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The present lipid-based wax compositions commonly include a polyol fatty acid ester component (made up of partial and/or completely esterified polyols). Generally, at least a portion of the polyol fatty acid ester has been subjected to a transesterification reaction. Lipid-based wax compositions having a melting point of about 48° C. to about 75° C. can be particularly advantageous for use in forming candles. The wax may contain other components such as mineral wax, plant wax, insect wax, and/or other components. The polyol fatty acid ester component can include triacylglycerols such as those derived from plant oils (soybean oil, palm oil, etc.). The polyol ester component may be characterized based on one or more of its physical characteristics, such as SFI-40, SFI-10, typical crystal structure, IV, melting curve, and/or other properties.

Referenced by

Citing PatentFiling dateIssue dateOriginal AssigneeTitle
US8021443Oct 27, 2006Sep 20, 2011Elevance Renewable Sciences, Inc.Triacylglycerol based wax composition
US8067610Jul 13, 2007Nov 29, 2011Synthesis of terminal alkenes from internal alkenes and ethylene via olefin metathesis
US8067623Jul 12, 2007Nov 29, 2011Elevance Renewable Sciences, Inc.Ring opening cross-metathesis reaction of cyclic olefins with seed oils and the like
US8070833Nov 12, 2008Dec 6, 2011Elevance Renewable Sciences, Inc.Triacyglycerol based candle wax
US8115021Jul 10, 2008Feb 14, 2012Elevance Renewable Sciences, Inc.Method of making hydrogenated metathesis products
US8157873Oct 13, 2010Apr 17, 2012Elevance Renewable Sciences, Inc.Wax and wax-based products
US8202329May 11, 2007Jun 19, 2012Elevance Renewable Sciences, Inc.Triacylglycerol-based alternative to paraffin wax

Claims

1. A candle comprising a wick and a lipid-based wax:

wherein the lipid-based wax comprises an interesterified polyol fatty acid ester component; and the lipid-based wax has a melting point of about 55° C. to 75° C.; an SFI-40 of at least about 20; and an Iodine Value of about 15 to 65.

2. The candle of claim 1 wherein the lipid-based wax has an SFI-40 of at least about 40.

3. The candle of claim 1 wherein the lipid-based wax has a slump temperature of at least about 120° F.

4. The candle of claim 1 wherein the lipid-based wax includes at least about 51 wt. % of a fully interesterified polyol fatty acid ester component.

5. The candle of claim 4 wherein the fully interesterified polyol fatty acid ester component includes a fully interesterified triacylglycerol component.

6. The candle of claim 1 wherein the lipid-based wax has a melting point of at least about 60° C.

7. The candle of claim 1 wherein the lipid-based wax further comprises a polyol fatty acid partial ester.

8. The candle of claim 1 wherein the lipid-based wax includes a fatty acid monoglyceride ester, a fatty acid diglyceride ester or a mixture thereof.

9. The candle of claim 1 wherein the lipid-based wax further comprises a second component selected from the group consisting of petroleum waxes, insect waxes, free fatty acids and mixtures thereof.

10. A candle comprising a wick and a lipid-based wax:

wherein the lipid-based wax has a melting point of about 48° C. to about 75° C.; and includes at least about 51 wt. % of a polyol fatty acid ester component formed by a process which comprises interesterifying a polyol fatty acid ester precursor mixture.

11. A method of forming a candle comprising:

compressing a plurality of particles of a lipid-based wax to form a candle;

wherein the lipid-based wax has a melting point of about 55° C. to 70° C.; and an SFI-40 of at least about 40; and lipid-based wax comprises at least about 51 wt. % of a fully interesterified polyol fatty acid ester component.

12. The method of claim 11 further comprising inserting a wick into the candle.

13. The method of claim 11 wherein the lipid-based wax comprises a triacylglycerol component having a fatty acid composition which includes no more than about 15 wt. % palmitic acid.

14. The method of claim 11 wherein fully interesterified polyol fatty acid ester component includes a fully interesterified triacylglycerol component; the lipid-based wax comprises at least about 51 wt. % of the fully interesterified triacylglycerol component.

15. The method of claim 14 wherein the lipid-based wax further comprises a polyol fatty acid partial ester.

16. The method of claim 11 wherein the lipid-based wax has a melting point of at least about 140° F. (60° C.).

17. A lipid-based wax comprising at least about 51 wt. % of a fully interesterified polyol fatty acid ester component.

18. A candle comprising a wick and a lipid-based wax:

wherein the lipid-based wax has a melting point of about 48° C. to about 75° C. and includes at least about 51 wt. % of a triacylglycerol component having a fatty acid composition which includes X wt. % stearic acid; and the triacylglycerol component has a SSS-TAG content which is given by (X3/104)±3 wt. %.

19. A method of producing a candle comprising:

spraying a molten lipid-based wax through a nozzle to form finely dispersed liquid wax particles;

solidifying the finely dispersed liquid wax to form prilled wax granules; and

compression molding the prilled wax granules to form a candle;

wherein the lipid-based wax has a melting point of about 48° C. to about 75° C.; and
includes at least about 51 wt. % of a polyol fatty acid ester component formed by a process which comprises interesterifying a polyol fatty acid ester precursor mixture.