A display device includes an electron-emitting device which is a laminate of an insulating layer and a pair of opposing electrodes formed on a planar substrate. A portion of the insulating layer is between the electrodes and contains fine particles of an electron emitting substance, that portion acting as an electron emitting region. Electrons are emitted from the electron emission region by applying a voltage to the electrodes, thereby stimulating a phosphorous to emit light. |
Citations|
| US2887413 | Nov 19, 1956 | May 19, 1959 | | METHOD FOR PRODUCING SAME | | US3278789 | Feb 26, 1964 | Oct 11, 1966 | | XX S SUBSTITUTE FOR MISSING XR | | US3500102 | May 15, 1967 | Mar 10, 1970 | | THIN ELECTRON TUBE WITH ELECTRON EMITTERS
AT INTERSECTIONS OF CROSSED CONDUCTORS | | US3581151 | Sep 21, 1967 | 1971 | | COLD CATHODE STRUCTURE COMPRISING | | US3611077 | Feb 26, 1969 | Oct 5, 1971 | | THIN FILM ROOM-TEMPERATURE ELECTRON
EMITTER
STATEMENT OF GOVERNMENT INTEREST | | US3631291 | Apr 30, 1969 | Dec 28, 1971 | | FIELD EMISSION CATHODE WITH METALLIC
BORIDE COATING | | US3663857 | | May 16, 1972 | | METAL CONTACT INTERFACE AND METHOD FOR | | US3735186 | Mar 10, 1971 | May 22, 1973 | | FIELD EMISSION CATHODE | | US3766423 | Dec 3, 1971 | Oct 6, 1973 | | INTEGRAL EMISSIVE ELECTRODE | | US3806372 | Jun 2, 1972 | Apr 23, 1974 | | AXITY S SILICON ELECTRON | | US3814968 | | 1974 | | SOLID STATE RADIATION SENSITIVE FIELD | | US3936329 | Feb 3, 1975 | Feb 3, 1976 | Texas Instruments Incorporated | Integral honeycomb-like support of very thin single crystal slices | | US3983443 | Mar 24, 1975 | Sep 28, 1976 | RCA Corporation | Vacuum electron device having directly-heated matrix-cathode-heater assembly | | US3990914 | Sep 3, 1974 | Nov 9, 1976 | Sensor Technology, Inc. | Tubular solar cell | | US4093562 | Feb 16, 1977 | Jun 6, 1978 | Matsushita Electric Industrial Co., Ltd. | Polymeric compositions for manufacture of secondary electron multiplier tubes and method for manufacture thereof | | US4303930 | Oct 12, 1979 | Dec 1, 1981 | U.S. Philips Corporation | Semiconductor device for generating an electron beam and method of manufacturing same | | US4325084 | Jul 21, 1980 | Apr 13, 1982 | U.S. Philips Corporation | Semiconductor device and method of manufacturing same, as well as a pick-up device and a display device having such a semiconductor device | | US4370797 | May 29, 1981 | Feb 1, 1983 | U.S. Philips Corporation | Method of semiconductor device for generating electron beams | | US4599076 | Apr 11, 1985 | Jul 8, 1986 | Sony Corporation | Method of producing discharge display device | | US4663559 | Nov 15, 1985 | May 5, 1987 | | Field emission device | | US4672268 | Jan 3, 1986 | Jun 9, 1987 | Heimann GmbH | Gas discharge lamp with sintered cathode | | US4680500 | Mar 6, 1986 | Jul 14, 1987 | The United States of America as represented by the Secretary of the Air Force | Integral grid/cathode for vacuum tubes | | US4683399 | Jun 29, 1981 | Jul 28, 1987 | Rockwell International Corporation | Silicon vacuum electron devices | | US4721524 | Sep 19, 1986 | Jan 26, 1988 | PDP Alloys, Inc. | Non-pyrophoric submicron alloy powders of Group VIII metals | | US4857799 | Jul 30, 1986 | Aug 15, 1989 | SRI International | Matrix-addressed flat panel display | | US4954744 | May 24, 1989 | Sep 4, 1990 | Canon Kabushiki Kaisha | Electron-emitting device and electron-beam generator making use | | US5063327 | Jan 29, 1990 | Nov 5, 1991 | Coloray Display Corporation | Field emission cathode based flat panel display having polyimide spacers | | US5066883 | Jul 13, 1988 | Nov 19, 1991 | Canon Kabushiki Kaisha | Electron-emitting device with electron-emitting region insulated from electrodes | | US5141460 | Aug 20, 1991 | Aug 25, 1992 | | Method of making a field emission electron source employing a diamond coating | | US5185554 | Mar 21, 1990 | Feb 9, 1993 | Canon Kabushiki Kaisha | Electron-beam generator and image display apparatus making use of it | | US5256936 | Sep 27, 1991 | Oct 26, 1993 | Futaba Denshi Kogyo K.K. | Image display device | | US5285129 | Dec 11, 1991 | Feb 8, 1994 | Canon Kabushiki Kaisha | Segmented electron emission device | | US5327050 | Apr 27, 1992 | Jul 5, 1994 | Canon Kabushiki Kaisha | Electron emitting device and process for producing the same | | US5470265 | Jan 28, 1993 | Nov 28, 1995 | Canon Kabushiki Kaisha | Multi-electron source, image-forming device using multi-electron source, and methods for preparing them | | US5559342 | Apr 6, 1995 | Sep 24, 1996 | Canon Kabushiki Kaisha | Electron emitting device having a polycrystalline silicon resistor coated with a silicide and an oxide of a work function reducing material | | US5627111 | Jun 7, 1995 | May 6, 1997 | Canon Kabushiki Kaisha | Electron emitting device and process for producing the same | | US5679043 | Jun 1, 1995 | Oct 21, 1997 | Microelectronics and Computer Technology Corporation SI Diamond Technology, Inc. | Method of making a field emitter | | US5686791 | Jun 7, 1995 | Nov 11, 1997 | Microelectronics and Computer Technology Corp. | Amorphic diamond film flat field emission cathode | | US5763997 | Jun 1, 1995 | Jun 9, 1998 | SI Diamond Technology, Inc. | Field emission display device | | US6169356 | Jun 23, 1994 | Jan 2, 2001 | Canon Kabushiki Kaisha | Electron-emitting device, electron source and image-forming apparatus |
Referenced by|
| US8080933 | Apr 24, 2009 | Dec 20, 2011 | Canon Kabushiki Kaisha | Electron-emitting device and image display apparatus |
Claims1. A method of preparing an electron-emitting device, comprising the steps of: - forming electrodes opposed to each other on a substrate;
- forming between the electrodes and in contact therewith an insulating layer in which fine particles are completely enclosed; and
- etching the insulating layer so as to partially expose the fine particles.
2. A method of preparing an electron-emitting device comprising the steps of: - forming electrodes opposed to each other on a substrate;
- forming between the electrodes and in contact therewith a semiconductor layer in which fine particles are completely enclosed; and
- etching the semiconductor layer so as to partially expose the fine particles.
3. A method of preparing an electron-emitting device, comprising the steps of: - (i) forming a semiconductor layer on a substrate;
- (ii) forming electrodes on said semiconductor layer; and
- (iii) dispersing fine particles between said electrodes.
4. The method of claim 3, wherein said semiconductor layer comprises a layer comprising an amorphous silicon semiconductor, a crystallized silicon semiconductor, or a compound semiconductor. 5. The method of claim 3, wherein said semiconductor layer has a film thickness of from 50 angstroms to 10 μm. id="INS-S-00034" date="20080212" 6. A method of fabricating an electron-emitting device which comprises a pair of electrodes and a layer disposed between the electrodes, the method comprising the steps of: - disposing the pair of electrodes in first and second regions on a substrate, respectively; and
- providing the layer between the regions, the layer comprising a metal and a semiconductor, and being in contact with the electrodes so that current flows from one of the electrodes to another one of the electrodes through the layer by a voltage applied between the electrodes,
- wherein the metal is Pd.id="INS-S-00034"
id="INS-S-00035" date="20080212" 7. The method of claim 6, wherein the semiconductor is selected from the group consisting of carbon and SnO2.id="INS-S-00035" id="INS-S-00036" date="20080212" 8. A method of fabricating an electron-emitting device, comprising the steps of: - disposing a pair of electrodes in first and second regions on a substrate, respectively; and
- providing a layer between the regions, the layer comprising carbon and a metal, and being in contact with the electrodes so that current flows from one of the electrodes to another one of the electrodes through the layer by a voltage applied between the electrodes,
- wherein the metal is Pd.id="INS-S-00036"
id="INS-S-00037" date="20080212" 9. A method of fabricating an electron-emitting device, comprising the steps of: - disposing a pair of electrodes in first and second regions on a substrate, respectively; and
- providing a layer between the regions, the layer comprising carbon and a metal, and being in contact with the electrodes so that current flows from one of the electrodes to another one of the electrodes through the layer by a voltage applied between the electrodes,
- wherein the layer comprises primarily carbon.id="INS-S-00037"
id="INS-S-00038" date="20080212" 10. A method of fabricating an electron-emitting device, comprising the steps of: - disposing a pair of electrodes in first and second regions on a substrate, respectively; and
- providing a layer between the regions, the layer being in contact with the electrodes so that current flows from one of the electrodes to another one of the electrodes through the layer by a voltage applied between the electrodes, the layer comprising an insulating material and at least some conductive particles which protrude from a surface of the layer,
- wherein the conductive particles comprise Pd.id="INS-S-00038"
id="INS-S-00039" date="20080212" 11. The method of claim 10, wherein the insulating material is SiO2.id="INS-S-00039" id="INS-S-00040" date="20080212" 12. A method of fabricating an electron-emitting device, comprising the steps of: - disposing a pair of electrodes in first and second regions on a substrate, respectively; and
- providing a layer between the regions, the layer comprising carbon and at least some conductive particles, and being in contact with the electrodes so that current flows from one of the electrodes to another one of the electrodes through the layer by a voltage applied between the electrodes,
- wherein the layer comprises primarily carbon.id="INS-S-00040"
id="INS-S-00041" date="20080212" 13. The method of claim 12, wherein the conductive particles comprise a material selected from the group consisting of a metal and a semiconductor.id="INS-S-00041" id="INS-S-00042" date="20080212" 14. The method of claim 13, wherein the metal is Pd.id="INS-S-00042" id="INS-S-00043" date="20080212" 15. The method of any one of claims 12, 13, and 14, wherein at least some of the conductive particles protrude from a surface of the layer.id="INS-S-00043" id="INS-S-00044" date="20080212" 16. The method of any one of claims 10, 12, 13 and 14, wherein the conductive particles are spatially separated from one another.id="INS-S-00044" id="INS-S-00045" date="20080212" 17. The method of any one of claims 10, 12, 13 and 14, wherein diameters of the conductive particles are in a range of several tens of angstroms to several micrometers.id="INS-S-00045" id="INS-S-00046" date="20080212" 18. A method of fabricating an electron-emitting device, comprising the steps of: - forming an insulating layer on a first portion of a surface of a substrate, so as to define a step-like structure;
- disposing a first electrode on a second portion of the surface of the substrate;
- disposing a second electrode on an upper surface of the insulating layer; and
- providing a layer along a side of the insulating layer, between the first and second electrodes, the layer comprising a metal and a semiconductor and being in contact with the first and second electrodes so that current flows from the first electrode to the second electrode through the layer by a voltage applied between the first and second electrodes.id="INS-S-00046"
id="INS-S-00047" date="20080212" 19. The method of claim 18, wherein the metal is Pd.id="INS-S-00047" id="INS-S-00048" date="20080212" 20. The method of claim 19, wherein the semiconductor is carbon.id="INS-S-00048" id="INS-S-00049" date="20080212" 21. A method of fabricating an electron-emitting device, comprising the steps of: - forming an insulating layer on a first portion of a surface of a substrate, so as to define a step-like structure;
- disposing a first electrode on a second portion of the surface of the substrate;
- disposing a second electrode on an upper surface of the insulating layer; and
- providing a layer along a side of the insulating layer, between the first and second electrodes, the layer comprising an insulating material and a conductive material, and being in contact with the first and second electrodes so that current flows from the first electrode to the second electrode through the layer by a voltage applied between the first and second electrodes.id="INS-S-00049"
id="INS-S-00050" date="20080212" 22. The method of claim 21, wherein the conductive material is selected from the group consisting of Pd and SnO2.id="INS-S-00050" id="INS-S-00051" date="20080212" 23. The method of claim 22, wherein the insulating material is SiO2.id="INS-S-00051" id="INS-S-00052" date="20080212" 24. A method of fabricating an electron-emitting device, comprising the steps of: - forming an insulating layer on a first portion of a surface of a substrate, so as to define a step-like structure;
- disposing a first electrode on a second portion of the surface of the substrate;
- disposing a second electrode on an upper surface of the insulating layer; and
- providing a layer along a side of the insulating layer, between and in contact with the first and second electrodes so that current flows from the first electrode to the second electrode through the layer by a voltage applied between the first and second electrodes, the layer including carbon and at least some conductive particles.id="INS-S-00052"
id="INS-S-00053" date="20080212" 25. The method of claim 24, wherein the layer comprises primarily carbon.id="INS-S-00053" id="INS-S-00054" date="20080212" 26. The method of claim 24 or 25, wherein the conductive particles include Pd.id="INS-S-00054" id="INS-S-00055" date="20080212" 27. A method of fabricating an electron source that includes a plurality of electron-emitting devices, each electron-emitting device comprising a pair of electrodes and a layer disposed between the electrodes, wherein each electron-emitting device is prepared by a method comprising the steps of: - disposing the pair of electrodes in first and second regions on a substrate, respectively; and
- providing the layer between the regions, the layer comprising Pd and a semiconductor, and being in contact with the electrodes so that current flows from one of the electrodes to another one of the electrodes through the layer by a voltage applied between the electrodes.id="INS-S-00055"
id="INS-S-00056" date="20080212" 28. A method of fabricating an electron source that includes a plurality of electron-emitting devices, each electron-emitting device being prepared by a method comprising the steps of: - disposing a pair of electrodes in first and second regions on a substrate, respectively; and
- providing a layer between the regions, the layer comprising carbon and Pd, and being in contact with the electrodes so that current flows from one of the electrodes to another one of the electrodes through the layer by a voltage applied between the electrodes.id="INS-S-00056"
id="INS-S-00057" date="20080212" 29. A method of fabricating an electron source that includes a plurality of electron-emitting devices, each electron-emitting device being prepared by a method comprising the steps of: - disposing a pair of electrodes in first and second regions on a substrate, respectively; and
- providing a layer between the regions, the layer including an insulating material and at least some conductive particles, wherein at least some of the conductive particles protrude from a surface of the layer, and the layer is in contact with the electrodes so that current flows from one of the electrodes to another one of the electrodes through the layer by a voltage applied between the electrodes,
- wherein the conductive particles comprise Pd.id="INS-S-00057"
id="INS-S-00058" date="20080212" 30. A method of fabricating an electron source that includes a plurality of electron-emitting devices, each electron-emitting device being prepared by a method comprising the steps of: - forming an insulating layer on a first portion of a surface of a substrate, so as to define a step-like structure;
- disposing a first electrode on a second portion of the surface of the substrate;
- disposing a second electrode on an upper surface of the insulating layer; and
- providing a layer along a side of the insulating layer, between and in contact with the first and second electrodes so that current flows from the first electrode to the second electrode through the layer by a voltage applied between the first and second electrodes, the layer comprising a metal and a semiconductor.id="INS-S-00058"
id="INS-S-00059" date="20080212" 31. A method of fabricating an electron source that includes a plurality of electron-emitting devices, each electron-emitting device being prepared by a method comprising the steps of: - forming an insulating layer on a first portion of a surface of a substrate, so as to define a step-like structure;
- disposing a first electrode on a second portion of the surface of the substrate;
- disposing a second electrode on an upper surface of the insulating layer; and
- providing a layer along a side of the insulating layer, between and in contact with the first and second electrodes so that current flows from the first electrode to the second electrode through the layer by a voltage applied between the first and second electrodes, the layer comprising an insulating material and a conductive material.id="INS-S-00059"
id="INS-S-00060" date="20080212" 32. A method of fabricating an electron source that includes a plurality of electron-emitting devices, each electron-emitting device being prepared by a method comprising the steps of: - forming an insulating layer on a first portion of a surface of a substrate, so as to define a step-like structure;
- disposing a first electrode on a second portion of the surface of the substrate;
- disposing a second electrode on an upper surface of the insulating layer; and
- providing a layer along a side of the insulating layer, between and in contact with the first and second electrodes so that current flows from the first electrode to the second electrode through the layer by a voltage applied between the first and second electrodes, the layer including carbon and at least some conductive particles.id="INS-S-00060"
id="INS-S-00061" date="20080212" 33. A method of fabricating an image forming apparatus which includes an electron source and a phosphor plate, the electron source including a plurality of electron-emitting devices that are each prepared by a method according to any one of claims 27-32.id="INS-S-00061" id="INS-S-00062" date="20080212" 34. A method of fabricating an electron-emitting device which comprises a pair of electrodes and a layer disposed between the electrodes, the method comprising the steps of: - disposing a pair of electrodes in first and second regions on a substrate, respectively; and
- providing the layer between the regions, the layer being a semiconductor layer that includes a metal, and being in contact with the electrodes so that current flows from one of the electrodes to another one of the electrodes through the layer by a voltage applied between the electrodes,
- wherein the metal is Pd.id="INS-S-00062"
id="INS-S-00063" date="20080212" 35. The method of claim 34, wherein the semiconductor layer includes a semiconductor selected from the group consisting of carbon and SnO2.id="INS-S-00063" id="INS-S-00064" date="20080212" 36. A method of fabricating an electron-emitting device, comprising the steps of: - forming an insulating layer on a first portion of a surface of a substrate, so as to define a step-like structure;
- disposing a first electrode on a second portion of the surface of the substrate;
- disposing a second electrode on an upper surface of the insulating layer; and
- providing a layer along a side of the insulating layer, between and in contact with the first and second electrodes so that current flows from the first electrode to the second electrode through the layer by a voltage applied between the first and second electrodes, the layer being a semiconductor layer which includes a metal.id="INS-S-00064"
id="INS-S-00065" date="20080212" 37. A method of fabricating an electron-emitting device, comprising the steps of: - forming an insulating layer on a first portion of a surface of a substrate, so as to define a step-like structure;
- disposing a first electrode on a second portion of the surface of the substrate;
- disposing a second electrode on an upper surface of the insulating layer; and
- providing a layer along a side of the insulating layer, between and in contact with the first and second electrodes so that current flows from the first electrode to the second electrode through the layer by a voltage applied between the first and second electrodes, the layer being an insulating layer which includes a conductive material.id="INS-S-00065"
id="INS-S-00066" date="20080212" 38. A method of fabricating an electron source that includes a plurality of electron-emitting devices, each electron-emitting device being prepared by a method comprising the steps of: - disposing a pair of electrodes in first and second regions on a substrate, respectively; and
- providing a layer between the regions, the layer comprising carbon and at least Pd particles, and being in contact with the electrodes so that current flows from one of the electrodes to another one of the electrodes through the layer by a voltage applied between the electrodes.id="INS-S-00066"
id="INS-S-00067" date="20080212" 39. A method of fabricating an electron source that includes a plurality of electron-emitting devices, each electron-emitting device comprising a pair of electrodes and a layer disposed between the electrodes, each electron-emitting device being prepared by a method comprising the steps of: - disposing a pair of electrodes in first and second regions on a substrate, respectively; and
- providing the layer between the regions, the layer being a semiconductor layer which includes Pd, and being in contact with the electrodes so that current flows from one of the electrodes to another one of the electrodes through the layer by a voltage applied between the electrodes.id="INS-S-00067"
id="INS-S-00068" date="20080212" 40. A method of fabricating an electron source that includes a plurality of electron-emitting devices, each electron-emitting device being prepared by a method comprising the steps of: - disposing a pair of electrodes in first and second regions on a substrate, respectively; and
- providing a layer between the regions, the layer being a carbon layer which includes Pd, and being in contact with the electrodes so that current flows from one of the electrodes to another one of the electrodes through the layer by a voltage applied between the electrodes.id="INS-S-00068"
id="INS-S-00069" date="20080212" 41. A method of fabricating an electron source that includes a plurality of electron-emitting devices, each electron-emitting device being prepared by a method comprising the steps of: - disposing a pair of electrodes in first and second regions on a substrate, respectively; and
- providing a layer between the regions, the layer being an insulated layer which includes at least some conductive particles, wherein at least some of the conductive particles protrude from a surface of the layer, and the layer is in contact with the electrodes so that current flows from one of the electrodes to another one of the electrodes through the layer by a voltage applied between the electrodes,
- wherein the conductive particles comprise Pd.id="INS-S-00069"
id="INS-S-00070" date="20080212" 42. A method of fabricating an electron source that includes a plurality of electron-emitting devices, each electron-emitting device being prepared by a method comprising the steps of: - forming an insulating layer on a first portion of a surface of a substrate, so as to define a step-like structure;
- disposing a first electrode on a second portion of the surface of the substrate;
- disposing a second electrode on an upper surface of the insulating layer; and
- providing a layer along a side of the insulating layer, between and in contact with the first and second electrodes so that current flows from the first electrode to the second electrode through the layer by a voltage applied between the first and second electrodes, the layer being a semiconductor layer which includes a metal.id="INS-S-00070"
id="INS-S-00071" date="20080212" 43. A method of fabricating an electron source that includes a plurality of electron-emitting devices, each electron-emitting device being prepared by a method comprising the steps of: - forming an insulating layer on a first portion of a surface of a substrate, so as to define a step-like structure;
- disposing a first electrode on a second portion of the surface of the substrate;
- disposing a second electrode on an upper surface of the insulating layer; and
- providing a layer along a side of the insulating layer, between and in contact with the first and second electrodes so that current flows from the first electrode to the second electrode through the layer by a voltage applied between the first and second electrodes, the layer being an insulating layer which includes a conductive material.id="INS-S-00071"
id="INS-S-00072" date="20080212" 44. A method of fabricating an image forming apparatus which includes an electron source and a phosphor plate, the electron source including a plurality of electron-emitting devices that are each prepared by a method according to any one of claims 38-43.id="INS-S-00072" id="INS-S-00073" date="20080212" 45. A method of fabricating an electron-emitting device, comprising the steps of: - disposing a pair of electrodes in first and second regions on a substrate, respectively; and
- providing a layer between the regions, the layer comprising carbon and a metal particle, and being in contact with the electrodes so that current flows from one of the electrodes to another one of the electrodes through the layer by a voltage applied between the electrodes,
- wherein a diameter of the metal particle is in a range of several tens of angstroms to several micrometers.id="INS-S-00073"
id="INS-S-00074" date="20080212" 46. The method of claim 45, wherein the metal particle comprises Pd.id="INS-S-00074" id="INS-S-00075" date="20080212" 47. A method of fabricating an electron-emitting device, comprising the steps of: - disposing a pair of electrodes in first and second regions on a substrate, respectively; and
- providing a layer between the regions, the layer comprising carbon and at least some conductive particles, and being in contact with the electrodes so that current flows from one of the electrodes to another one of the electrodes through the layer by a voltage applied between the electrodes,
- wherein diameters of the conductive particles are in a range of several tens of angstroms to several micrometers.id="INS-S-00075"
id="INS-S-00076" date="20080212" 48. The method of claim 47, wherein the conductive particles comprise Pd.id="INS-S-00076" |