WO2009073442A3 - Process to reduce acidity of crude oil - Google Patents

Process to reduce acidity of crude oil Download PDF

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Publication number
WO2009073442A3
WO2009073442A3 PCT/US2008/084530 US2008084530W WO2009073442A3 WO 2009073442 A3 WO2009073442 A3 WO 2009073442A3 US 2008084530 W US2008084530 W US 2008084530W WO 2009073442 A3 WO2009073442 A3 WO 2009073442A3
Authority
WO
WIPO (PCT)
Prior art keywords
crude oil
organic acid
acid compounds
acidity
crude
Prior art date
Application number
PCT/US2008/084530
Other languages
French (fr)
Other versions
WO2009073442A9 (en
WO2009073442A2 (en
Inventor
Ki-Hyouk Choi
Ali Al-Shareef
Original Assignee
Saudi Arabian Oil Company
Aramco Services Company
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Saudi Arabian Oil Company, Aramco Services Company filed Critical Saudi Arabian Oil Company
Priority to JP2010536099A priority Critical patent/JP5290317B2/en
Priority to KR1020107014333A priority patent/KR101504384B1/en
Priority to BRPI0820363-6A priority patent/BRPI0820363B1/en
Priority to CN2008801257542A priority patent/CN101983227B/en
Priority to MX2010005852A priority patent/MX357637B/en
Priority to EP08858300.0A priority patent/EP2222819B1/en
Publication of WO2009073442A2 publication Critical patent/WO2009073442A2/en
Publication of WO2009073442A3 publication Critical patent/WO2009073442A3/en
Publication of WO2009073442A9 publication Critical patent/WO2009073442A9/en

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J3/00—Processes of utilising sub-atmospheric or super-atmospheric pressure to effect chemical or physical change of matter; Apparatus therefor
    • B01J3/008—Processes carried out under supercritical conditions
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G9/00—Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G31/00—Refining of hydrocarbon oils, in the absence of hydrogen, by methods not otherwise provided for
    • C10G31/08—Refining of hydrocarbon oils, in the absence of hydrogen, by methods not otherwise provided for by treating with water
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
    • C10G45/24—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing with hydrogen-generating compounds
    • C10G45/26—Steam or water
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
    • C10G47/32—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions in the presence of hydrogen-generating compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G75/00—Inhibiting corrosion or fouling in apparatus for treatment or conversion of hydrocarbon oils, in general
    • E—FIXED CONSTRUCTIONS
    • E21—EARTH DRILLING; MINING
    • E21B—EARTH DRILLING, e.g. DEEP DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
    • E21B43/00—Methods or apparatus for obtaining oil, gas, water, soluble or meltable materials or a slurry of minerals from wells
    • E21B43/16—Enhanced recovery methods for obtaining hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1033—Oil well production fluids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20—Characteristics of the feedstock or the products
    • C10G2300/201—Impurities
    • C10G2300/202—Heteroatoms content, i.e. S, N, O, P
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20—Characteristics of the feedstock or the products
    • C10G2300/201—Impurities
    • C10G2300/205—Metal content
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20—Characteristics of the feedstock or the products
    • C10G2300/201—Impurities
    • C10G2300/205—Metal content
    • C10G2300/206—Asphaltenes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/40—Characteristics of the process deviating from typical ways of processing
    • C10G2300/4081—Recycling aspects
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/80—Additives
    • C10G2300/805—Water

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Geology (AREA)
  • Mining & Mineral Resources (AREA)
  • Thermal Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Fluid Mechanics (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Treatment Of Water By Oxidation Or Reduction (AREA)
  • Mixers With Rotating Receptacles And Mixers With Vibration Mechanisms (AREA)
  • Colloid Chemistry (AREA)

Abstract

A process to reduce the acidity of acidic crude oils for preventing corrosion during processing of the crude oils, including transferring through pipe lines, tanker ships and tank vehicles. Crude oil having substantial amount of organic acid, in particular, naphthenic acid compounds is contacted with supercritical water and a catalyst for deacidification. A treated crude oil product has lower amounts of organic acid compounds than the original crude oil.
PCT/US2008/084530 2007-11-28 2008-11-24 Process to reduce acidity of crude oil WO2009073442A2 (en)

Priority Applications (6)

Application Number Priority Date Filing Date Title
JP2010536099A JP5290317B2 (en) 2007-11-28 2008-11-24 How to reduce the acidity of crude oil
KR1020107014333A KR101504384B1 (en) 2007-11-28 2008-11-24 Process to reduce acidity of crude oil
BRPI0820363-6A BRPI0820363B1 (en) 2007-11-28 2008-11-24 PROCESS FOR REDUCING CRUDE OIL ACIDITY.
CN2008801257542A CN101983227B (en) 2007-11-28 2008-11-24 Process to reduce acidity of crude oil
MX2010005852A MX357637B (en) 2007-11-28 2008-11-24 Process to reduce acidity of crude oil.
EP08858300.0A EP2222819B1 (en) 2007-11-28 2008-11-24 Process to reduce acidity of crude oil

Applications Claiming Priority (10)

Application Number Priority Date Filing Date Title
US99066207P 2007-11-28 2007-11-28
US99064107P 2007-11-28 2007-11-28
US99065807P 2007-11-28 2007-11-28
US99064807P 2007-11-28 2007-11-28
US99067007P 2007-11-28 2007-11-28
US60/990,662 2007-11-28
US60/990,648 2007-11-28
US60/990,670 2007-11-28
US60/990,658 2007-11-28
US60/990,641 2007-11-28

Publications (3)

Publication Number Publication Date
WO2009073442A2 WO2009073442A2 (en) 2009-06-11
WO2009073442A3 true WO2009073442A3 (en) 2009-11-05
WO2009073442A9 WO2009073442A9 (en) 2009-12-17

Family

ID=40674560

Family Applications (5)

Application Number Title Priority Date Filing Date
PCT/US2008/084530 WO2009073442A2 (en) 2007-11-28 2008-11-24 Process to reduce acidity of crude oil
PCT/US2008/084542 WO2009073446A2 (en) 2007-11-28 2008-11-24 Process to upgrade highly waxy crude oil by hot pressurized water
PCT/US2008/084543 WO2009073447A2 (en) 2007-11-28 2008-11-24 Process for upgrading heavy and highly waxy crude oil without supply of hydrogen
PCT/US2008/084526 WO2009073440A2 (en) 2007-11-28 2008-11-24 Process to upgrade heavy oil by hot pressurized water and ultrasonic wave generating pre-mixer
PCT/US2008/084520 WO2009082585A2 (en) 2007-11-28 2008-11-25 Process to upgrade whole crude oil by hot pressurized water and recovery fluid

Family Applications After (4)

Application Number Title Priority Date Filing Date
PCT/US2008/084542 WO2009073446A2 (en) 2007-11-28 2008-11-24 Process to upgrade highly waxy crude oil by hot pressurized water
PCT/US2008/084543 WO2009073447A2 (en) 2007-11-28 2008-11-24 Process for upgrading heavy and highly waxy crude oil without supply of hydrogen
PCT/US2008/084526 WO2009073440A2 (en) 2007-11-28 2008-11-24 Process to upgrade heavy oil by hot pressurized water and ultrasonic wave generating pre-mixer
PCT/US2008/084520 WO2009082585A2 (en) 2007-11-28 2008-11-25 Process to upgrade whole crude oil by hot pressurized water and recovery fluid

Country Status (10)

Country Link
US (7) US8025790B2 (en)
EP (5) EP2240556B1 (en)
JP (5) JP5202644B2 (en)
KR (6) KR101419977B1 (en)
CN (5) CN101970611B (en)
BR (5) BRPI0820362A2 (en)
DK (1) DK2240556T3 (en)
ES (1) ES2582392T3 (en)
MX (5) MX2010005851A (en)
WO (5) WO2009073442A2 (en)

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