean formations using low-molecular-weight fluids
US7299875B2 (en) 2004-06-08 2007-11-27 Halliburton Energy Services, Inc. Methods for controlling particulate migration
US7073581B2 (en) 2004-06-15 2006-07-11 Halliburton Energy Services, Inc. Electroconductive proppant compositions and related methods
US7216707B2 (en) 2004-06-21 2007-05-15 Halliburton Energy Services, Inc. Cement compositions with improved fluid loss characteristics and methods of cementing using such cement compositions
WO2006022456A1 (en) 2004-08-27 2006-03-02 Canon Kabushiki Kaisha Water-base ink, ink jet recording method, ink cartridge, recording unit, ink jet recording apparatus, and image forming method
US7255169B2 (en) 2004-09-09 2007-08-14 Halliburton Energy Services, Inc. Methods of creating high porosity propped fractures
US20060052251A1 (en) 2004-09-09 2006-03-09 Anderson David K Time release multisource marker and method of deployment
US7281580B2 (en) * 2004-09-09 2007-10-16 Halliburton Energy Services, Inc. High porosity fractures and methods of creating high porosity fractures
US7093658B2 (en) 2004-10-29 2006-08-22 Halliburton Energy Services, Inc. Foamed treatment fluids, foaming additives, and associated methods
US7237612B2 (en) 2004-11-17 2007-07-03 Halliburton Energy Services, Inc. Methods of initiating a fracture tip screenout
US7461696B2 (en) 2004-11-30 2008-12-09 Halliburton Energy Services, Inc. Methods of fracturing using fly ash aggregates
US7325608B2 (en) 2004-12-01 2008-02-05 Halliburton Energy Services, Inc. Methods of hydraulic fracturing and of propping fractures in subterranean formations
US7281581B2 (en) 2004-12-01 2007-10-16 Halliburton Energy Services, Inc. Methods of hydraulic fracturing and of propping fractures in subterranean formations
US7273099B2 (en) 2004-12-03 2007-09-25 Halliburton Energy Services, Inc. Methods of stimulating a subterranean formation comprising multiple production intervals
US7398825B2 (en) 2004-12-03 2008-07-15 Halliburton Energy Services, Inc. Methods of controlling sand and water production in subterranean zones
US7883740B2 (en) 2004-12-12 2011-02-08 Halliburton Energy Services, Inc. Low-quality particulates and methods of making and using improved low-quality particulates
US7334635B2 (en) 2005-01-14 2008-02-26 Halliburton Energy Services, Inc. Methods for fracturing subterranean wells
US8703659B2 (en) 2005-01-24 2014-04-22 Halliburton Energy Services, Inc. Sealant composition comprising a gel system and a reduced amount of cement for a permeable zone downhole
US7334636B2 (en) 2005-02-08 2008-02-26 Halliburton Energy Services, Inc. Methods of creating high-porosity propped fractures using reticulated foam
US7448451B2 (en) 2005-03-29 2008-11-11 Halliburton Energy Services, Inc. Methods for controlling migration of particulates in a subterranean formation
US7673686B2 (en) 2005-03-29 2010-03-09 Halliburton Energy Services, Inc. Method of stabilizing unconsolidated formation for sand control
US20060240995A1 (en) 2005-04-23 2006-10-26 Halliburton Energy Services, Inc. Methods of using resins in subterranean formations
BRPI0610614A2 (en) 2005-05-02 2010-07-13 Trican Well Services Ltd method for transporting aqueous sludge by particulate hydrophobization
US7500519B2 (en) 2005-05-20 2009-03-10 Halliburton Energy Services, Inc. Methods of modifying fracture faces and other surfaces in subterranean formations
US20060264332A1 (en) 2005-05-20 2006-11-23 Halliburton Energy Services, Inc. Methods of using reactive surfactants in subterranean operations
US8158720B2 (en) 2005-06-28 2012-04-17 Halliburton Energy Services, Inc. Crosslinkable polymer compositions and associated methods
US7318474B2 (en) 2005-07-11 2008-01-15 Halliburton Energy Services, Inc. Methods and compositions for controlling formation fines and reducing proppant flow-back
US7493957B2 (en) 2005-07-15 2009-02-24 Halliburton Energy Services, Inc. Methods for controlling water and sand production in subterranean wells
US20080110624A1 (en) 2005-07-15 2008-05-15 Halliburton Energy Services, Inc. Methods for controlling water and particulate production in subterranean wells
US20070114032A1 (en) 2005-11-22 2007-05-24 Stegent Neil A Methods of consolidating unconsolidated particulates in subterranean formations
US7392847B2 (en) 2005-12-09 2008-07-01 Clearwater International, Llc Aggregating reagents, modified particulate metal-oxides, and methods for making and using same
US7350579B2 (en) 2005-12-09 2008-04-01 Clearwater International Llc Sand aggregating reagents, modified sands, and methods for making and using same
US7500521B2 (en) 2006-07-06 2009-03-10 Halliburton Energy Services, Inc. Methods of enhancing uniform placement of a resin in a subterranean formation
US7678743B2 (en) 2006-09-20 2010-03-16 Halliburton Energy Services, Inc. Drill-in fluids and associated methods
US7687438B2 (en) 2006-09-20 2010-03-30 Halliburton Energy Services, Inc. Drill-in fluids and associated methods
US7678742B2 (en) 2006-09-20 2010-03-16 Halliburton Energy Services, Inc. Drill-in fluids and associated methods
US20080139411A1 (en) 2006-12-07 2008-06-12 Harris Phillip C Methods of treating subterranean formations using hydrophobically modified polymers and compositions of the same
US7730950B2 (en) 2007-01-19 2010-06-08 Halliburton Energy Services, Inc. Methods for treating intervals of a subterranean formation having variable permeability
US7934557B2 (en) 2007-02-15 2011-05-03 Halliburton Energy Services, Inc. Methods of completing wells for controlling water and particulate production

Patent Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3865600A (en) * 1972-03-08 1975-02-11 Fosroc Ag Soil consolidation
US4091868A (en) * 1977-03-07 1978-05-30 Diversified Chemical Corporation Method of treating oil wells
US4718491A (en) * 1985-08-29 1988-01-12 Institut Francais Du Petrole Process for preventing water inflow in an oil- and/or gas-producing well
US5150754A (en) * 1991-05-28 1992-09-29 Mobil Oil Corporation Aqueous and petroleum gel method for preventing water-influx
US5379841A (en) * 1992-04-10 1995-01-10 Hoechst Aktiengesellschaft Method for reducing or completely stopping the influx of water in boreholes for the extraction of oil and/or hydrocarbon gas
US6920928B1 (en) * 1998-03-27 2005-07-26 Schlumberger Technology Corporation Method for water control
US6228812B1 (en) * 1998-12-10 2001-05-08 Bj Services Company Compositions and methods for selective modification of subterranean formation permeability
US6187839B1 (en) * 1999-03-03 2001-02-13 Halliburton Energy Services, Inc. Methods of sealing compositions and methods
US6283210B1 (en) * 1999-09-01 2001-09-04 Halliburton Energy Services, Inc. Proactive conformance for oil or gas wells
US20040144542A1 (en) * 2001-05-25 2004-07-29 Luisa Chiappa Process for reducing the production of water in oil wells
US20030092578A1 (en) * 2001-11-15 2003-05-15 Hirasaki George J. Subterranean formation water permeability reducing methods

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7934557B2 (en) 2007-02-15 2011-05-03 Halliburton Energy Services, Inc. Methods of completing wells for controlling water and particulate production
WO2009087349A1 (en) * 2008-01-08 2009-07-16 Halliburton Energy Services, Inc. Methods for controlling water and particulate production in subterranean wells
CN102250595A (en) * 2011-05-19 2011-11-23 中国石油天然气集团公司 Drilling fluid used for active mud shale drilling
WO2015016934A1 (en) * 2013-08-01 2015-02-05 Halliburton Energy Services, Inc. Resin composition for treatment of a subterranean formation
US10005951B2 (en) 2013-08-01 2018-06-26 Halliburton Energy Services, Inc. Resin composition for treatment of a subterranean formation
CN104449618A (en) * 2015-01-06 2015-03-25 西南石油大学 Temperature-resisting salt-tolerant high-temperature self-cross-linking onsite polymerization water plugging gel
EP3420047B1 (en) * 2016-02-23 2023-01-11 Ecolab USA Inc. Hydrazide crosslinked polymer emulsions for use in crude oil recovery
CN111139039B (en) * 2018-11-02 2022-06-10 中国石油化工股份有限公司 Sulfonated phenolic resin graft modified polymer filtrate reducer and preparation method thereof
CN111139042A (en) * 2018-11-02 2020-05-12 中国石油化工股份有限公司 Resin modified polymer fluid loss agent based on degradation and preparation method thereof
CN111139039A (en) * 2018-11-02 2020-05-12 中国石油化工股份有限公司 Sulfonated phenolic resin graft modified polymer filtrate reducer and preparation method thereof
CN111139042B (en) * 2018-11-02 2022-06-10 中国石油化工股份有限公司 Resin modified polymer fluid loss agent based on degradation and preparation method thereof
WO2020146885A1 (en) * 2019-01-11 2020-07-16 Saudi Arabian Oil Company Methods and compositions for controlling excess water production
CN110387222A (en) * 2019-08-01 2019-10-29 西南石油大学 A kind of porous gel sealing agent, preparation method and application

Also Published As

Publication number Publication date
US20080196897A1 (en) 2008-08-21
US7934557B2 (en) 2011-05-03

Similar Documents

Publication Publication Date Title
US7934557B2 (en) Methods of completing wells for controlling water and particulate production
US7398825B2 (en) Methods of controlling sand and water production in subterranean zones
US7730950B2 (en) Methods for treating intervals of a subterranean formation having variable permeability
US7493957B2 (en) Methods for controlling water and sand production in subterranean wells
US7441598B2 (en) Methods of stabilizing unconsolidated subterranean formations
CA2630319C (en) Methods of consolidating unconsolidated particulates in subterranean formations
US7665517B2 (en) Methods of cleaning sand control screens and gravel packs
US20100186954A1 (en) Methods for controlling water and particulate production in subterranean wells
US7413010B2 (en) Remediation of subterranean formations using vibrational waves and consolidating agents
US7766099B2 (en) Methods of drilling and consolidating subterranean formation particulates
US7690431B2 (en) Methods for controlling migration of particulates in a subterranean formation
WO2007054708A1 (en) Methods for treating a subterranean formation with a curable composition using a jetting tool
WO2009122120A1 (en) Methods for placement of sealant in subterranean intervals
US20050263283A1 (en) Methods for stabilizing and stimulating wells in unconsolidated subterranean formations

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 08709372

Country of ref document: EP

Kind code of ref document: A1

NENP Non-entry into the national phase

Ref country code: DE

122 Ep: pct application non-entry in european phase

Ref document number: 08709372

Country of ref document: EP

Kind code of ref document: A1