WO2008140596A2 - Methods for high figure-of-merit in nanostructured thermoelectric materials - Google Patents

Abstract

Thermoelectric materials with high figures of merit, ZT values, are disclosed In many instances, such materials include nano-sized domains (e g, nanocrystalhne), which are hypothesized to help increase the ZT value of the material (e g, by increasing phonon scattering due to interfaces at grain boundaries or grain/inclusion boundaries) The ZT value of such materials can be greater than about 1, 1.2, 1.4, 1.5, 1.8, 2 and even higher Such materials can be manufactured from a thermoelectric starting material by generating nanoparticles therefrom, or mechanically alloyed nanoparticles from elements which can be subsequently consolidated (e g, via direct current induced hot press) into a new bulk material Non-limiting examples of starting materials include bismuth, lead, and/or silicon-based materials, which can be alloyed, elemental, and/or doped Various compositions and methods relating to aspects of nanostructured theromoelectπc materials (e g, modulation doping) are further disclosed

Description

METHODS FOR HIGH FIGURE-OF-MERIT IN NANOSTRUCTURED THERMOELECTRIC MATERIALS

CROSS REFERENCE TO RELATED APPLICATIONS

The present application is a continuation-in-part of a U S Patent Application bearing serial number 10/977,363, filed October 29, 2004, entitled "Nanocomposites with High Thermoelectric Figures of Merit," and claims the benefit of a U S Provisional Patent Application bearing serial number 60/872,242, filed December 1, 2006, entitled "Methods for High Figure-of-Meπt in Nanostructured Thermoelectric Materials " The contents of all these applications are hereby incorporated herein by reference in their entirety

FIELD OF THE APPLICATION The present application relates generally to thermoelectric materials and methods for their fabπcation, and more particularly, to such thermoelectric materials that exhibit enhanced thermoelectric properties

BACKGROUND The thermoelectric properties of any material can be characterized by a quantity called figure of merit Z (or dimensionless figure of merit ZT), defined as Z = S²σ/k, where S is Seebeck coefficient, σ is electrical conductivity, and k is total thermal conductivity It is desirable to construct materials with high ZT values (e g , having low thermal conductivity k and/or high power factor S²σ) By way of example, such materials can potentially be used to construct high quality power generation devices and cooling devices

SUMMARY

In one aspect, the invention is directed to a method of fabricating a thermoelectric material by generating a plurality of nanoparticles from a starting material such as a thermoelectric bulk material, and consolidating those nanoparticles under pressure at an elevated temperature to form a thermoelectric material that exhibits a higher ZT value than the thermoelectric starting material, e g , at a temperature below about 2000⁰C, below about 1000⁰C, below about 600⁰C, below about 200°C, or below about 2O⁰C In some instances the peak ZT value of the formed material can be about 25% to about 1000% greater than the peak ZT value of the starting material In other instances, the peak ZT of the formed material can be substantially higher than 1000% of the peak ZT of the starting material

The term "nanoparticle" is generally known in the art, and it is used herein to refer to a material particle having a size (e g , an average or a maximum size) less than about 1 micron such as in a range from about 1 nm to about 1000 nm Preferably the size can be less than about 500 nanometers (nm), preferably in a range of about 1 to about 200 nm, and more preferably m a range of about 1 to about 100 nm The nanoparticles can be generated, for instance, by breaking up a starting material into nano-sized pieces (e g , grinding using any of dry milling, wet milling, or other suitable techniques) In one example, ball milling can be used to achieve the desired nanoparticles Optionally, cooling can also be employed while generating nanoparticles

(e g , cooling a starting material while grinding it), so as to further reduce the size of the particles Some other methods of generating the nanoparticles can include condensation from a gas phase, wet chemical methods, and other methods of forming nanoparticles In some cases, nanoparticles of different elemental materials (e g , bismuth or tellurium) can be generated separately, and subsequently consolidated into a resultant thermoelectric material, as discussed further below

The nanoparticles can be consolidated under a selected temperature and selected pressure so as to induce electrical coupling between the nanoparticles sufficient to form the resultant thermoelectric material By way of examples, hot pressing including current induced hot press (but also known as plasma pressure compaction, "P²C", or spark plasma sintering, SPS), unidirectional hot press, and isostatic hot press processes can be used to achieve the consolidation of the nanoparticles The selected pressure can be, for example, in a range of about 10 MPa to about 900 MPa, or in a range of about 40 MPa to about 300 MPa, and preferably m a range of about 60 MPa to about 200 MPa The selected temperature can be, for example, in a range between about 200⁰C to about the melting point of the thermoelectric material (e g , 200⁰C to about 2000⁰C), or in a range of about 400⁰C to about 1200⁰C, or in a range of about 400⁰C to about 600⁰C, or in a range of about 400⁰C to about 550⁰C in the case of Bi2Tβ3 based materials In a related aspect, in the above method, consolidating the nanoparticles refers to compactifying the nanoparticles so as to provide a material exhibiting a density in a range of about 90% to about 100% of the respective theoretical density (e g , a porosity less than about 10% or less than about 1%)

In a related aspect, a thermoelectric material generated by the methods of the invention, such as those discussed above, exhibits a ZT value (e g , a peak ZT value) greater than about 1, or greater than about 1 2, or greater than about 1 4, and preferably greater than about 1 5, and most preferably greater than about 2 Further, in many embodiments, the thermoelectric materials exhibit high ZT values at certain operating temperatures, which can depend, e g , on the materials' melting point, e g , at a temperature below about 300⁰C for Bi₂Te3-based materials The elevated ZT values can also depend on the doping levels and/or the material's microstructure

In many cases, the starting thermoelectric material (e g , a starting bulk material, or a fluid phase material for synthesizing particles) exhibits a ZT value less than about 1, and optionally greater than about 0 1, and the final thermoelectric material, obtained by generating nanoparticles from the starting material (e g , breaking up the starting material by gnnding or other suitable technique) and consolidating those nanoparticles, exhibits a ZT value greater than about 1, 1 1, 1 2, 1 3, 1 4, 1 5, or 2 A variety of thermoelectric materials can be used as the starting material in the practice of the invention The starting thermoelectric material can be p-doped or n- doped Exemplary starting thermoelectric materials include, without limitation, bismuth-based, lead-based, or silicon-based materials For example, the starting thermoelectric material can comprise a bismuth-antimony-telluπum alloy, a bismuth- selenium-tellurium alloy, a lead-tellurium alloy, a lead-selenium alloy, or a sihcon- germanium (e g , SiGe) alloy By way of example, m some embodiments, the thermoelectric material can be Bi₂Te3_-xSeχ alloy, wherein x is in a range of about 0 to about 0 8 Alternatively, in some other embodiments, the thermoelectric material can be Bi_xSb₂-_xTe3 alloy, wherein x is in a range of about 0 to about 0 8 In some embodiments, starting thermoelectric materials can be used that have a polycrystalline structure, which can optionally include an average crystalline gram size (e g , greater than about 1 micron) In another aspect, nanoparticles can be generated from a starting thermoelectric material such that the generated nanoparticles have sizes (e g , average or maximum sizes) less than about 1000 nm, or less than about 500 nm, or less than about 200 ran, and preferably less than about 100 nm, e g , in a range of about 1 nm to about 200 nm, or in a range of about 1 nm to about 100 nm, and preferably in a range of about 1 nm to about 50 nm Such particle sizes can be generated by any of the techniques discussed herein, such as grinding a starting material by ball milling, or other suitable techniques In a related aspect, in the above method, the nanoparticles are held at the elevated temperature under pressure for a time period, e g , in a range of about 1 second to about 10 hours, so as to generate a resultant thermoelectric material with enhanced thermoelectric properties In other aspects, the nanoparticles are subjected to a selected temperature while being held at low or ambient pressure for a time sufficient to allow the resultant thermoelectric material to be formed In another aspect, nanoparticles can be consolidated under high pressure at room temperature to form a sample with high theoretical density (e g , about 100%), and then annealed at high temperature to form the final thermoelectric material

Another aspect is directed to a method of forming a thermoelectric material that includes generating a plurality of nanoparticles By way of example, the particles can be generated by grinding one or more bulk elemental materials For example, the nanoparticles can be generated by grinding at least two different bulk elemental materials such as bismuth and tellurium, bismuth and selenium, antimony and tellurium, antimony and selenium, and silicon and germanium in any workable proportion In such an instance, at least two types of nanoparticles can be formed If the different types of particles are generated separately, the particles can be mixed and further grinded (e g , ball milled) to form mechanically alloyed particles Alternatively, the various bulk materials can all be grinded simultaneously to form the mechanically alloyed particles A mixture of the nanoparticles, formed using mechanical alloying or separately generated nanoparticles from elements, compounds, or alloys, can be compactified under pressure and at an elevated temperature to generate a resultant thermoelectric material exhibiting a ZT value greater than about 1 A dopant can optionally be added to the mixture In other embodiments, the nanoparticles can be compactified with other types of particles such as particles from a source material having a good ZT value (e g , greater than about O 5), and/or micron-sized particles (e g , particles having an average size from about 1 micron to about 10, 50, 100, or 500 microns)

In another aspect, a thermoelectric material is provided that includes a material structure comprising a plurality of inclusions having an average size in a range of about

1 nm to about 500 nm, wherein the structure exhibits a ZT value (e g , a peak ZT value) greater than about 1, and preferably a ZT value greater than about 1 2, or greater than about 1 5, or even greater than about 2

In a related aspect, the thermoelectric material can exhibit the above ZT values at a temperature below about 2000⁰C or below about 1000⁰C or below about 600⁰C or below about 200⁰C or below about 20⁰C Further, the average gram size can be in a range of about 1 to about 500 nm The structure can be substantially free of grams larger than about 500 nm (e g , it is substantially free of grains having an average and/or a maximum dimension greater than about 500 nm), or can include some larger size grains (e g , larger than about 1 μm)

In another aspect, one or more of the grains include one or more precipitation regions or other inclusions therein, where the precipitation region or other inclusion can have, e g , a size in a range of about 1 to about 50 nm, or m a range of about 1 nm to about 20 nm A precipitation region can be characterized by a different composition, and/or the same composition but different crystalline direction, and/or different phase relative to the rest of the grain

In another aspect, the thermoelectric material can have a density in a range of about 90% to about 100% of a respective theoretical density By way of example, the thermoelectric material can exhibit a porosity less than about 10%, and preferably less than about 1%

In a related aspect, the thermoelectric material exhibits a polycrystallme structure formed of small crystalline grains (e g , having average sizes less than about 500 nm, or less than about 200 nm, and preferably m a range of about 1 nm to about 100 nm) randomly oriented relative to one another One aspect of the invention is directed to a thermoelectric material, which can include a material structure having a plurality of grains The grains can have an average size in the range of about 1 micron to about 10 microns, or a range of about 1 micron to about 5 microns, or a range of about 1 micron to about 2 microns At least some of the grains can include one or more precipitation regions or other types of inclusions Such regions can have an average size from about 1 nm to about 100 ran, or about 1 nm to about 50 nm The thermoelectπc material can have a ZT value greater than about 1, 1 2, 1 5, or 2 For example, the ZT value can also be m a range from about 1 to about 5 The thermoelectric material can exhibit such ZT values at an operating temperature less than about 2000⁰C, or less than about 1000⁰C, or less than about 600⁰C, or less than about 200⁰C, or less than about 2O⁰C The grains can be formed from a variety of materials such as any combination of a bismuth-based alloy, a lead-based alloy, and a sihcon- based alloy

Another aspect of the invention is drawn to a thermoelectric material that includes a host material having a plurality of inclusions or particles dispersed throughout the host The particles or inclusions can have a size less than a threshold value, e g , less than about 20 microns Host materials can include one or more grains, where at least some of the grains have a size (e g , a maximum size in any dimension and/or an average size) greater than about 1 micron, or less than about 1 micron In some embodiments, the host materials are not heavily doped as in typical thermoelectπc materials because a large portion of charge carriers, e g , more than 50%, 80%, 90%, and preferably 99% in the host material, are due to the presence of these inclusions In some embodiments, the particles can be more highly doped than the host mateπal The thermoelectric material can exhibit a carrier concentration and/or charge carrier mobility greater than a respective carrier concentration and/or charge carrier mobility of the host mateπal in the absence of the particles or inclusions, and consequently a higher power factor (S²σ) Also, or alternatively, the thermoelectric material can be characterized by the inclusions having an energy band (e g , conduction or valence) for the charge carrier type that has a higher energy relative to the associated energy band of the host material for the corresponding charge carrier type The thermoelectric material can optionally include any number of the properties discussed herein with respect to thermoelectric materials For example, the thermoelectric material can exhibit a ZT value greater than about 1, 1 1, 1 2, 1 3, 1 4, 1 5, or 2 BRIEF DESCRIPTION OF THE DRAWINGS

Some embodiments of the present invention can be better understood with reference to the following drawings, which are not necessarily drawn to scale

FIG IA is a schematic of a plurality of grams in a thermoelectric material, where some of the grains include one or more precipitation regions, consistent with some embodiments of the present invention,

FIG IB is a schematic diagram of a host material with embedded inclusions therein, consistent with some embodiments of the present invention,

FIG 1 C is a schematic of conduction energy diagram for the material depicted in FIG IB,

FIG 2 is an XRD pattern of p-type BiSbTe nanoparticles prepared by ball milling, consistent with some embodiments,

FIG 3 A is a SEM image of the p-type BiSbTe nanoparticles of FIG 2,

FIG 3B is a lower resolution TEM micrograph of the BiSbTe nanoparticles of FIG 2,

FIG 3C is a higher resolution TEM micrograph of the BiSbTe nanoparticles shown in FIG 3B,

FIG 4 is a diagram and photograph of a DC hot press (plasma pressure or spark plasma sintering) device which can be utilized with some embodiments of the present invention, FIG 5 is a graph depicting the temperature dependence of the electrical conductivity for a thermoelectric material prepared from the particles of FIG 2 and a state-of-the-art bulk material of p-type BiSbTe alloy, consistent with some embodiments,

FIG 6 is a graph depicting the temperature dependence of the Seebeck Coefficient for a thermoelectric material prepared from the particles of FIG 2 and a state-of-the-art bulk material of p-type BiSbTe alloy, consistent with some embodiments,

FIG 7 is a graph depicting the temperature dependence of the power factor for a thermoelectric material prepared from the particles of FIG 2 and a state-of-the-art bulk material of p-type BiSbTe alloy, consistent with some embodiments,

FIG 8 is a graph depicting the temperature dependence of the thermal conductivity for a thermoelectric material prepared from the particles of FIG 2 and a state-of-the-art bulk material of p-type BiSbTe alloy, consistent with some embodiments,

FIG 9 is a graph depicting the temperature dependence of the figure of merit, ZT, for a thermoelectric material prepared from the particles of FIG 2 and a state-of-the-art bulk material of p-type BiSbTe alloy, consistent with some embodiments,

FIG 10 is a TEM micrograph of a thermoelectric material prepared from the particles of FIG 2,

FIG 11 is a magnified TEM micrograph of a thermoelectric material prepared from the particles of FIG 2 showing the nano size of the closely packed nanograms,

FIG 12 is a TEM micrograph of a thermoelectric material prepared from the particles of FIG 2 showing the presence of a grain larger than the nanograms shown in FIG 11, FIG 13 is a TEM micrograph of a thermoelectric material prepared from the particles of FIG 2 showing the presence of nanodots,

FIG 14 is a TEM micrograph of a thermoelectric material prepared from the particles of FIG 2 showing the presence of a nanodot with small angle boundaries,

FIG 15 is a TEM micrograph of a thermoelectric material prepared from the particles of FIG 2 showing a Te precipitate, the inset of the figure depicting an electron diffraction pattern of the Te precipitate,

FIG 16 is a graph depicting the temperature dependence of the electrical conductivity for a thermoelectric material prepared from a p-type SiGe bulk starting material, consistent with some embodiments,

FIG 17 is a graph depicting the temperature dependence of the Seebeck Coefficient for a thermoelectric material prepared from a p-type SiGe bulk starting material, consistent with some embodiments,

FIG 18 is a graph depicting the temperature dependence of the thermal conductivity for a thermoelectric material prepared from a p-type SiGe bulk starting material, consistent with some embodiments,

FIG 19 is a graph depicting the temperature dependence of the figure-of-meπt, ZT, for a thermoelectric material prepared from a p-type SiGe bulk starting material, consistent with some embodiments,

FIG 20 is a graph depicting the temperature dependence of the electrical conductivity for a thermoelectric material prepared from a n-type SiGe bulk starting material, consistent with some embodiments, FIG 21 is a graph depicting the temperature dependence of the Seebeck Coefficient for a thermoelectric material prepared from an-type SiGe bulk starting material, consistent with some embodiments,

FIG 22 is a graph depicting the temperature dependence of the thermal conductivity for a thermoelectric material prepared from a n-type SiGe bulk starting material, consistent with some embodiments,

FIG 23 is a graph depicting the temperature dependence of the figure-of-meπt,

ZT, for a thermoelectric material prepared from a n-type SiGe bulk starting material, consistent with some embodiments,

FIG 24 is a TEM micrograph of a ball milled sample of SiGe bulk starting material, consistent with some embodiments of the present invention,

FIG 25 is a TEM micrograph of the particles of FIG 24 after hot pressing, the inset showing a corresponding electron diffraction pattern on the sample,

FIG 26 is a high-resolution TEM micrograph of the hot pressed sample shown in

FIG 25,

FIG 27 is a graph depicting the temperature dependence of the electrical conductivity for a thermoelectric material prepared from a p-type Bio ₃Sbi ₇Te₃ bulk starting material, consistent with some embodiments,

FIG 28 is a graph depicting the temperature dependence of the Seebeck Coefficient for a thermoelectric material prepared from a p-type Bi₀3Sbi ₇Te3 bulk starting material, consistent with some embodiments,

FIG 29 is a graph depicting the temperature dependence of the thermal conductivity for a thermoelectric material prepared from a p-type Bio 3Sbi ₇Te3 bulk starting material, consistent with some embodiments, FIG 30 is a graph depicting the temperature dependence of the figure of merit, ZT, for a thermoelectric material prepared from a p-type Bio 3Sbi

bulk starting material, consistent with some embodiments,

FIG 31 is a graph depicting the temperature dependence of the electrical conductivity for a thermoelectric material prepared from a p-type Bio sSbi ₅Te₃ bulk starting material, consistent with some embodiments,

FIG 32 is a graph depicting the temperature dependence of the Seebeck

Coefficient for a thermoelectric material prepared from a p-type Bio sSbi sTe₃ bulk starting material, consistent with some embodiments,

FIG 33 is a graph depicting the temperature dependence of the thermal conductivity for a thermoelectric material prepared from a p-type Bio sSbi sTβ3 bulk starting material, consistent with some embodiments, and

FIG 34 is a graph depicting the temperature dependence of the figure of merit, ZT, for a thermoelectric material prepared from a p-type Bi₀5Sb₁ gTβ3 bulk starting material, consistent with some embodiments

DETAILED DESCRIPTION

In one aspect, the invention is directed to thermoelectric materials that have high ZT values, and methods of producing such mateπals In general, such thermoelectric materials typically comprise a plurality of grains Such grains can be, e g , in the form of nano-sized grains that can be obtained from a bulk material such as a starting thermoelectric material In general, thermoelectric materials consistent with embodiments of the invention can include a variety of sizes of grains For example, the thermoelectric material can have some grains larger than 1 μm and some grains smaller than 1 μm In some embodiments, thermoelectric materials can be substantially-free of grains that can adversely affect the ZT value of the material (e g , being substantially free of adverse grains that can decrease the ZT value of the entire material by more than about 5%, 10%, 15%, 20%, 25%, 30%, 40%, or 50%) Some embodiments are directed to thermoelectric materials with a plurality of grains having an average grain size on the order of microns (e g , greater than about 1 micron) In some instances, the material can be substantially-free of large grains Non-limiting examples include being substantially free of grains larger than about 5000 nm, 1000 nm, 300 nm, 100 ran, 50 nm, 20 nm, or

10 nm In many cases, such grains can optionally include one or more precipitation regions or other types of inclusions having average sizes, e g , in a range of about 1 nm to about 50 nm In some preferred embodiments, at least some, and preferably substantially all, of the grains include precipitation regions, nanoparticles, and/or other types of inclusions, these various inclusions can be formed in-situ by chemical reaction and/or by insertion of such inclusions Further embodiments are directed to a material having a plurality of grain sizes (e g , at least some nanosized grains and some grains larger than 1 micron), wherein some of the grains can optionally include precipitation regions or other types of inclusions In other words, the thermoelectric materials of the invention can include any combination of sub-micron sized grains with or without precipitation regions, grains larger than 1 micron with or without precipitation regions (e g , using modulation doping), or a mixture of sub-micron grains and grains larger than 1 micron with or without precipitation regions Any of these grains can be formed by a plurality of mechanisms including, but not limited to, precipitation region formation during material compaction, particle insertion into a host matrix, and/or formation by solid-state chemical reaction

The ZT value of a thermoelectric material of the invention can take on a variety of values For example, the peak ZT value, or the average ZT value, of the material can be greater than the peak ZT value, or the average ZT value, of a corresponding starting material from which the thermoelectric material is formed by converting the starting material into nanoparticles and compactifying the nanoparticles under pressure and at an elevated temperature For example, the ZT value of the material can be about 25% to about 1000 % greater than the ZT value of the starting material In other examples, the ZT value of the material can be substantially greater than 1000% of the ZT value of the starting material Starting materials can have a range of ZT values In some embodiments, the ZT values of the formed material can be greater than about 0 8, 0 9, 1, 1 1 , 1 2, 1 3, 1 4, 1 5, 1 6, 1 7, 1 8, 1 9, or 2 In some embodiments, the thermoelectric mateπal can exhibit a ZT value in a range whose lower limit is one of the above ZT values and whose upper limit reaches to a value of about 4, 5, or 6

While these elevated ZT values can be identified without a limitation in temperature, in some embodiments the thermoelectric materials can exhibit the elevated

ZT value at a particular temperature or within a temperature range For example, the thermoelectric material can exhibit an elevated ZT value at a temperature below about 2000°C, below about 1000⁰C, below about 800⁰C, below about 600⁰C, or below about 400⁰C In other examples, the thermoelectric material can exhibit an elevated ZT value at a temperature range that begins to approach, or includes, room temperature (e g , a temperature below about 200⁰C, below about 150⁰C, below about 100⁰C, below about 60⁰C, below about 4O⁰C, below about 3O⁰C, or below about 20°C) In still other examples, the thermoelectric material can exhibit an elevated ZT value at a temperature range that approaches, or includes, cryogenic temperatures (e g , a temperature below about O⁰C, below about -50⁰C, or below about -100⁰C), such materials can be useful for particular cooling applications such as air conditioners, refrigerators, or superconductors In some embodiments, the temperature range in which an elevated ZT value is exhibited can depend upon the composition of a thermoelectric material In some non-limiting examples, a boron-carbide based composition can exhibit, m some embodiments, an elevated ZT value below about 2000⁰C, a SiGe based composition can exhibit, in some embodiments, an elevated ZT value below about 1000⁰C, a PbTe based composition can exhibit, in some embodiments, an elevated ZT value below about 600⁰C, and/or a Bi2Tβ3 based composition can exhibit, in some embodiments, an elevated ZT value below about 200⁰C In another non-limiting example, the thermoelectric material comprises Bi_xSbi_-x and exhibits an elevated ZT below room temperature (e g , below about 20⁰C)

Without necessarily being bound by any particular theory, it is believed that the high ZT values of such thermoelectric materials can be the result of variations in any combination of the thermal conductivity, the Seebeck coefficient, and the electrical conductivity Thermal conductivity has two contributions lattice and electron contributions In single crystals or polycrystalhne samples with large grains, lattice thermal conductivity is fixed for a specific material However, if the bulk material is composed of nanosized grains, and/or nanoparticles embedded in a grain larger than the nanoparticle, we can think of three effects resulting from the nanograms and/or embedded nanoparticles First, the lattice part of thermal conductivity drops due to interface scattering of phonons Second, the Seebeck coefficient can increase because of carrier filtering effect (usually low energy electrons/ holes are scattered thereby increasing Seebeck coefficient), and third, the electrical conductivity can increase because of a modulation doping effect - the particles serve as a carrier (electron and hole) contributors, and hence reduce impurity scattering in comparison to conventional materials that are homogeneously doped The electronic contribution to thermal conductivity can potentially be reduced by interfacial barrier scattering of electrons, especially the bi-polar contribution to thermal conductivity since the barrier can preferentially scatter one-type of charge (electrons or holes) without substantially affecting another type of carrier Additionally, quantum size effects can further affect the Seebeck coefficient and electrical conductivity so that S²σ increases Accordingly, some embodiments of the present invention can utilize nanoparticles prepared, e g , by ball milling a starting material, to prepare dense samples (e g , about 90% to about 100% of theoretical density) by hot press including P²C, unidirectional hot press, isostatic hot press These hot pressed samples typically show lower thermal conductivity compared to the bulk counterpart, thereby enhancing the ZT value, the power factor is usually maintained or enhanced, though it can also be lowered if the gam in ZT from the drop in thermal conductivity is sufficient

In some embodiments, a thermoelectric material can comprise grains generated from a bulk starting material, such as a bulk thermoelectric material Examples include bulk starting materials with a large power factor and/or starting materials with a good ZT value (e g , a ZT value above about 0 1) For instance, the ZT of the starting material can be greater than about 0 05, 0 1, 0 2, 0 3, 0 4, 0 5, or higher In some non-hmitmg instances, the starting material can have a ZT value lower than about 0 8, 0 9, 1, 1 1, 1 2, 1 3, 1 4, 1 5, or 2 In other examples, the starting thermoelectric materials can have a high power factor (e g , S²σ larger than 20 μW/cm-K² and preferably larger than 40 μW/cm-K²) but a large thermal conductivity (e g , larger than 2 W/mK) Such bulk thermoelectric materials can be specifically prepared, or commercially available materials can be utilized Though many bulk starting materials are solids that can be broken apart to generate grains, bulk starting materials can also be generated from other thermodynamic states such as gases, when generating grains from gas phase condensation, or liquids, when generating grams from wet chemical methods It is also understood that the grains can be generated from more than one type of bulk starting material, or a mixture of materials having different thermodynamic phases (e g , a mixture of liquid and gas)

Though any number of starting materials can be utilized, in some embodiments the bulk starting material can be chosen from any combination of a bismuth-based material, a lead-based material, and/or a silicon-based material In some embodiments, the bulk starting materials can be derived from various alloys such as bismuth-antimony- tellurium alloys, bismuth-selenium-telluπum alloys, bismuth-antimony -tellurium- selenium alloys, lead-tellurium alloys, lead-selenium alloys, silicon-germanium alloys, or any combination thereof Particular embodiments can be drawn to using bulk starting materials that are either p-type or n-type materials For example, such starting materials can be compositionally modified forms of a parent composition such as Bi₂Tβ3 By way of example, n-type materials can be obtained by substituting tellurium in Bi₂Tβ3 with selenium such that the stoichiometry of the bulk material has a formula Bi2Te3-_xSe_x, where x is in a range of about 0 to about 0 8 For p-type materials, antimony can be, for example, used to replace bismuth such that the stoichiometry of the bulk material has a formula Bi_xSb₂-_xTe₃, where x is in a range of about 0 to about 0 8 In a particular embodiment, the bulk starting material utilized is Bi₀ sSbi ₅Te₃ In general, the bulk starting materials can be a crystalline material or a polycrystalline material (e g , polycrystalline with an average crystal grain size greater than about a micron) Other examples of starting materials include MgSi₂, InSb, GaAs CoSb₃, Zn₄Sb₃, etc In some instances, the bulk starting material can be a mateπal with a threshold power factor value, S²σ, e g , larger than about 20 μV/cm K² In such instances, the bulk starting mateπal can have a reasonable ZT value (e g , greater than about 0 1) due to the bulk starting material's low thermal conductivity, or the power factor can be at or above a threshold value but the ZT value of the starting material can be low because of the material's relatively high thermal conductivity In some embodiments, particles (e g , nanoparticles) of a thermoelectπc mateπal can be generated from a bulk starting mateπal, or elemental materials, by methods beyond grinding/milling one or more starting materials Particles can be generated by a number of methods, including those methodologies known to the skilled artisan Non- hmiting examples include gas phase condensation, laser ablation, chemical synthesis (e g , wet or dry methods), rapid cooling of sprays, etc Accordingly, the scope of the present application is not limited to the specific particle production methodologies discussed herein It is understood that particle generation techniques can be combined in any fashion to create materials for consolidation For example, some particles can be generated by ball milling (e g , to create a host material), while other particles can be generated by one or more other techniques (e g , gas phase condensation, laser ablation, etc ) Grains that form a thermoelectπc material can have a variety of characteristics

In some embodiments, each grain has a crystalline structure In such an instance, the thermoelectric material can comprise a polycrystalline-hke structure in which the grains generally lack a preferred orientation (e g , randomly distributed) In some instances, the grains can also exhibit some type of preferred orientation due to grain shapes, where the general crystalline direction of the grains can either be random or exhibit some preferred direction relative to one another Accordingly, such embodiments differ substantially from many known thermoelectric materials that exhibit an average crystalline structure (including superlattice structures formed, e g , as a stack of a plurality of semiconducting layers), albeit with small defect or compositional inhomogeneities in the average crystalline structure

Grains of which the various thermoelectric materials discussed herein are composed can have a variety of sizes In some embodiments, the sizes are generally nanometer-scale, and generally smaller than a micron For example, the grains can have an average grain size less than about 500 nm, or less than about 200 nm, or less than about 100 nm, or less than about 50 nm, or less than about 20 nm In such embodiments, the average grain size can be greater than some lower threshold value (e g , about 1 nm) In some cases, the average grain size can be determined using a variety of methodologies, including methods understood by those skilled in the art For example, transmission electron micrographs (herein "TEMs") can be used to image the grains whose sizes can then be determined and averaged Since grains are typically irregularly shaped, the measured size of a grain can be determined using any number of techniques, including ones known to the skilled artisan For example, the largest dimension of the grain can be used from an image (e g , a SEM and/or TEM image), or an effective diameter can be calculated based on surface area measurements or the effective-cross sectional area of grains from an image

In many embodiments of the invention, the grains of a thermoelectric material can be compacted such that the end-product exhibits desired properties such as an elevated ZT value In some embodiments, the thermoelectric mateπal comprises compacted grains in a structure that exhibits a low porosity (e g , the actual density of the end-product can approach the theoretical density of the composition, for instance a bulk starting mateπal used to make nanoparticles in some embodiments), which can aid in obtaining an elevated ZT value Porosity is defined as the difference between the theoretical density and the actual density of the material divided by the theoretical density In general, the phrase "theoretical density" is known to those skilled m the art The porosity in the material can be less than about 10%, 5%, or 4%, or 3%, or 2%, or 1%, or 0 5%, or 0 1% In some embodiments, a thermoelectric material exhibits a density approaching 100% of a theoretical density In some embodiments, the density of a thermoelectric material can be between 100% and 90%, 95%, 96%, 97%, 98%, 99%, 99 5%, or 99 9% of a respective theoretical density Without necessarily being bound by theory, it is believed that densification can help maintain contact between grains, which can help maintain the electrical conductivity of the material Some embodiments are directed to a thermoelectric material formed from a plurality of grains, in which one or more of the grains can include one or more precipitation regions By way of example, FIG 1 schematically depicts such a thermoelectric mateπal that exhibits a polycrystalline structure including a plurality of grains 110 The grains can further include one or more precipitation regions 120, which can enhance the thermoelectric properties of the mateπal A precipitation region can be characterized by a compositional inhomogeneity such as having a different composition and/or phase than the rest of the grain A precipitation region can also be characterized as having a similar crystalline structure to the matrix in which it is embedded, though oriented m a different crystalline direction In some embodiments, one or more precipitation regions can be embodied as a discrete particle (e g , a nanoparticle) embedded in a grain, or the whole grain can be embodied as a crystal, albeit with defects due to the presence of a precipitation region In some embodiments, the thermoelectric material can include other grains that do not have precipitation regions In an alternative embodiment, substantially all of the grains that comprise a thermoelectric material include precipitation regions The precipitation regions typically have sizes (e g , maximum average size) less than about 10 run, or less than about 50 run (e g , in a range of about 1 nm to about 50 nm) Formation of precipitation regions can be achieved in a variety of manners including the techniques discussed in U S Patent Application Publication No US 2006/0102224, bearing serial number 10/977,363, filed October 29, 2004, entitled "Nanocomposites with High Thermoelectric Figures of Merit," which is incorporated herein by reference in its entirety In some cases, the precipitation regions are generated spontaneously through the formation of the thermoelectric mateπal, e g , via the methods discussed herein In other cases, the precipitation regions are generated by mixing two types of nanoparticles having different melting temperatures For example, one type can have a lower melting point than the other By mixing the nanoparticles and heating/consolidating them (e g , at a temperature close to the melting point of one type of the nanoparticles but below the melting point of the other type), the nanoparticles having the lower melting temperature can form grains around the other type of nanoparticles In other words, grains formed of one type of the nanoparticles can embed the nanoparticles of the other type Examples of ensemble materials that can be used to form such embedded nanoparticles include bismuth-telluπde mateπal systems, lead-telluπde mateπal systems, silicon-germanium mateπal systems, etc

It should be understood that though the aforementioned discussion is explicitly directed to precipitate formation in thermoelectric materials, other materials are formed by utilizing other types of inclusions into a matrix (e g , use of nanoparticles in a host) For example, two or more types of nanoparticles can be mixed together to form a thermoelectric material may not include precipitates but can still have advantageous properties (e g , use of modulation doping) Accordingly, the disclosure herein regarding precipitates can also be utilized with respect to other types of inclusions where appropriate For example, the precipitation or inclusion regions can be formed via solid- state chemical reaction of a particle with the host, such as Mo, Fe, Mn, Mg, Ag, Cr, W,

Ta, Ti, Cu, Ni, or V metallic particle reacting with Si in a SiGe host to form MoSi₂, FeSi₂, MgSi₂, etc particles Without being limited to any particular theory, it is believed that the precipitation regions or other types of inclusions can enhance phonon scattering in a thermoelectric material, which can lead to lowering of the thermal conductivity of the material In addition, n-doped or p-doped regions can enhance electrical conductivity of the material, e g , via a modulation-doping mechanism In such an instance, some or all of the charge carriers (electrons and holes) can be donated by precipitation regions or other inclusions embedded in larger grains Because the distance between inclusion regions can be larger than the distance between atomic dopants in a homogeneously doped material, the impurity scattering of the charge carriers is reduced compared to that in homogeneously doped materials Such a modulation-doping like mechanism can increase the electrical conductivity through improving carrier mobility In some instances, these precipitation regions or other inclusions can also improve the Seebeck coefficient by scattering low energy carriers more than higher energy ones As such, the precipitation regions or other inclusions can improve the ZT of the thermoelectric material

In other embodiments, precipitation regions, or gram regions or other inclusions, may be preferentially doped In such circumstances, the carriers of these regions can fall into the surrounding host medium when they are at a higher potential energy For example, in the case of modulation doping, doping in the host material can be correspondingly reduced or completely eliminated, thus enhancing the electron mobility in the host by reducing ionized impurity scattering

Embodiments that include precipitation regions or other inclusions in grains can exhibit any number of grain sizes In some embodiments, the gram sizes are consistent with any of the sizes described herein for grains that are generally smaller than a micron For example, the average grain size can be less than about 500 nm, about 200 nm, about

100 nm, about 50 nm, or about 20 nm Alternatively or in addition, the average grain size can be greater than about 1 nm In other embodiments with one or more inclusions, the gram sizes can be larger than a micron For example, a plurality of grains can have average sizes up to about 2 microns, 5 microns, or 10 microns In particular embodiments, the plurality of grains have an average size in a range of about 1 micron to about 10 microns, or in a range of about 1 micron to about 5 microns, or m a range of about 1 micron to about 2 microns The size of the precipitation regions or inclusions can also vary For example, the size of the precipitation region can be bound by the size of the grain in which it is embedded In many embodiments, a precipitation region or inclusion can preferably have an average size in a range of about 1 nm to about 50 nm, or a range from about 1 nm to about 20 nm In other instances, for example when a modulation doping mechanism is used to increase the electron performance, the precipitation region or inclusion can have a larger size, e g , from 1 nm to 10 microns, while the phonon thermal conductivity reduction in the surrounding region is achieved by alloying or nanograining

Some embodiments are directed to manufactured thermoelectric materials that exhibit modulation doping to achieve enhanced figures of merit In some embodiments, a thermoelectric material can include particles (e g , nanoparticles) or other inclusions embedded in a host material, where the inclusions donate charge carriers (e g , electrons or holes) to the host, thereby increasing the carrier mobility in the host This can advantageously enhance the electrical conductivity of the entire material, and hence improve its thermoelectric performance, e g , characterized by the material's ZT value In many such cases, the host is selected to be initially undoped or to have an n-type or p- type doping level (typically a doping level that is spatially substantially uniform) that is less than typical doping values for thermoelectric materials For example, the initial doping level of the host can be a factor of 1 5, 2, 5, 10, 100, or 1000 less than a conventional thermoelectric material Further, the embedded inclusions (e g , precipitation sites or distinct particles) can be formed of doped or undoped materials By way of example, FIG IB schematically depicts such a thermoelectric material that includes a host 130 m which a plurality of particles 140 are embedded - the particles acting as inclusions In this case, the host includes a plurality of grams 135, e g , a plurality of crystalline grains, which have in some cases sizes (e g , maximum grain size in any dimension) less than about 1 micron, e g , in a range of about 500 nm to less than about 1 micron In other cases, the gram sizes can be larger, e g , in a range of about 1 micron to about 20 microns Further, while in some cases the particles can have sizes (e g , a maximum size in any direction) less than about 1 micron, e g , in a range of about 1 nm to about 200 nm or in a range of about 2 nm to about 100 nm, in other cases the particle sizes can be greater than 1 micron, e g , in a range of about 1 micron to about 10 microns The inclusions 140 can be formed in a variety of ways For example, they can be formed as precipitation regions using any appropriate technique including those discussed with respect to other embodiments herein In other cases, they can be formed of a material different than that of the host by utilizing, e g , the techniques discussed in the above-referenced patent application entitled "Nanocomposites with High Thermoelectric Figures of Merit " In yet other cases, the particles can be formed via solid-state chemical reaction, e g , during a consolidation phase

Without loss of generality, in this example, the host 130 is assumed to be a SiGe alloy having a plurality of micron-sizes and/or nanosized grains 135, and the particles

140 can be MoSi₂ (molybdenum silicide) particles that are embedded in the SiGe alloy Such a thermoelectrical material can be formed, e g , m the following way adding molybdenum to SiGe, melting the material, and cooling the material (e g , in a manner discussed above) to make ingots, which can be grinded and compacted if needed In this approach, the MoSi₂ particles are formed via a solid-state chemical reaction of Mo with

Si, e g , during the cooling process In this example, the SiGe host is not heavily doped although in other cases it can be, e g , it can be doped p-type, but less than in a conventional SiGe thermoelectric materials by a factor of 2, 5, 10, or 100 Additionally, holes can be generated by the presence of MoSi₂ Such donation of the holes to the host can enhance the hole mobility within the material and hence improve the electrical conduction and consequently thermoelectric performance of the material In other instances, the particles can be formed via solid-state chemical reaction of a Si m a host (e g , SiGe) by grinding Si and Ge elements or SiGe crystalline alloy with Fe, Mn, Mg, Cr, W, Ta₅ Ti, Cu, Ni, or V to form FeSi₂, MgSi₂, etc particles, or grinding the respective suicides with the Si and Ge or SiGe alloy together Some of them may be applicable to n-type while others to p-type materials Other nanoparticles (e g , metallic and/or semiconductor nanoparticles) that do not react with Si can also be used to create modulation doping such as Ag as inclusions

For further illustration of such donation of charge carriers from the particles to the host, without being limited to any particular theory, FIG 1C schematically depicts a charge carrier energy diagram corresponding to a hypothetical thermoelectric material (e g , the above SiGe-based material having MoSi₂ particles embedded therein) representing portions 151, 152, 153 corresponding to the host material and portions 161, 162 corresponding to a particle embedded in the host It is understood that the diagram is schematic and presented only for illustrative purposes Charge carriers (e g , electrons or holes) in a energy band of the particles 161, 162 (e g , a conduction or valence band) can have higher energy than those in an energy band of the host 151, 152, 153, which can be the conduction or valence band Accordingly, a plurality of charge earners in the particles, which can be either due to additional doping in the particle or due to its intrinsic large density of electrons (as in metals or semimetals), can move to the host to lower their energies This transfer of charge carriers from the particles to the host can advantageously increase carrier mobility, e g , by reducing dopant in the host material and hence reducing the ionized impurity scattering In this manner, a higher electrical conduction can be achieved In some cases, even though an overall higher electron mobility is not achieved, because grain boundaries still scatter electrons, this modulation doping method can still beneficial by compensating for the reduction in mobility due to electron grain boundary scattering The particles used for modulation doping can also potentially lead to higher Seebeck coefficient as they can scatter low energy carriers, and reducing thermal conductivity of both phonons and electrons In some other cases, rather than donating electrons to the host, the particles can donate holes to the host Again, without being limited to any particular theory, the mechanism of such donation of charge carriers from the particles to the host can be based on some holes moving from higher energy levels in the valence band of the particles to lower energy levels in the valence band of the host, or by attracting electrons in the valence band of the host into the particles, creating more holes in the host, or attracting electrons in the valence band of the host into the particles, creating more holes in the host In general, the types of starting materials, the temperatures at which an elevated

ZT is measured, the gram constituents, the formation methods, and other properties and processes that can be associated with these embodiments include all the traits and methods discussed within the present application, which are consistent with the grain sizes, precipitation regions, and/or other inclusions described For example, the grains can be formed of any suitable thermoelectric material, such as those discussed above, and can further include n-type or p-type dopants In another example, the formed thermoelectπc material has a ZT value greater than about 1 0, greater than about 1 5, greater than about 2, or in a range from about 1 to about 5 In yet another example, the formed thermoelectric material has a ZT value (e g , elevated relative to a starting material) at an operating temperature below about 2000°C, below about 1000⁰C, below about 600⁰C, below about 200⁰C, or below about 20⁰C In another example, the grains of the thermoelectric material can include at least one of a bismuth-based material (e g ,

Bi₂T β3 and/or its associated alloys), a silicon-based material, and a lead-based material With regard to producing such materials, the methods of forming nanoparticles from bulk starting materials, or elemental materials, can be applied as discussed herein, albeit by adjusting parameters such as grinding speeds, duration, and/or temperature (including cryogenic) to obtain the desired nanoparticle sizes for compaction Further, such adjustment of the nanoparticle sizes can be employed to obtain desired gram sizes in the final thermoelectric material (e g , less than 1 micron, or greater than 1 micron but less than 10 microns) The compaction methods can also be applied as discussed herein, and as applied by one skilled in the art Other embodiments of the present application are directed toward methods of fabricating a thermoelectric material In such a method, a plurality of nanoparticles is generated from a thermoelectric material The nanoparticles can be consolidated under pressure at an elevated temperature to form the thermoelectric material The types of thermoelectric starting materials that can be utilized to generate the nanoparticles include, without limitation, any of the bulk materials disclosed herein, and others known to those skilled in the art Accordingly, embodiments can include thermoelectric materials having a ZT value greater than about 1 (e g , at a temperature below about 2000⁰C) In addition or alternatively, the methods can utilize starting materials (e g , bulk thermoelectπcs which are elemental and/or alloys) that are n-doped or p-doped A variety of techniques can be utilized to generate the nanoparticles from a thermoelectric material In some embodiments, the nanoparticles are produced by grinding the thermoelectric material Grinding can be performed using a mill, such as a ball mill using planetary motion, a figure-eight-like motion, or any other motion When generating nanoparticles, some techniques, such as some grinding techniques, produce substantial heat, which may affect the nanoparticle sizes and properties (e g , resulting in particle agglomeration) Thus, in some embodiments, cooling of a thermoelectric material can be performed while grinding the material Such cooling may make a thermoelectric material more brittle, and ease the creation of nanoparticles Cooling and particle generation can be achieved by wet milling and/or cryomilling (e g , in the presence of dry-ice or liquid nitrogen surrounding the mill) Embodiments of the invention can also utilize other methods for forming nanoparticles Such methods can include gas-phase condensation, wet chemical methods, spinning molten materials at high speed, and other suitable techniques

Consolidation of the nanoparticles under pressure and elevated temperature can be performed in a vaπety of manners, under a variety of conditions Processes such as hot press (herein "P²C"), also known as spark plasma sintering, can be employed to impose the desired pressure and temperature during consolidation A description of this process, and an apparatus for carrying out this process, is available in U S Patent Application Publication No US 2006/0102224, bearing serial number 10/977,363, filed October 29, 2004, which is incorporated by reference in its entirety herein

The pressures utilized are typically super-atmospheric, which allow for the use of lower temperatures to achieve consolidation of the nanoparticles In general, the pressures utilized can range from about 10 MPa to about 900 MPa In some embodiments, the pressure ranges from about 40 MPa to about 300 MPa In other embodiments, the pressure ranges from about 60 MPa to about 200 MPa

With respect to the elevated temperature, a range of temperatures can be utilized In general, the temperature typically ranges from about 200⁰C to about the melting point of the thermoelectric material In some exemplary embodiments, the temperature is in a range from about 400⁰C to about 2000⁰C, from about 400⁰C to about 1200⁰C, from about 400⁰C to about 600⁰C, from about 400⁰C to about 55O⁰C For some exemplary n-doped materials, the temperature is in a range from about 450⁰C to about 55O⁰C, while for some exemplary p-doped materials the range is a few degree higher (e g , in a range of about

475 ⁰C to about 580 ⁰C) Other temperature ranges can also be utilized in connection with processing n and p-type materials These particular pressure and temperature ranges can be utilized with any material, though they can preferably be applied to materials such as BiSbTe alloys and BiSeTe alloys The pressures and temperatures can be maintained for a time sufficient to allow consolidation of the nanoparticles In some embodiments, the time is in the range from about 1 sec to about 10 hours Other consolidation techniques can also be utilized to form the thermoelectric materials described in the present application For example, nanoparticles can be impacted at high speed against other particles to achieve low temperature compaction Subsequent heat treatment can optionally be utilized to form the thermoelectric material

Other consolidation processes can utilize annealing of particles (e g , nanoparticles) using little or no pressure to consolidate the particles In such instances, the temperature can be selected to induce annealing of particles at whatever pressure the sample is held at during annealing In other instances, particles can be consolidated at high pressure at a relatively low temperature to form a consolidated material, such as a material with close to 100% theoretical density The consolidated material can be subsequently annealed at an elevated temperature to form the thermoelectric material Accordingly, consolidation techniques need not be restricted to P²C or hot pressing methods As an exemplary embodiment, nanopowders of various materials from commercial materials can be prepared by high energy ball milling to obtain nanoparticles with particle sizes as small as 1 nm In some cases, dry milling can be combined with wet milling and/or cryo-milling to inhibit agglomeration of the milled particles into larger size particles due to heat generated during the milling In this manner, more dispersed particles can be obtained These powders can be compacted into solid samples by hot press including a P²C technique In many embodiments, about

100% density of the theoretical value can be achieved by this method within a short period of time (typically about 1 to about 10 minutes per sample) The lattice thermal conductivity of hot pressed samples prepared by these methods can be reduced to a fraction of the original value in both n- and p-types while maintaining a power factor comparable to the bulk counterpart thereby substantially enhancing the ZT value

For example, in a p-type commercial material of Bi_xSb₂-_xTe3, where x can range from about 0 to about 0 8, the commercial material has a highest ZT value about 1 whereas after ball milling and hot pressing, it can be as much as 1 4 or higher These enhancements are primarily due to reduced thermal conductivity attributed to the presence of nanostructures in the samples

In some embodiments, rather than converting a thermoelectric starting material into nanoparticles (or using some other particle generation method) and compactifying those nanoparticles, nanoparticles are generated (e g , by grinding) from at least two elemental materials (e g , elemental Bi and elemental Te) The nanoparticles are then mixed and compactified under pressure and at elevated temperature (e g , the pressures and temperatures discussed above) to generate a resultant thermoelectric material (e g , one having a polycrystalline structure with grains having sizes less than about 500 nm, and preferably in a range of about 1 to about 100 nm) that exhibits a ZT value greater than about 1, and preferably greater than about 1 2, or about 1 5, or about 2

In an alternative embodiment, two or more bulk materials can be grinded simultaneously to generate a variety of nanoparticles having different compositions The grinding process can be used to "mechanically alloy" the nanoparticles Mechanical alloying can also be performed by generating two or more different particles separately, and subsequently mixing the particles together and further grinding them to alloy and decrease the size of the particles to form alloyed nanoparticles The particles can be consolidated to form a thermoelectric material having one or more of the properties discussed in the present application

In yet another embodiment, different types of nanoparticles can be separately generated using any of the techniques discussed herein (e g , grinding bulk elemental materials such as bismuth or tellurium), and then mixed together and consolidated to form a thermoelectric material Additional grinding of the mixture can optionally be applied before consolidation The end-consolidated material formed by any of these processes can have any of the composition characteristics described within the present application, e g , Bi₂Te_3-xSe_x where x is m a range of about 0 to about 0 8 such as Bi₂Te_{2 δ}Seo _% or Bi_xSb₂-_xTe3, wherein x is in a range from about 0 to about 0 8 such as

Other embodiments directed to forming thermoelectric materials utilize one or more repetitions of steps used to form thermo electrics as discussed herein For example, particles (e g , nanoparticles) can be generated from one or more starting materials (e g , bulk starting thermoelectric materials or elemental materials) and consolidated into a material structure The resulting structure can then be used to generate a new plurality of particles (e g , by grinding the material structure), which can be subsequently consolidated to form another material structure This process can be repeated any number of times to form an end-thermoelectric material Such a process can aid in generating small grain sizes that are thoroughly mixed For some embodiments, it can be advantageous to protect particles that are being generated from oxidation (e g , during a ball milling process) Non-hmitmg examples of protection techniques include exposing the generated particles (e g , the environment in which grinding of a material takes place) to an oxygen-depleted environment such as a relative vacuum or an environment with low oxygen content relative to atmospheric pressure The generated particles can also be exposed to some type of chemical coating to reduce oxygen exposure to the surface, the coating can be optionally removed later in the thermoelectric material manufacturing process Accordingly, protection schemes can include any number of adequate techniques, including those known to one skilled in the art

The following experimental section is provided for further illustration of various aspects of the invention and for illustrating the feasibility of utilizing the methods of the invention for generating thermoelectric materials exhibiting enhanced thermoelectric properties It should, however, be understood that the following examples are provided only for illustrative purposes and are not necessarily indicative of optimal results achievable by practicing the methods of the invention

EXPERIMENTAL RESULTS

Commercial materials (p-type BiSbTe alloy ingots) were pulverized and loaded into a zirconiajar inside the glove box in an argon atmosphere to avoid oxidation A few zirconia balls (5-15 mm size) were also added and sealed The sealed jar was placed into a ball null and milled for total of about 0 5 to 50 hours at a speed of 100 to 2000 rpm The powders were characterized using scanning electron microscope (SEM), transmission electron microscope (TEM), and x-ray diffraction (XRD)

FIG 3 shows the x-ray diffraction (XRD) pattern of the nanopowders after ball milling The XRD pattern verifies that the powder is a single phase, and is well matched with those Of Bi_{0 5}Sb₁ sTe^ The broadened diffraction peaks indicates that the particles are small The small size is confirmed by the scanning electron microscope (SEM) image of the nanopowders depicted in FIG 2 A, and the lower magnification transmission electron microscope (TEM) image of the powder presented in FIG 2B The lower resolution TEM image of FIG 2B clearly shows that the nanoparticles have sizes of a few to about 50 nm, with an average size about 20 nm The high resolution TEM image presented by FIG 2C confirmed the good crystalhnity of the nanoparticles and the clean particle surfaces, which are desired for good thermoelectric properties

The inset of FIG 2C also shows that some of the nanoparticles are even smaller than 5 nm

Once the powders were obtained, powder samples were processed into bulk disk samples of ¹A" in diameter and 2 - 12 mm thick by hot-pressing of the nano powders loaded in a ¹A" diameter die The powders after milling, which were stored inside the glove box to prevent oxidation, were loaded into a graphite die and pressed into pellets using a DC hot press technique (see FIG 4) Parameters for the hot pressing conditions are from 40-160 MPa and 450⁰C - 600⁰C The densities are close to 100% of the theoretical value for all the compositions Disks of ¹A" diameter and 2 mm thick and bars of about 2 x 2 x 12 mm³ were cut and polished from the pressed disks for measurements of the electrical and thermal conductivities and Seebeck coefficient using both DC and AC methods

Typically in preparing the hot pressed samples, the powder is exposed to the selected pressure and the device is activated at a designated heating rate Upon reaching a selected elevated temperature, the sample is held at the temperature and pressure for anywhere between about 0 mm and to about 60 mm, preferably between about 0 min to about 30 min, between about 0 min to about 10 min, or between about 0 mm and less than 5 min (e g , for 2 min ) Then cooling is initiated It is understood, however, that the pressure can be imposed during or after the sample reaches the elevated temperature FIGS 5-9 compare the temperature dependence of various properties of a hot pressed nano crystalline material (labeled BP0572) and a commercial material (labeled com ingot) p-type BiSbTe alloy ingot All the properties are measured from the same sample in FIGS 5-9 Cylinder-like thick disks were hot-pressed and cut both along and perpendicular to the press direction and then measured To test the temperature stability of the nanocrystalline bulk samples, the same samples were repeatedly measured up to

25O⁰C No significant property degradation was observed FIG 5 compares the temperature dependence of the electrical conductivity of the nanocrystalline and commercial samples The electrical conductivity was measured by a four-point current-switching technique The electrical conductivity of the nanocrystalline bulk sample is slightly higher than that of the commercial mgot

FIG 6 presents the temperature dependencies of the Seebeck coefficient for the nanocrystalline and commercial samples, while FIG 7 compares the power factor (S²σ) temperature dependencies of the samples The Seebeck coefficients were measured by a static DC method based on the slope of a voltage vs temperature-difference curve, using commercial equipment (ZEM-3, Ulvac, Inc ) on the same bar-type sample with a dimension of 2^χ2 mm² in cross-section and 12 mmin length, cut along the disk plane These properties were also measured on a home-made system on the same sample The two sets of measurements are within 5% of each other The Seebeck coefficient of the nanocrystalline sample is either slightly lower or higher than that of the ingot depending on temperature, which makes the power factor of the nanocrystalline sample comparable to that of the commercial ingot below 75°C and higher than that of the commercial ingot above 75⁰C

FIG 8 depicts the temperature dependencies of the thermal conductivity for the nanocrystalline and commercial samples The thermal conductivities are derived from measurements of the thermal diffusivities and the heat capacities of the samples The thermal diffusivity was measured by a laser-flash method on a disk along the disk axial direction using a commercial system (Netzsch Instruments, Inc ) After the laser-flash measurements, bars were diced from the disks and their thermal diffusivities were measured along the bar (disk-plane) direction using an Angstrom method in the home- built system The thermal diffusivity values of the bar and of the disk are in agreement within 5%

FIG 9 documents the variation in the figure of merit, ZT , as a function of temperature for the nanocrystalline and commercial samples Since the thermal conductivity of the nanocrystalline bulk samples is significantly lower than that of the commercial ingot, and more importantly the difference increases with increasing temperature, this leads to significantly enhanced ZTs in the temperature range of 20 - 250⁰C FIG 9 also shows that the peak ZT value is shifted to a higher temperature (100⁰C) The peak ZT of nanocrystalline bulk samples is of about 1 4 at 100⁰C, which is significantly higher than that of the commercial Bi₂Te3-based alloys The ZT value of the commercial ingot starts to drop above 75⁰C, and falls below 0 25 at 25O⁰C In comparison, the nano crystal line bulk samples exhibit ZTs higher than 0 8 at 25O⁰C Such ZT characteristics are very much desired for power generation applications since there are no good materials presently available with high ZT in this temperature range

A detailed microstructure examination was conducted on the nanocrystalline bulk samples using a transmission electron microscope (TEM) The TEM specimens were prepared by dicing, polishing, and ion milling the bulk nanocrystalline samples Hot-pressed nanocrystalline bulk pellets were cut into blocks of 2><3^χl mm and ground down to 2^χ3^χO 002 mm using a mechanical Tripod Polisher The sample was glued to a Copper grid, and milled using Precision Ion Polishing System (Gatan Inc ) for 30 minutes with incident energy of 3 2 kV and a beam current of 15 μA at an incident angle of 3 5 degrees FIGS 10-15 present some representative TEM micrographs, which show the main structural features observed

In general, as depicted in FIGS 10 and 11 , most of the grains are nanosized Furthermore, the nanograms are highly crystalline, randomly-oriented (large angles among lattice planes) with very clean boundaries As depicted in FIG 11, the nanograms can be closely packed, consistent with density measurements that suggest full dense samples Some larger grains are also present as shown in FIG 12 High- resolution TEM microscopy, as shown in FIG 13, reveals that these grains are composed of nanodots 2 to 10 nm in size without boundaries These nanodots are typically Sb-πch with an exemplary composition close to Bi Sb Te = 8 44 48, the Sb substituting for Te Although some of the nanodots are boundaryless with the matrix as depicted in FIG 13, other observed nanodots included small angle boundaries with the matrix as depicted in FIG 14 Pure Te precipitates of sizes in the range from 5 - 30 nm were also observed, as depicted in FIG 15 The selected-area electron diffraction pattern, shown in the inset of FIG 15, confirmed the Te phase Generally speaking, nanodots could be found within each 50 nm diameter area Without necessarily being bound by any particular theory, it can be hypothesized that these nanodots could be formed during the hot-press heating and cooling processes The larger-sized grains containing nanodots, as depicted in FIG 12, could be the result of non-uniform milling of the mgot during ball milling These large grains may have grown even larger during the hot-press compaction via Oswald Ripening Given the large population of nano interfacial features in our material, such as nanograms, nanodots may not be the only reason for the strong phonon scattering

Example 2 Nanocrystalline SiGe Materials

Silicon and germanium elemental mateπals, both p and n-type, were used as starting materials and ground using a ball mill to form nanoparticles having a size of about 1 - about 200 nm These elemental materials can have a ZT lower than about 0 01 in some instances It is also understood that a SiGe alloy could have been used to form the particles, perhaps leading to further improvement in the final manufactured material Samples were hot pressed at a pressure of about 40 - about 200 MPa and at a temperature of about 900⁰C - 1300⁰C to form thermoelectric material samples

FIGS 16-19 depict graphs showing the temperature dependence of various properties of a hot pressed nanocrystalline material formed from a p-type SiGe ball milled bulk material The properties were measured using the same techniques as described earlier for FIGS 5-9 FIG 16 shows the temperature dependence of the electrical conductivity of the nanocrystalline p-type SiGe sample FIG 17 presents the temperature dependence of the Seebeck coefficient for the nanocrystalline p-type SiGe sample FIG 18 depicts the temperature dependencies of the thermal conductivity for the p-type SiGe sample FIG 19 documents the variation in the figure of merit, ZT , as a function of temperature for the nanocrystalline p-type SiGe sample

FIGS 20-23 depict graphs showing the temperature dependence of various properties of a hot pressed nanocrystalline material formed from a n-type SiGe ball milled bulk material FIG 20 shows the temperature dependence of the electrical conductivity of the nanocrystalline n-type SiGe sample FIG 17 presents the temperature dependence of the Seebeck coefficient for the nanocrystalline n-type SiGe sample FIG 18 depicts the temperature dependencies of the thermal conductivity for the n-type SiGe sample FIG 19 documents the variation in the figure of merit, ZT , as a function of temperature for the nanocrystalline n-type SiGe sample

FIGS 24-26 depict TEM micrographs of p-type SiGe materials associated with nanocrystalline materials FIG 24 presents a TEM micrograph of a ball-milled powder sample of SiGe bulk material, showing the nano-sized particulates of the milled particulates FIG 25 presents a TEM micrograph of a SiGe powder sample after hot pressing The micrograph shows numerous grains of the hot-pressed material which are densely packed and in the nano-sized range The inset of FIG 25 presents a selected- area electron diffraction pattern taken on the sample FIG 26 presents a high-resolution

TEM of the hot-pressed SiGe sample, further showing the nano size of the various grains of the sample, indicating lots of grain boundaries that are designed for phonon scattering

Example 3 Temperature Tailoring of Nanocrystalline p-type BiSbTe Materials Samples of nanocrystalline p-type BiSbTe alloyed materials were prepared to demonstrate how the figure of merit, ZT, can be tailored to various temperature conditions In particular, Bi_xSb₂-_xTe₃ type materials can be prepared with various stoichiometries depending upon the value of x selected Two particular example types of samples were prepared p-type nanocrystalline, hot pressed materials having a stoichiometry of Bio 3Sbi ₇Te3, and p-type nanocrystalline, hot pressed materials having a stoichiometry of Bio sSbi 5Tβ3 Appropriate bulk starting materials were ground up by a ball mill to form nanoparticle samples The samples are pressed at 40 - 160 MPa and 450⁰C - 600⁰C for up to about 5 minutes

FIGS 27-30 depict the temperature dependence of the electrical conductivity, Seebeck coefficient, thermal conductivity, and ZT, respectively, for nanocrystalline

Bio 3Sbi ₇Tβ3 samples, while FIGS 31-34 depict the temperature dependence of the electrical conductivity, Seebeck coefficient, thermal conductivity, and ZT, respectively, for nanocrystalline Bio sSbi sTβ3 samples The measurements were earned in accord as described in Example 1 As can be seen in FIGS 30 and 34, the peak ZT value for a Bi₀3Sbi ₇Te3 sample was measured at about 150⁰C, while the peak ZT value for a

Bi₀5Sbi 5Tβ3 sample was measured at about 75°C

Accordingly, the results show that a nanocrystalline material's peak ZT can be tailored for particular temperature range applications For example, the lower temperature peak material can be utilized in applications adapted for closer to room temperature use, such as cooling - while the higher temperature peak material can be utilized in applications for high temperature such as power generation It is understood that the various embodiments discussed herein, along with the experimental results, describe a variety of methods and matenals that are merely representative of the scope of the present invention Indeed, those skilled in the art will readily appreciate that many other modifications to the methods and materials disclosed herein can be made All such modifications represent related embodiments that are also within the scope of the present invention As well, all numbers expressing quantities of ingredients, reaction conditions, and so forth used in the specification and claims are to be understood as being modified in all instances by the term "about " Accordingly, unless indicated to the contrary, the numerical parameters set forth in this specification and attached claims are approximations that can vary depending upon the desired properties

What is claimed is

Claims

1 A method of fabricating a thermoelectric material comprising generating a plurality of nanoparticles from a thermoelectric starting material, and consolidating said nanoparticles under pressure at an elevated temperature to form a densified thermoelectric material, the thermoelectric material having a higher ZT value than the thermoelectric starting material at least at one temperature

2 The method of claim 1 , further comprising selecting said pressure and elevated temperature such that said thermoelectric material exhibits a ZT value greater than about 1

3 The method of claim 1 , wherein said thermoelectric material exhibits said ZT value at a temperature below about 2000⁰C

4 The method of claim 3, wherein said thermoelectric material exhibits said ZT value at a temperature below about 1000⁰C

5 The method of claim 4, wherein said thermoelectπc material exhibits said ZT value at a temperature below about 600⁰C

6 The method of claim 5, wherein said thermoelectπc material exhibits said ZT value at a temperature below about 200⁰C

7 The method of claim 6, wherein said thermoelectric material exhibits said ZT value at a temperature below about 2O⁰C

8 The method of claim 1 , wherein the step of generating the plurality of nanoparticles includes grinding said thermoelectric material 9 The method of claim 8, further comprising cooling said thermoelectric material while grinding it

10 The method of claim 9, wherein the step of grinding said thermoelectric material comprises utilizing ball milling

11 The method of claim 1 , wherein the step of consolidating said nanoparticles includes using at least one of a plasma pressure compaction process, a unidirectional hot press process, and an isostatic hot press process

12 The method of claim 1, further comprising selecting said pressure to be in a range from about 10 MPa to about 900 MPa

13 The method of claim 12, further comprising selecting said pressure to be in a range from about 40 MPa to about 300 MPa

14 The method of claim 13, further comprising selecting said pressure to be in a range from about 60 MPa to about 200 MPa

15 The method of claim 1 , further comprising selecting said elevated temperature to be in a range from about 200⁰C to about a melting point of said thermoelectnc starting material

16 The method of claim 1 , further comprising selecting said elevated temperature to be in a range from about 400⁰C to about 2000⁰C

17 The method of claim 1 , wherein the step of generating the plurality of nanoparticles includes using a thermoelectric starting material comprising any of a p- doped and n-doped material 18 The method of claim 1 , wherein said thermoelectric starting material exhibits a poly-crystalline structure with an average crystalline grain size greater than about 1 micron

19 The method of claim 1 , further comprising selecting said thermoelectric starting material to include any of a bismuth-based material, a lead-based material, and a silicon-based material

20 The method of claim 1 , further comprising selecting said thermoelectric material to comprise at least one of a bismuth- antimony-telluπum alloy, a bismuth-selemum-telluπum alloy, a lead-tellurium alloy, a lead-selenium alloy, and a silicon-germanium alloy

21 The method of claim 1 , further comprising selecting said thermoelectric material to be a Bi2Te3_-xSeχ alloy, wherein x is in a range of about 0 to about 0 8

22 The method of claim 1 , further comprising selecting said thermoelectric material to be a Bi_xSb₂-_xTe₃ alloy, wherein x is in a range of about 0 to about 0 8

23 The method of claim 1 , wherein the step of generating the plurality of nanoparticles includes generating the nanoparticles with an average particle size of less than about 500 nm

24 The method of claim 23, wherein the average particle size is in a range of about 1 nm to about 200 nm

25 The method of claim 1 , further comprising maintaining said nanoparticles at said elevated temperature for a time period between about 1 sec and about 10 hours 26 A thermoelectric material, comprising a material structure comprising a plurality of grains having an average grain size in a range from about 1 nm to about 1000 nm, wherein said structure is characterized by a ZT value greater than about 1 0 at a temperature below about 2000⁰C

27 The thermoelectric material of claim 26, wherein said material exhibits said ZT value at a temperature below about 1000 ⁰C

28 The thermoelectric material of claim 26, wherein said material exhibits said ZT value at a temperature below about 600 ⁰C

29 The thermoelectric material of claim 26, wherein said material exhibits said ZT value at a temperature below about 200 ⁰C

30 The thermoelectric material of claim 26, wherein said material exhibits said ZT value at a temperature below about 20 ⁰C

31 The thermoelectric material of claim 26, wherein said average grain size of said plurality of grains is in a range from about 1 nm to about 500 nm

32 The thermoelectric material of claim 26, wherein at least one of said plurality of grains includes at least one precipitation region therein

33 The thermoelectric material of claim 32, wherein said at least one precipitation region has a size m a range of about 1 nm to about 20 nm

34 The thermoelectric material of claim 26, wherein said structure is substantially free of grains larger than about 1000 nm

35 The thermoelectric material of claim 26, wherein said structure has a porosity less than about 10% 36 The thermoelectric material of claim 35, wherein said porosity is less than about 1%

37 The thermoelectric material of claim 26, wherein said ZT value of said structure is greater than about 1 2

38 The thermoelectric material of claim 37, wherein said ZT value of said structure is greater than about 1 5

39 The thermoelectric material of claim 38, wherein said ZT value of said structure is greater than about 2

40 The thermoelectric material of claim 37, wherein the material exhibits said ZT value at a temperature below about 2000⁰C

41 The thermoelectric material of claim 40, wherein the material exhibits said ZT value at a temperature below about 1000⁰C

42 The thermoelectric material of claim 41 , wherein the material exhibits said ZT value at a temperature below about 600⁰C

43 The thermoelectric material of claim 42, wherein the material exhibits said ZT value at a temperature below about 200⁰C

44 The thermoelectric material of claim 43, wherein the material exhibits said ZT value at a temperature below about 2O⁰C

45 The thermoelectric material of claim 26, wherein said material exhibits a density in a range of about 90% to about 100% of a respective theoretical density

46 The thermoelectric material of claim 26, wherein the plurality of grains comprise at least one of an n-doped material and a p-doped material 47 The thermoelectric material of claim 26, wherein the plurality of grains comprise at least one of a bismuth-based material, a lead-based material, and a silicon-based material

48 The thermoelectric material of claim 47, wherein the plurality of grains comprise at least one of a bismuth-antimony-telluπum alloy, a bismuth-selemum-tellunum alloy, a lead-tellurium alloy, a lead-selenmm alloy, and a silicon-germanium alloy

49 The thermoelectric material of claim 48, wherein the plurality of grains comprise a bismuth-antimony-telluπum alloy

50 The thermoelectric material of claim 26, wherein the plurality of grains comprise a Bi₂Te_3-xSeχ alloy, wherein x is in a range of about 0 to about 0 8

51 The thermoelectric material of claim 26, wherein said thermoelectric material is a Bi_xSb₂-_xTe₃ alloy, wherein x is in a range of about 0 to about 0 8

52 The thermoelectric material of claim 26, wherein the plurality of grains comprise at least two grains having different elemental compositions

53 A thermoelectric material, comprising a plurality of compacted crystalline inclusions disposed randomly relative to one another, wherein an average size of the inclusions lies m a range of about 1 nm to about 500 nm, said compacted inclusions providing a thermoelectric material exhibiting a ZT greater than about 1

54 The thermoelectric material of claim 53, wherein the inclusions comprise grains

55 The thermoelectric material of claim 53, wherein an average size of the inclusions lies in a range of about 1 nm to about 100 nm 56 The thermoelectric material of claim 53, wherein an average size of the inclusions lies in a range of about 1 nm to about 50 nm

57 The thermoelectric material of claim 53, wherein said material is substantially free of inclusions greater than about 500 nm

58 The thermoelectric material of claim 53, wherein said material exhibits a polycrystalline structure

59 The thermoelectric material of claim 53, wherein said material exhibits a ZT greater than about 1 2

60 The thermoelectric material of claim 59, wherein said material exhibits a ZT greater than about 1 5

61 The thermoelectric material of claim 60, wherein said material exhibits a ZT greater than about 2

62 A method of forming a thermoelectric material, comprising grinding at least one bulk elemental material so as to generate a plurality of nanop articles, and compactifying the plurality of nanoparticles under pressure and at an elevated temperature so as to generate a thermoelectric material exhibiting a ZT value greater than about 1

63 The method of claim 62, wherein the at least one bulk elemental material includes at least two different bulk elemental materials, and further wherein the step of grinding includes generating at least two types of nanoparticles

64 The method of claim 63, wherein said at least two different bulk elemental materials include bismuth and tellurium 65 The method of claim 63, wherein said at least two different bulk elemental materials include bismuth, tellurium, and antimony

66 The method of claim 63, wherein said at least two different bulk elemental materials include bismuth, tellurium, and selenium

67 The method of claim 62, further comprising adding a dopant to said plurality of nanoparticles

68 The method of claim 62, further comprising providing particles from a source material being at least one of an alloy and compound, the source material having a ZT value greater than about 0 5, wherein the step compactifying the plurality of nanoparticles comprises compactifying the plurality of nanoparticles with the particles from the source material

69 The method of claim 62, further comprising providing micron-sized particles, wherein the step compactifying the plurality of nanoparticles comprises compactifying the plurality of nanoparticles with the micron-sized particles

70 A thermoelectric material, comprising a material structure comprising a plurality of grams having average sizes in a range of about 1 nm to about 10 microns, wherein at least some of said grains include one or more precipitation regions having average sizes in a range of about 1 nm to about 100 nm, and wherein said material exhibits a ZT value greater than about 1

71 The thermoelectric material of claim 70, wherein said grains have average sizes m a range of about 1 nm to about 5 microns

72 The thermoelectric material of claim 71, wherein said grains have average sizes in a range of about 1 nm to about 2 microns 73 The thermoelectric material of claim 70, wherein said material exhibits a ZT value in a range of about 1 to about 5

74 The thermoelectric material of claim 70, wherein said material exhibits a ZT value greater than about 1 5

75 The thermoelectric material of claim 70, wherein said material exhibits a ZT value greater than about 2

76 The thermoelectric material of claim 70, wherein said material exhibits said ZT value at an operating temperature less than about 2000⁰C

77 The thermoelectric material of claim 70, wherein said precipitation regions exhibit an average size in a range of about 1 nm to about 50 nm

78 The thermoelectric material of claim 70, wherein said grains are formed from at least one of a bismuth-based alloy, a lead-based alloy, and a silicon-based alloy

79 A thermoelectric material, comprising a host material, and a plurality of particles dispersed throughout the host, said particles having sizes less than about 20 microns, wherein said thermoelectric material exhibits a carrier concentration greater than a respective carrier concentration in said host material in absence of said particles

80 The thermoelectric material of claim 79, wherein a charge earner mobility of the thermoelectric material is greater than a respective charge carrier mobility in said host material m the absence of said particles

81 The thermoelectric material of claim 79, wherein said plurality of particles are more highly doped than said host material 82 The thermoelectric material of claim 79, wherein a ZT value of said thermoelectric material is greater than about 0 8

83 The thermoelectric material of claim 79, wherein the host material comprises a plurality of grains, at least some of the grains characterized by a size less than about 1 micron

84 The thermoelectric material of claim 79, wherein the host material comprises a plurality of grains, at least some of the grains characterized by a size greater than about 1 micron

85 A thermoelectric material, comprising a host material characterized by a first energy band, and a plurality of inclusions distributed in said host material, said inclusions having sizes less than about 20 microns and being characterized by a second energy band, wherein the second energy band has a higher energy relative to the first energy band

86 The thermoelectric material of claim 85, wherein the energy bands are at least one of a conduction band and a valence band

87 The thermoelectric material of claim 85, wherein a ZT value of said thermoelectric material is greater than about 0 8

88 The thermoelectric material of claim 85, wherein the host material comprises a plurality of grains, at least some of the grains characterized by a size less than about 1 micron

89 The thermoelectric material of claim 85, wherein the host material comprises a plurality of grains, at least some of the grains characterized by a size greater than about 1 micron 90 The thermoelectric material of claim 85, wherein the plurality of inclusions comprises a doped material

91 A method of fabricating a thermoelectric material comprising generating a plurality of nanoparticles using at least one of gas phase condensation, laser ablation, chemical synthesis, and rapid cooling of sprays, and consolidating said nanoparticles under pressure at an elevated temperature to form a densified thermoelectric material, the thermoelectric material having a ZT value higher than about 0 8

92 The method of claim 91, further comprising generating a plurality of host particles by ball milling at least one starting material, wherein the step of consolidating said nanoparticles comprises consolidating said nanoparticles with said plurality of host particles