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Process for creping tissue paper

 Kenneth Douglas Vinson et al
An adhesive for applying to a creping surface in the process for dry creping tissue paper is disclosed. The adhesive comprises cationic starch and optionally a polyvinyl alcohol and a water-soluble, thermosetting, cationic polyamide-epihalohydrin resin. The adhesive provides high adhesion and...
Inventors: Kenneth Douglas Vinson, Howard Thomas Deason, Bart Steven Hersko
Assignee: The Procter & Gamble Company

U.S. Classification
162/111; 162/112; 162/113; 264/283

International Classification
B31F 112

View patent at USPTO

Citations

Patent NumberTitleIssue date
962505(unknown)Jun 1910
3821068(unknown)May 1974
3926716(unknown)Dec 1975
3994771Process for forming a layered paper web having improved bulk, tactile impression and absorbency and paper thereofNov 30, 1976
4064213Creping process using two-position adhesive applicationDec 20, 1977
4127637Method of manufacturing a dry-formed, embossed adhesively bonded, nonwoven fibrous sheetNov 28, 1978
4158594Bonded, differentially creped, fibrous webs and method and apparatus for making sameJun 19, 1979
4166001Multiple layer formation process for creped tissueAug 28, 1979
4191609Soft absorbent imprinted paper sheet and method of manufacture thereofMar 4, 1980
4300981Layered paper having a soft and smooth velutinous surface, and method of making such paperNov 17, 1981
4308092Creping paper using cationic water soluble additionDec 29, 1981
4406737Creping paper using cationic water soluble addition polymerSep 27, 1983
4501640Creping adhesives containing polyvinyl alcohol and cationic polyamide resinsFeb 26, 1985
4528316Creping adhesives containing polyvinyl alcohol and cationic polyamide resinsJul 9, 1985
4529480Tissue paperJul 16, 1985
4637859Tissue paperJan 20, 1987
4788243Creping adhesives containing polyvinyl alcohol and thermoplastic polyamide resins derived from poly(oxyethylene) diamineNov 29, 1988
4940513Process for preparing soft tissue paper treated with noncationic surfactantJul 10, 1990
4994146Creping adhesive utilizing polymer-polymer complex formationFeb 19, 1991
5143776Tissue laminates having adhesively joined tissue laminaeSep 1, 1992
5326434Creping adhesive formulationJul 5, 1994
5382323Cross-linked poly(aminoamides) as yankee dryer adhesivesJan 17, 1995
5399241Soft strong towel and tissue paperMar 21, 1995
5468796Creeping chemical composition and method of useNov 21, 1995
5490903Creping chemical composition and method of useFeb 13, 1996

Claims

What is claimed is:

1. A process for creping tissue paper comprising:

a) applying to a rotating creping cylinder an aqueous dispersion comprising from about 90% to about 99.9% water and from about 10% to about 0.1% solids, wherein from about 50% to about 90% of said solids is a cationic starch having between about 0.001 and about 0.2 cationic substituents per anhydroglucose unit of starch, and from about 10% to about 50% of said solids is a water soluble, thermosetting, cationic polyamide-epihalohydrin resin;
b) pressing a tissue paper web against the creping cylinder to effect adhesion of the web to the surface of the cylinder; and
c) dislodging the web from the creping cylinder by contact with a doctor blade.

2. A process for creping tissue paper comprising:

a) applying to a rotating creping cylinder an aqueous dispersion comprising from about 90% to about 99.9% water and from about 10% to about 0.1% solids, wherein from about 10% to about 70% of said solids is a cationic starch having between about 0.001 and about 0.2 cationic substituents per anhydroglucose unit of starch, from about 5% to about 40% of said solids is a water soluble, thermosetting, cationic polyamide-epihalohydrin resin, and from about 20% to about 85% of said solids is a polyvinyl alcohol.
b) pressing a tissue paper web against the creping cylinder to effect adhesion of the web to the surface of the cylinder; and
c) dislodging the web from the creping cylinder by contact with a doctor blade.

3. The process of claim 2 wherein said polyamide-epihalohydrin resin comprises the reaction product of an epihalohydrin and a polyamide containing secondary amine groups or tertiary amine groups.

4. The process of claim 3 wherein said polyamide-epihalohydrin resin comprises the reaction product of an epihalohydrin and a polyamide containing secondary amine groups, the mole ratio of epihalohydrin to secondary amine groups of said polyamide being from about 0.5 to 1 to about 2 to 1.

5. The process of claim 4 wherein said polyamide containing secondary amine groups is obtained by reacting a C.sub.3 -C.sub.10 saturated aliphatic dibasic carboxylic acid and a polyalkylene polyamine in a mole ratio of polyalkylene to dibasic carboxylic acid of from about 0.8 to 1 to about 1.5 to 1.

6. The process of claim 5 wherein the water soluble, thermosetting, cationic polyamide-epihalohydrin resin comprises the reaction product of an epihalohydrin and a polyamide precursor containing the recurring group

--NH(C.sub.n H.sub.2n HN).sub.x --CORCO--

wherein n and x are each 2 or more and R is a saturated aliphatic chain having 3-10 carbon atoms.

7. The process of claim 5 wherein said epihalohydrin is epichlorohydrin.

8. The process of claim 7 wherein said aliphatic dibasic carboxylic acid is adipic acid.

9. The process of claim 8 wherein said polyalkylene polyamine is diethylenetriamine.

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