Abstract
Crocobelonite, CaFe23+(PO4)2O, is a new natural oxyphosphate discovered in the pyrometamorphic complexes of the Hatrurim Formation in Israel and Jordan. Crocobelonite-bearing assemblages contain a series of anhydrous Fe-Ni phosphates, hematite, diopside, anorthite, and phosphides—barringerite Fe2P, transjordanite Ni2P, murashkoite FeP, halamishite Ni5P4, and negevite NiP2. Crocobelonite forms submillimeter-sized aggregates of prismatic to acicular crystals of saffron-red to pinkish-red color. There are two polymorphic modifications of the mineral whose structures are interrelated by the unit-cell twinning. Crocobelonite-2O is orthorhombic, Pnma, a = 14.2757(1), b = 6.3832(1), c = 7.3169(1) Å, V 666.76(1) Å3, Z = 4. This polymorphic modification is isotypic with synthetic oxy-phosphates
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