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    Publication numberWO1989008021 A1
    Publication typeApplication
    Application numberPCT/US1989/000774
    Publication dateSep 8, 1989
    Filing dateMar 1, 1989
    Priority dateMar 2, 1988
    Publication numberPCT/1989/774, PCT/US/1989/000774, PCT/US/1989/00774, PCT/US/89/000774, PCT/US/89/00774, PCT/US1989/000774, PCT/US1989/00774, PCT/US1989000774, PCT/US198900774, PCT/US89/000774, PCT/US89/00774, PCT/US89000774, PCT/US8900774, WO 1989/008021 A1, WO 1989008021 A1, WO 1989008021A1, WO 8908021 A1, WO 8908021A1, WO-A1-1989008021, WO-A1-8908021, WO1989/008021A1, WO1989008021 A1, WO1989008021A1, WO8908021 A1, WO8908021A1
    InventorsJohn J. Krajewski, Edward J. Murphy, Robert E. Ansel
    ApplicantDesoto, Inc.
    Export CitationBiBTeX, EndNote, RefMan
    External Links: Patentscope, Espacenet
    Stereolithographie utilisant une composition assurant une distortion reduite
    WO 1989008021 A1
    Abstract
    Un procédé de stéréolithographie permettant de former un objet tridimensionnel à parois minces consiste à exposer de manière répétée la surface d'un réservoir de matière liquide non saturée par de l'éthylène durcissable aux rayons ultraviolets, à une lumière actinique se situant dans ou près de la plage des rayons ultraviolets, afin de solidifier le liquide proche de la surface pour former une pluralité de couches superposées de matériau polymère tridimensionnel de forme complexe pouvant être gonflé par du solvant et légèrement réticulé, à retirer l'élément du réservoir, tout en drainant le liquide polymérisable excédentaire, et à durcir complétement ledit élément afin de le rigidifier et de le renforcer. La composition se trouvant dans le réservoir se compose d'un photoexcitant et d'environ 20 à 80 % de polyacrylate résineux ou de polymétacrylate dissous dans environ 80 à 20 % de polyacrylate ou de polyméthacrylate liquide, les pourcentages étant basés sur le poids de matière non saturée présente, l'une des matières précitées étant le polyacrylate et le reste un polyméthacrylate. On préconise de remplacer le polyacrylate ou polyméthacrylate liquide par 10 à 45 % de polyacrylate ou polyméthacrylate liquide et 10 à 45 % de monomère de N-vinyle liquide combinés.
    Description  available in English
    Patent Citations
    Cited PatentFiling datePublication dateApplicantTitle
    US4011084 *Sep 10, 1975Mar 8, 1977Basf AktiengesellschaftFluid photo-crosslinkable compositions for the manufacture of relief printing plates
    US4195103 *Aug 30, 1978Mar 25, 1980Wallace Business Forms, Inc.Method of desensitizing carbonless paper
    US4477327 *Apr 19, 1982Oct 16, 1984Ford Motor CompanyDiscoloration resistant, flexible, radiation curable coating compositions
    US4575330 *Aug 8, 1984Mar 11, 1986Uvp, Inc.Apparatus for production of three-dimensional objects by stereolithography
    US4690502 *Jul 8, 1985Sep 1, 1987Desoto, Inc.Ultraviolet curable optical glass fiber coatings from acrylate terminated, end-branched polyurethane polyurea oligomers
    Referenced by
    Citing PatentFiling datePublication dateApplicantTitle
    WO1992002572A1 *Jul 24, 1991Feb 20, 1992Dsm N.V.Compositions contenant des melanges reactifs et associatifs
    US5437964 *Feb 24, 1994Aug 1, 1995Alliedsignal Inc.Stereolithography using vinyl ether-epoxide polymers
    US5498782 *Sep 8, 1993Mar 12, 1996Union Carbide Chemicals & Plastics Technology CorporationDistortion control additives for ultraviolet-curable compositions
    US5506087 *Apr 20, 1994Apr 9, 1996Alliedsignal Inc.Stereolithography using vinyl ether based polymers
    US5510226 *Apr 20, 1994Apr 23, 1996Alliedsignal Inc.Stereolithography using vinyl ether-epoxide polymers
    US5674921 *Feb 1, 1995Oct 7, 1997Ethicon, Inc.Radiation-curable, urethane-acrylate prepolymers and crosslinked polymers
    US5705316 *Nov 9, 1995Jan 6, 1998Ciba Specialty Chemicals CorporationVinyl ether compounds having additional functional groups other than vinyl ether groups and the use thereof in the formulation of curable compositions
    US5783615 *Apr 16, 1997Jul 21, 1998Ciba Specialty Chemicals CorporationVinyl ether compounds having additional functional groups other than vinyl ether groups and the use thereof in the formulation of curable compositions
    US5783712 *Aug 13, 1996Jul 21, 1998Ciba Specialty Chemicals CorporationVinyl ether compounds having additional functional groups other than vinyl ether groups and the use thereof in the formulation of curable compositions
    US5801392 *Dec 8, 1995Sep 1, 1998Union Carbide Chemicals & Plastics Technology CorporationDistortion control additives for ultraviolet-curable compositions
    US6025114 *Mar 6, 1996Feb 15, 2000Zeneca LimitedLiquid photocurable compositions
    US6054250 *Jan 26, 1998Apr 25, 2000Alliedsignal Inc.High temperature performance polymers for stereolithography
    US6600965Jan 26, 1999Jul 29, 20033D Systems, Inc.Method and apparatus for production of high resolution three-dimensional objects by stereolithography
    US20140129019 *Jan 13, 2014May 8, 2014Drexel UniversityMethods and apparatus for computer-aided tissue engineering for modeling, design and freeform fabrication of tissue scaffolds, constructs, and devices
    Classifications
    International ClassificationB29D11/00, C08F226/02, B29C35/08, B29C67/00, C08L33/06, C08F26/00, B29K33/04, G03F7/00, G03F7/028, B29K33/00, B29C39/00, G03F7/027
    Cooperative ClassificationG03F7/0037, B29C39/006, B29K2033/04, B29K2025/00, B29C67/0066, B29K2055/00
    European ClassificationB29C39/00B2, G03F7/00S, B29C67/00R2D2
    Legal Events
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