EP1924331B1 - Balle de tennis de table sans celluloid - Google Patents
Balle de tennis de table sans celluloid Download PDFInfo
- Publication number
- EP1924331B1 EP1924331B1 EP06805719A EP06805719A EP1924331B1 EP 1924331 B1 EP1924331 B1 EP 1924331B1 EP 06805719 A EP06805719 A EP 06805719A EP 06805719 A EP06805719 A EP 06805719A EP 1924331 B1 EP1924331 B1 EP 1924331B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- tennis ball
- shell
- ball according
- principal component
- celluloid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Revoked
Links
Classifications
-
- A—HUMAN NECESSITIES
- A63—SPORTS; GAMES; AMUSEMENTS
- A63B—APPARATUS FOR PHYSICAL TRAINING, GYMNASTICS, SWIMMING, CLIMBING, OR FENCING; BALL GAMES; TRAINING EQUIPMENT
- A63B39/00—Hollow non-inflatable balls, i.e. having no valves
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
- Y10T428/1352—Polymer or resin containing [i.e., natural or synthetic]
Definitions
- the invention is directed to a celluloid-free table tennis ball, preferably with a diameter of 38.5 to 48 mm, a weight between 2.0 and 4.5 grams and a shell thickness (approximately) between 0.20 mm and 1.30 mm, wherein the shell is made of plastic, whose main component is an organic, uncrosslinked polymer, and on the other hand to a method for producing such a table tennis ball.
- Diameter and weight are properties largely defined by the International Rules, the rolling behavior is a specified and desired quality, while the mechanical properties defined according to FIGS. 4 to 8 describe the properties of the previously used celluloid ball.
- the organic polymer has no nitrogen atoms outside the main chain. Such nitration changes the material properties rather negatively.
- thermoplastic with a homogeneous structure without fillers and / or reinforcing materials, which can be processed better than inhomogeneous substances.
- the main constituent of the substance according to the invention should have the lowest possible water absorption, in particular a water absorption under normal conditions according to DIN EN ISO 62 of less than 1.0%. This excludes uncontrolled sources.
- the ball pressure hardness according to DIN EN ISO 2039-1 of the main constituent of the substance according to the invention should be 120 MPa or above, so that it can be used to produce a table tennis ball corresponding to the usual requirements.
- the invention recommends to use such substances whose main component has a density according to DIN EN ISO 1183 of 1.22 g / cm 3 or more.
- the weight of a table tennis ball can be optimally adjusted in the given shell cross-section.
- the main constituent of the substance of the invention should have a continuous use temperature of 80 ° C or more (engineering thermoplastic, high temperature thermoplastic) to be sufficiently resistant to thermal stress. Even better suited Substances whose main component has a continuous service temperature of 150 ° C or more (high temperature thermoplastic).
- the main component is semicrystalline, can be adjusted by the partial parallel alignment of the polymer chains high stability, which is important especially in the relatively thin shell.
- the main constituent of the shell is one of the following substances: polyoxymethylene (POM), polybutylene terephthalate (PBT), polyethylene terephthalate (PET), polysulfone (PSU), polyetherimide (PEI), polyetheretherketone (PEEK), polyethylene naphthalate (PEN), polybutylene naphthalate (PBN), polytrimethylene terephthalate (PTT), or a copolymer of one or more of these substances.
- POM polyoxymethylene
- PBT polybutylene terephthalate
- PET polyethylene terephthalate
- PSU polysulfone
- PEI polyetherimide
- PEEK polyetheretherketone
- PEN polyethylene naphthalate
- PBN polybutylene naphthalate
- PTT polytrimethylene terephthalate
- copolymer of one or more of these substances are characterized by a good processability with various molding processes such as deep drawing or injection molding and can be
- the molding compound is a mixture or blend of one or more of the plastics mentioned, substances having a particularly advantageous property profile can be created.
- nanofillers preferably sheet silicates, nanotubes or spherical nanoparticles.
- the shell has a textured inner surface, and / or a structured outer surface.
- the shell a specific variation of the wall thickness in order to compensate for any inhomogeneities or anisotropies caused by the production process (for example, welding of two shell halves).
- Optimum properties of the table tennis ball when it reaches a jump height of 220 mm to 280 mm when hitting 305 mm height on a standard stone slab and on its surface at a pressure of 50 N on a surface of 20 mm diameter at the Ballober Structure one reversible deformation between 0.65 mm and 0.90 mm, with a standard deviation across different points of the surface of less than 0.20 mm.
- a method for producing a table tennis ball according to the invention is characterized in that a plurality of shell parts are produced in a first step, which are joined together in a subsequent step.
- the shells or shell parts can be produced by forming a blank, for example a flat body, for example by deep drawing. This process may possibly be carried out near or below the softening temperature, so that the material behavior is very easy to control.
- the shells or shell parts by shaping from a liquid or pasty raw material by means of a primary molding process, for example by injection molding. In such a case can be exactly affect the cross section and thus ensure a consistent shell thickness.
- the invention recommends that the shell parts are joined together by gluing, welding and / or clipping. While the former methods lead to a very stable table tennis ball, can be ensured with the latter method, a precisely defined cross-section of the ball at the joint. A sufficiently strong undercut ensures that the two shell halves can not be separated without destroying the ball.
- the production costs can be further reduced by having the shell parts directly in the tool, preferably by means of assembly injection molding or hollow body injection molding.
- thermoplastic material is particularly good moldable.
- a ping-pong ball was made from two injection-molded PEI shells that had been given a plasma surface treatment with a polyvinyl butyral hot melt adhesive.
- a ping-pong ball was made from two injection-molded PET half-shells, which have been given a plasma surface treatment with an epoxy-based reactive adhesive.
- a ping-pong ball was made from two deep-drawn POM half shells, which after surface treatment are equipped with an epoxy-based reaction adhesive.
Claims (23)
- Balle de tennis de table sans celluloïd, de préférence d'un diamètre de 38,5 à 45 mm, d'un poids compris entre 2,0 et 4,5 grammes et d'une épaisseur de coque entre 0,20 mm et 1,30 mm, la coque étant en une matière plastique, dont le composant principal est un polymère organique non réticulé qui présente, outre des atomes de carbone, également des hétéroatomes dans la chaîne principale, caractérisée en ce que le composant principala) est un thermoplastique et, en outre,b) qu'il présente une masse volumique selon ISO 1183 supérieure à 1,22 g/cm3c) ainsi qu'une absorption d'eau dans des conditions climatiques normales selon ISO 62 inférieure à 1,0%.
- Balle de tennis de table sans celluloïd selon la revendication 1, caractérisée en ce que le composant principal est un thermoplastique qui est partiellement cristallin et/ou qui présente une température d'utilisation constante de 150 °C ou plus.
- Balle de tennis de table selon l'une des revendications 1 ou 2, caractérisée en ce que le polymère organique ne présente pas de groupe nitrate.
- Balle de tennis de table selon l'une des revendications précédentes, caractérisée en ce que le polymère organique ne présente pas d'atomes d'azote hors de la chaîne principale.
- Balle de tennis de table selon l'une des revendications précédentes, caractérisée en ce que le thermoplastique présente une structure homogène sans charge et/ou sans renfort.
- Balle de tennis de table selon l'une des revendications précédentes, caractérisée par un composant principal qui présente une dureté à la bille selon ISO 2039-1 de 120 MPa ou plus.
- Balle de tennis de table selon l'une des revendications précédentes caractérisée en ce que le composant principal de la coque est l'une des substances suivantes : polyoxyméthylène (POM), polybutylène téréphtalate; (PBT), polyéthylène téréphtalate (PET), polysulfone (PSU), polyétherimide (PEI), polyétheréthercétone (PEEK), polynaphtalate d'éthylène (PEN), polynaphtalate de butylène (PBN), polytriméthylène téréphtalate (PTT), ou un copolymère de deux ou de plusieurs de ces substances.
- Balle de tennis de table selon la revendication 7, caractérisée en ce que la matière à mouler est une composition ou un mélange d'une ou de plusieurs des matières plastiques précitées.
- Balle de tennis de table selon l'une des revendications précédentes caractérisée en ce que la matière à mouler est modifiée avec des nanocharges, de préférence des phyllosilicates ou des nanoparticules sphériques.
- Balle de tennis de table selon l'une des revendications précédentes, caractérisée en ce que la coque a une surface intérieure structurée.
- Balle de tennis de table selon l'une des revendications précédentes, caractérisée en ce que la coque a une surface extérieure structurée.
- Balle de tennis de table selon l'une des revendications précédentes, caractérisée en ce que la coque présente une variation ciblée de l'épaisseur de paroi.
- Balle de tennis de table selon l'une des revendications précédentes, caractérisée en ce qu'elle consiste en une coque d'une seule pièce, de préférence réalisée par moulage par rotation.
- Balle de tennis de table selon l'une des revendications 1 à 12, caractérisé en ce qu'elle est assemblée en une coque de plusieurs pièces, de préférence de deux pièces.
- Balle de tennis de table selon l'une des revendications précédentes, caractérisée en ce que, au moment de l'impact d'une hauteur de 305 mm sur une plaque en pierre standard, elle atteint une hauteur de rebond entre 220 mm et 280 mm et présente sur sa surface, à une pression de 50 N sur une surface de 20 mm de diamètre sur la surface de la balle, une déformation réversible entre 0,65 mm et 0,90 mm, à un écart type via différents points de la surface de moins de 0,20 mm.
- Procédé de fabrication d'une balle de tennis de table selon l'une ou plusieurs des revendications précédentes, caractérisé en ce que dans une première étape plusieurs parties de coque sont réalisées en une matière plastique dont le composant principal est un polymère organique non réticulé, le polymère organique présentant dans la chaîne principale non seulement des atomes de carbone mais aussi des hétéroatomes, le composant principal étant un thermoplastique et présentant une masse volumique selon ISO 1183 supérieure à 1,22 g/cm3 ainsi qu'une absorption d'eau dans des conditions climatiques normales selon ISO 62 inférieure à 1,0%, qui sont assemblées dans une étape ultérieure.
- Procédé selon la revendication 16, caractérisé en ce que les coques sont réalisées par déformation d'une ébauche, par exemple d'un corps plat, par exemple par emboutissage.
- Procédé selon la revendication 16, caractérisé en ce que les coques sont réalisées par moulage à partir d'une matière brute liquide ou pâteuse, par exemple par moulage par injection.
- Procédé selon l'une des revendications 16 à 18, caractérisé en ce que les parties de la coque sont assemblées par collage, soudage et/ou clipsage.
- Procédé selon l'une des revendications 16 à 19, caractérisé en ce que les parties de la coque sont assemblées par soudage par rotation, soudage par ultrasons, soudage par induction ou soudage au laser.
- Procédé selon l'une des revendications 16 à 20, caractérisé en ce que les coques sont disposées directement dans le moule, de préférence par montage par injection dans le moule ou par moulage par injection de corps creux.
- Procédé selon l'une des revendications 16 à 21, caractérisé par des mesures de moulage pour la variation ciblée de l'épaisseur de paroi des coques, de préférence durant un processus de moulage par injection.
- Procédé selon l'une des revendications 16 à 22, caractérisé en ce que, lors de la fabrication de la balle, une ou plusieurs étapes sont exécutées à une température de 110 °C ou plus, de préférence supérieure à 140 °C.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102005044178A DE102005044178A1 (de) | 2005-09-15 | 2005-09-15 | Tischtennisball |
PCT/EP2006/008963 WO2007031315A1 (fr) | 2005-09-15 | 2006-09-14 | Balle de tennis de table sans celluloid |
Publications (2)
Publication Number | Publication Date |
---|---|
EP1924331A1 EP1924331A1 (fr) | 2008-05-28 |
EP1924331B1 true EP1924331B1 (fr) | 2012-04-25 |
Family
ID=37547080
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP06805719A Revoked EP1924331B1 (fr) | 2005-09-15 | 2006-09-14 | Balle de tennis de table sans celluloid |
Country Status (8)
Country | Link |
---|---|
US (1) | US8105183B2 (fr) |
EP (1) | EP1924331B1 (fr) |
JP (1) | JP5078894B2 (fr) |
KR (1) | KR101331035B1 (fr) |
CN (1) | CN101272830B (fr) |
AT (1) | ATE554832T1 (fr) |
DE (1) | DE102005044178A1 (fr) |
WO (1) | WO2007031315A1 (fr) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102015003699A1 (de) | 2014-03-21 | 2015-09-24 | Weener Plastik Gmbh | Zelluloidfreier im Wesentlichen kugelförmiger Hohlkörper und dessen Fertigung |
Families Citing this family (20)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102005044178A1 (de) * | 2005-09-15 | 2007-03-29 | Thomas Dr. Wollheim | Tischtennisball |
CN101850170B (zh) | 2009-03-31 | 2014-04-16 | 张辉伦 | 一种整体无缝结构的乒乓球 |
CN102838782B (zh) * | 2012-09-06 | 2015-04-22 | 无锡市科恩塑胶有限公司 | 一种替代赛璐珞的乒乓球用材料及制造方法 |
CN102896788A (zh) * | 2012-10-17 | 2013-01-30 | 丁杭峰 | 一种注塑成型的无赛璐珞乒乓球 |
CN103157255A (zh) * | 2012-12-26 | 2013-06-19 | 缪国平 | 运动用球 |
CN105142741B (zh) * | 2013-04-26 | 2016-08-17 | 日本卓球株式会社 | 乒乓球及乒乓球用热塑性树脂组合物 |
WO2015021138A1 (fr) | 2013-08-06 | 2015-02-12 | Celanese International Corporation | Balles de ping-pong en acétate de cellulose et procédés de fabrication associés |
CN103394180B (zh) * | 2013-08-12 | 2016-02-17 | 信阳农林学院 | 抗形变乒乓球制作方法 |
KR102022576B1 (ko) * | 2014-03-21 | 2019-09-18 | 비너 플라스틱 게엠베하 | 셀룰로이드-무함유의 실질적으로 구형인 중공체 및 이의 제조 방법 |
FR3039076B1 (fr) * | 2015-07-22 | 2017-09-01 | Decathlon Sa | Balle de tennis de table et son procede de fabrication |
CN105080081A (zh) * | 2015-07-28 | 2015-11-25 | 上海红双喜股份有限公司 | 一种乒乓球二个半球连接结构和制造方法 |
CN105037990A (zh) * | 2015-08-27 | 2015-11-11 | 浙江曙光体育用品有限公司 | 一种乒乓球用纳米无机填料改性聚苯乙烯及其制备方法 |
CN105111671B (zh) * | 2015-09-28 | 2018-01-09 | 无锡市科恩塑胶有限公司 | 一种乒乓球及其制备方法 |
CN105694339B (zh) * | 2016-03-14 | 2019-05-10 | 赵帅 | 一种制备乒乓球的方法、制备材料及乒乓球 |
KR102402639B1 (ko) | 2017-11-24 | 2022-05-26 | 삼성전자주식회사 | 전자 장치 및 그의 통신 방법 |
CN108042990B (zh) * | 2018-02-09 | 2022-12-13 | 华北理工大学 | 一种训练用乒乓球及其成型装置 |
CN109796760A (zh) * | 2018-12-11 | 2019-05-24 | 盐城市艾斯特体育器材有限公司 | 一种环保的乒乓球 |
CN109568905A (zh) * | 2018-12-11 | 2019-04-05 | 盐城市艾斯特体育器材有限公司 | 一种长寿命的乒乓球 |
CN109810449B (zh) * | 2018-12-27 | 2021-08-17 | 聚石化学(苏州)有限公司 | 一种乒乓球用asa复合材料及其制备方法和应用 |
US11786792B2 (en) * | 2022-02-26 | 2023-10-17 | Play Everywhere Sports, Llc | Table tennis apparatus and methods |
Family Cites Families (15)
Publication number | Priority date | Publication date | Assignee | Title |
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US2633894A (en) * | 1948-04-21 | 1953-04-07 | Raytheon Mfg Co | Plastic welding |
BE756475Q (fr) * | 1964-10-14 | 1971-03-01 | Dunlop Co Ltd | Balles de tennis de table |
GB1131322A (en) * | 1964-10-14 | 1968-10-23 | Dunlop Co Ltd | Apparatus for forming hollow plastic articles |
US3617589A (en) | 1964-10-14 | 1971-11-02 | James Jones Hinton | Method for manufacturing table-tennis balls |
GB1222901A (en) * | 1968-07-04 | 1971-02-17 | Dunlop Co Ltd | Hollow plastic articles |
JPS5017897A (fr) * | 1973-05-30 | 1975-02-25 | ||
DE2611919A1 (de) * | 1975-03-27 | 1976-10-14 | Uop Inc | Verfahren zur gegenstromkontaktbehandlung von gasen und fluessigkeiten und kontaktkoerper hierfuer |
JPS5481936A (en) * | 1977-12-10 | 1979-06-29 | Dainippon Printing Co Ltd | Table tennis ball |
DE3438227A1 (de) * | 1984-10-18 | 1986-04-30 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V., 8000 München | Verfahren zur herstellung von tischtennisbaellen |
CN1057790A (zh) * | 1990-06-26 | 1992-01-15 | 广州市文教体育用品工业公司 | 改性聚苯乙烯乒乓球 |
JP2002035189A (ja) | 2000-07-26 | 2002-02-05 | Haaguru:Kk | 卓球用のボール及び卓球セット |
CN1410250A (zh) * | 2001-09-25 | 2003-04-16 | 骆益群 | 一种新型乒乓球和其制备方法 |
US20100210745A1 (en) * | 2002-09-09 | 2010-08-19 | Reactive Surfaces, Ltd. | Molecular Healing of Polymeric Materials, Coatings, Plastics, Elastomers, Composites, Laminates, Adhesives, and Sealants by Active Enzymes |
DE10315154A1 (de) * | 2003-04-03 | 2004-10-14 | Kuhn, Joachim, Dr. | Tischtennisball mit Struktur- und Formelementen in der Schale |
DE102005044178A1 (de) * | 2005-09-15 | 2007-03-29 | Thomas Dr. Wollheim | Tischtennisball |
-
2005
- 2005-09-15 DE DE102005044178A patent/DE102005044178A1/de not_active Withdrawn
-
2006
- 2006-09-14 US US11/991,584 patent/US8105183B2/en not_active Expired - Fee Related
- 2006-09-14 AT AT06805719T patent/ATE554832T1/de active
- 2006-09-14 EP EP06805719A patent/EP1924331B1/fr not_active Revoked
- 2006-09-14 CN CN200680034220XA patent/CN101272830B/zh not_active Expired - Fee Related
- 2006-09-14 JP JP2008530414A patent/JP5078894B2/ja not_active Expired - Fee Related
- 2006-09-14 WO PCT/EP2006/008963 patent/WO2007031315A1/fr active Application Filing
- 2006-09-14 KR KR1020087005533A patent/KR101331035B1/ko not_active IP Right Cessation
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102015003699A1 (de) | 2014-03-21 | 2015-09-24 | Weener Plastik Gmbh | Zelluloidfreier im Wesentlichen kugelförmiger Hohlkörper und dessen Fertigung |
Also Published As
Publication number | Publication date |
---|---|
KR101331035B1 (ko) | 2013-11-20 |
JP2009507589A (ja) | 2009-02-26 |
EP1924331A1 (fr) | 2008-05-28 |
ATE554832T1 (de) | 2012-05-15 |
CN101272830A (zh) | 2008-09-24 |
DE102005044178A1 (de) | 2007-03-29 |
CN101272830B (zh) | 2013-03-27 |
US20100009791A1 (en) | 2010-01-14 |
JP5078894B2 (ja) | 2012-11-21 |
WO2007031315A1 (fr) | 2007-03-22 |
KR20080044853A (ko) | 2008-05-21 |
US8105183B2 (en) | 2012-01-31 |
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